Ex situ and in situ Raman microscopic investigation of the differences between stoichiometric LiMO2 and high-energy xLi2MnO 3·(1-x)LiMO2 (M = Ni, Co, Mn)

Electrochimica Acta

Volumn 130, Issue , 2014, Pages 206-212

  Lanz, Patrick ^a   Villevieille, Claire ^a   Novák, Petr ^a  

^a PAUL SCHERRER INSTITUTE   (Switzerland)

Author keywords

High energy NCM; In situ Raman microscopy; Li ion batteries; Positive electrode material; Stoichiometric NCM

Indexed keywords

LITHIUM; LITHIUM BATTERIES; LITHIUM COMPOUNDS; MANGANESE; NICKEL; SCANNING ELECTRON MICROSCOPY; SOL-GEL PROCESS; X RAY DIFFRACTION;

HIGH-ENERGY NCM; LI-ION BATTERIES; POSITIVE ELECTRODE MATERIALS; SITU RAMAN; STOICHIOMETRIC NCM;

MANGANESE OXIDE;

EID: 84897494975     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2014.03.004     Document Type: Article

References (40)

1. T. Ohzuku, A. Ueda, M. Nagayama, Y. Iwakoshi, and H. Komori Comparative-Study of LiCoO2, LiNi1/2Co1/2O2 and LiNiO2 for 4- Volt Secondary Lithium Cells Electrochimica Acta 38 1993 1159
2. Y.Y. Xia, and M. Yoshio An investigation of lithium ion insertion into spinel structure Li-Mn-O compounds Journal of the Electrochemical Society 143 1996 825
3. A.K. Padhi, K.S. Nanjundaswamy, and J.B. Goodenough Phospho-olivines as positive-electrode materials for rechargeable lithium batteries Journal of the Electrochemical Society 144 1997 1188
4. M.S. Whittingham Lithium batteries and cathode materials Chemical Reviews 104 2004 4271
5. Z.L. Liu, A.S. Yu, and J.Y. Lee Synthesis and characterization of LiNi1-x-yCoxMnyO2 as the cathode materials of secondary lithium batteries Journal of Power Sources 82 1999 416
6. T. Ohzuku, and Y. Makimura Layered lithium insertion material of LiCo1/3Ni1/3Mn1/3O2 for lithium-ion batteries Chemistry Letters 2001 642
7. J.M. Kim, and H.T. Chung Role of transition metals in layered Li Ni,Co,Mn O-2 under electrochemical operation Electrochimica Acta 49 2004 3573
8. M.M. Thackeray, S.H. Kang, C.S. Johnson, J.T. Vaughey, R. Benedek, and S.A. Hackney Li2MnO3-stabilized LiM.O2 (M = Mn Ni, Co) electrodes for lithium-ion batteries Journal of Materials Chemistry 17 2007 3112
9. J.M. Kim, N. Kumagai, and H.T. Chung Improved electrochemical properties and structural stability of overlithiated Li1 + x (Ni1/3Co1/3Mn1/3)(1-x)O-2 prepared by spray-drying method Electrochemical and Solid State Letters 9 2006 A494
10. H.J. Yu, H.J. Kim, Y.R. Wang, P. He, D. Asakura, Y. Nakamura, and H.S. Zhou High-energy 'composite' layered manganese-rich cathode materials via controlling Li2MnO3 phase activation for lithium-ion batteries Physical Chemistry Chemical Physics 14 2012 6584
11. P. Lanz, H. Sommer, M. Schulz-Dobrick, and P. Novak Oxygen release from high-energy xLi(2)MnO(3)center dot(1-x)LiMO2 (M = Mn, Ni, Co): Electrochemical, differential electrochemical mass spectrometric, in situ pressure, and in situ temperature characterization Electrochimica Acta 93 2013 114
12. S.H. Yu, T. Yoon, J. Mun, S. Park, Y.S. Kang, J.H. Park, S.M. Oh, and Y.E. Sung Continuous activation of Li2MnO3 component upon cycling in Li1.167Ni0.233Co0.100Mn0.467Mo0.033O2 cathode material for lithium ion batteries Journal of Materials Chemistry A 1 2013 2833
13. M.M. Thackeray, S.H. Kang, C.S. Johnson, J.T. Vaughey, and S.A. Hackney Comments on the structural complexity of lithium-rich Li1 + xM1-xO2 electrodes (M = Mn, Ni, Co) for lithium batteries Electrochemistry Communications 8 2006 1531
14. J.S. Kim, C.S. Johnson, J.T. Vaughey, M.M. Thackeray, and S.A. Hackney Electrochemical and structural properties of xLi(2)M'O-3 center dot(1-x)LiMn0.5Ni0.5O2 eIectrodes for lithium batteries (M' = Ti, Mn, Zr; 0 <= x <= 0.3) Chemistry of Materials 16 2004 1996
15. Z.H. Lu, and J.R. Dahn Understanding the anomalous capacity of Li/Li NixLi(1/3-2x/3)Mn(2/3-x/3 O-2 cells using in situ X-ray diffraction and electrochemical studies Journal of the Electrochemical Society 149 2002 A815
16. N. Tran, L. Croguennec, M. Menetrier, F. Weill, P. Biensan, C. Jordy, and C. Delmas Mechanisms associated with the Plateau observed at high voltage for the overlithiated Li(1.12)(Ni(0.425)Mn(0.425)Co(0.15))(0.88)O(2) system Chemistry of Materials 20 2008 4815
17. C.L. Gan, H. Zhan, X.H. Hu, and Y.H. Zhou Origin of the irreversible plateau (4.5 V) of Li0.182Ni0.182Co0.091Mn0.545]O-2 layered material Electrochemistry Communications 7 2005 1318
18. N. Yabuuchi, K. Yoshii, S.T. Myung, I. Nakai, and S. Komaba Detailed Studies of a High-Capacity Electrode Material for Rechargeable Batteries, Li2MnO3-LiCo1/3Ni1/3Mn1/3O2 Journal of the American Chemical Society 133 2011 4404
19. A.R. Armstrong, M. Holzapfel, P. Novák, C.S. Johnson, S.H. Kang, M.M. Thackeray, and P.G. Bruce Demonstrating oxygen loss and associated structural reorganization in the lithium battery cathode Li[Ni0.2Li0.2Mn0.6]O-2 Journal of the American Chemical Society 128 2006 8694
20. A.D. Robertson, and P.G. Bruce Mechanism of electrochemical activity in Li2MnO3 Chemistry of Materials 15 2003 1984
21. H. Koga, L. Croguennec, P. Mannessiez, M. Menetrier, F. Weill, L. Bourgeois, M. Duttine, E. Suard, and C. Delmas Li1.20Mn0.54Co0.13Ni0.13O2 with Different Particle Sizes as Attractive Positive Electrode Materials for Lithium-Ion Batteries: Insights into Their Structure Journal of Physical Chemistry C 116 2012 13497
22. H. Koga, L. Croguennec, M. Menetrier, P. Mannessiez, F. Weill, and C. Delmas Different oxygen redox participation for bulk and surface: A possible global explanation for the cycling mechanism of Li1.20Mn0.54Co0.13Ni0.13O2 Journal of Power Sources 236 2013 250
23. X. Li, Y.J. Wei, H. Ehrenberg, F. Du, C.Z. Wang, and G. Chen Characterizations on the structural and electrochemical properties of LiNi1/3Mn1/3Co1/3O2 prepared by a wet-chemical process Solid State Ionics 178 2008 1969
24. X. Zhang, A. Mauger, Q. Lu, H. Groult, L. Perrigaud, F. Gendron, and C.M. Julien Synthesis and characterization of LiNi1/3Mn1/3Co1/3O2 by wet-chemical method Electrochimica Acta 55 2010 6440
25. F. Amalraj, D. Kovacheva, M. Talianker, L. Zeiri, J. Grinblat, N. Leifer, G. Goobes, B. Markovsky, and D. Aurbach Synthesis of Integrated Cathode Materials xLi(2)MnO(3)center dot(1 - x)LiMn(1/3)Ni(1/3)Co(1/3)O(2) (x = 0.3, 0.5, 0.7) and Studies of Their Electrochemical Behavior (vol 157, A1121, 2010) Journal of the Electrochemical Society 157 2010 S19
26. K. Ben-Kamel, N. Amdouni, A. Mauger, and C.M. Julien Study of the local structure of LiNi0.33 + delta Mn0.33 + delta Co0. 33-2 delta O2 (0.025 <= delta <= 0.075) oxides Journal of Alloys and Compounds 528 2012 91
27. F. Amalraj, M. Talianker, B. Markovsky, D. Sharon, L. Burlaka, G. Shafir, E. Zinigrad, O. Haik, D. Aurbach, J. Lampert, M. Schulz-Dobrick, and A. Garsuch Study of the Lithium-Rich Integrated Compound xLi(2)MnO(3) center dot (1-x)LiMO2 (x around 0.5; M = Mn, Ni, Co; 2:2:1) and Its Electrochemical Activity as Positive Electrode in Lithium Cells Journal of the Electrochemical Society 160 2013 A324
28. G. Singh, W.C. West, J. Soler, and R.S. Katiyar In situ Raman spectroscopy of layered solid solution Li2MnO3-LiMO2 (M = Ni, Mn, Co) Journal of Power Sources 218 2012 34
29. P. Novák, D. Goers, L.J. Hardwick, M. Holzapfel, W. Scheifele, J. Ufheil, and A. Würsig Advanced in situ characterization methods applied to carbonaceous materials Journal of Power Sources 146 2005 15
30. M. Moshkovich, M. Cojocaru, H.E. Gottlieb, and D. Aurbach The study of the anodic stability of alkyl carbonate solutions by in situ FTIR spectroscopy, EQCM, NMR and MS Journal of Electroanalytical Chemistry 497 2001 84
31. C.M. Julien, and M. Massot Lattice vibrations of materials for lithium rechargeable batteries III. Lithium manganese oxides Materials Science and Engineering B-Solid State Materials for Advanced Technology 100 2003 69
32. C. Julien, and M. Massot Raman scattering of LiNi1-yAlyO2 Solid State Ionics 148 2002 53
33. P. Lanz, C. Villevieille, and P. Novák Electrochemical activation of Li2MnO3 at elevated temperature investigated by in situ Raman microscopy Electrochimica Acta 109 2013 426
34. M.M. Thackeray Manganese oxides for lithium batteries Prog Solid State Chem 25 1997 1
35. T. Gao, H. Fjellvag, and P. Norby A comparison study on Raman scattering properties of alpha- and beta-MnO(2) Analytica Chimica Acta 648 2009 235
36. C. Julien, M. Massot, S. Rangan, M. Lemal, and D. Guyomard Study of structural defects in gamma-MnO2 by Raman spectroscopy Journal of Raman Spectroscopy 33 2002 223
37. R. Baddour-Hadjean, and J.P. Pereira-Ramos Raman Microspectrometry Applied to the Study of Electrode Materials for Lithium Batteries Chemical Reviews 110 2010 1278
38. S. Hy, F. Felix, J. Rick, W.-N. Su, and B.J. Hwang Direct In situ Observation of Li2O Evolution on Li-Rich High-Capacity Cathode Material, Li[NixLi(1-2x)/3Mn(2-x)/3]O2 (0 FOR VERIFICATION & x FOR VERIFICATION;0.5) Journal of the American Chemical Society 136 2013 999
39. M. Shibuya, T. Nishina, T. Matsue, and I. Uchida In situ conductivity measurements of LiCoO2 film during lithium insertion/extraction by using interdigitated microarray electrodes Journal of the Electrochemical Society 143 1996 3157
40. M. Inaba, H. Yoshida, Z. Ogumi, T. Abe, Y. Mizutani, and M. Asano In-Situ Raman-Study on Electrochemical Li-Intercalation into Graphite Journal of the Electrochemical Society 142 1995 20