Unravelling the mechanism of photoinduced charge transfer processes in lead iodide perovskite solar cells

Nature Photonics

Volumn 8, Issue 3, 2014, Pages 250-255

  Marchioro, Arianna ^a   Teuscher, Joël ^a   Friedrich, Dennis ^b   Kunst, Marinus ^b   Van De Krol, Roel ^b   Moehl, Thomas ^a   Grätzel, Michael ^a   Moser, Jacques E ^a  

^a EPFL   (Switzerland)

^b HAHN MEITNER INSTITUT   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CHARGE RECOMBINATIONS; HOLE-TRANSPORTING MATERIALS; HYBRID ORGANIC-INORGANIC; MICROWAVE PHOTOCONDUCTIVITY; PHOTOINDUCED CHARGE TRANSFER; SOLID STATE SOLAR CELLS; TIME RESOLVED TECHNIQUE; TRANSIENT LASER SPECTROSCOPY;

CHARGE TRANSFER; LASER SPECTROSCOPY; PHOTOVOLTAIC CELLS; SOLAR CELLS;

PEROVSKITE;

EID: 84897604505     PISSN: 17494885     EISSN: 17494893     Source Type: Journal    
DOI: 10.1038/nphoton.2013.374     Document Type: Article

References (20)

1. Burschka, J. et al. Sequential deposition as a route to high-performance perovskite-sensitized solar cells. Nature 499, 316-319 (2013
2. Heo, J. H. et al. Efficient inorganic-organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors. Nature Photon. 7, 486-491 (2013
3. Noh, JH., Im, S. H., Heo, J. H., Mandal, T. N. & Seok, S. I. Chemical management for colorful, efficient, and stable inorganic-organic hybrid nanostructured solar cells. Nano Lett. 13, 1764-1769 (2013
4. Qiu, J. et al. All-solid-state hybrid solar cells based on a new organometal halide perovskite sensitizer and one-dimensional TiO2 nanowire arrays. Nanoscale 5, 3245-3248 (2013
5. Kim, H-S. et al. Lead iodide perovskite sensitized all-solid-state submicron thin film mesoscopic solar cell with efficiency exceeding 9%. Sci. Rep. 2, 591 (2012
6. Lee, M. M., Teuscher, J., Miyasaka, T., Murakami, T. N. & Snaith, H. J. Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites. Science 338, 643-647 (2012
7. Im, J-H., Lee, C-R., Lee, J-W., Park, S-W. & Park, N-G. 6.5% efficient perovskite quantum-dot-sensitized solar cell. Nanoscale 3, 4088-4093 (2011
8. Papavassiliou, G. C. Three-And low-dimensional inorganic semiconductors. Prog. Solid State Chem. 25, 125-270 (1997
9. Ishihara, T. Optical properties of PbI-based perovskite structures. J. Lumin. 60, 269-274 (1994
10. Mitzi, D. B. Templating and structural engineering in organic-inorganic perovskites. J. Chem. Soc. Dalton Trans. 1-12 (2001
11. Stoumpos, C. C., Malliakas, C. D. & Kanatzidis, M. G. Semiconducting tin and lead iodide perovskites with organic cations: Phase transitions, high mobilities, and near-infrared photoluminescent properties. Inorg. Chem. 52, 9019-9038 (2013
12. Etgar, L. et al. Mesoscopic CH3NH3PbI3/TiO2 heterojunction solar cells. J. Am. Chem. Soc. 134, 17396-17399 (2012
13. Bi, D., Yang, L., Boschloo, G., Hagfeldt, A. & Johansson, E. M. J. Effect of different hole transport materials on recombination in CH3NH3PbI3 perovskitesensitized mesoscopic solar cells. J. Phys. Chem. Lett. 4, 1532-1536 (2013
14. Liu, M., Johnston, M. B. & Snaith, H. J. Efficient planar heterojunction perovskite solar cells by vapour deposition. Nature 501, 395-398 (2013
15. Snaith, H. J. et al. Charge collection and pore filling in solid-state dye-sensitized solar cells. Nanotechnology 19, 424003 (2008
16. Olson, C., Veldman, D., Bakker, K. & Lenzmann, F. Characterization of the pore filling of solid state dye sensitized solar cells with photoinduced absorption spectroscopy. Int. J. Photoenergy 2011, 513089 (2011
17. Rothenberger, G., Fitzmaurice, D. & Grätzel, M. Spectroscopy of conduction band electrons in transparent metal oxide semiconductor films: Optical determination of the flatband potential of colloidal titanium dioxide films. J. Phys. Chem. 96, 5983-5986 (1992
18. Stranks, S. D. et al. Electron-hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber. Science 342, 341-344 (2013
19. Xing, G. et al. Long-range balanced electron-And hole-Transport lengths in organic-inorganic CH3NH3PbI3. Science 342, 344-347 (2013
20. Friedrich, D. & Kunst, M. Analysis of charge carrier kinetics in nanoporous systems by time resolved photoconductance measurements. J. Phys. Chem. C 115, 16657-16663 (2011