Feasibility of electrochemical degradation of pharmaceutical pollutants in different aqueous matrices: Optimization through design of experiments

Journal of Environmental Science and Health - Part A Toxic/Hazardous Substances and Environmental Engineering

Volumn 49, Issue 7, 2014, Pages 843-850

  Palo, Patricia ^a   Domínguez, Joaquín R ^a   González, Teresa ^a   Sánchez Martin, Jesús ^a   Cuerda Correa, Eduardo M ^a  

^a UNIVERSITY OF EXTREMADURA   (Spain)

Author keywords

carbamazepine; design of experiments; Electro oxidation; pharmaceuticals; wastewater treatment

Indexed keywords

DESIGN OF EXPERIMENTS; DRUG PRODUCTS; EFFLUENTS; ELECTROOXIDATION; WASTEWATER TREATMENT;

AQUEOUS MATRICES; CARBAMAZEPINE; DESIGNS OF EXPERIMENTS; ELECTROCHEMICAL DEGRADATION; OPERATIONAL VARIABLES; PHARMACEUTICAL CONTAMINANTS; ULTRA-PURE WATER; URBAN WASTEWATER;

AMIDES;

CARBAMAZEPINE; LAKE WATER; SURFACE WATER; DRUG; WASTE WATER; WATER POLLUTANT;

ARTICLE; COMPARATIVE STUDY; DEGRADATION; EFFLUENT; ELECTRIC CURRENT; ELECTROCHEMISTRY; EXPERIMENTAL DESIGN; FEASIBILITY STUDY; OXIDATION; PHARMACEUTICAL POLLUTANT; POLLUTANT; WASTE WATER TREATMENT PLANT; ANALYSIS; CHEMISTRY; ECOSYSTEM RESTORATION; ELECTROLYSIS; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; OXIDATION REDUCTION REACTION; PROCEDURES; SEWAGE; WASTE WATER; WATER MANAGEMENT; WATER POLLUTANT;

CARBAMAZEPINE; CHROMATOGRAPHY, HIGH PRESSURE LIQUID; ELECTROLYSIS; ENVIRONMENTAL RESTORATION AND REMEDIATION; OXIDATION-REDUCTION; PHARMACEUTICAL PREPARATIONS; WASTE DISPOSAL, FLUID; WASTE WATER; WATER POLLUTANTS, CHEMICAL; WATER PURIFICATION;

EID: 84897464819     PISSN: 10934529     EISSN: 15324117     Source Type: Journal    
DOI: 10.1080/10934529.2014.882652     Document Type: Article

References (24)

1. Scheytt, T.J.; Mersmann, P.; Heberer, T. Mobility of pharmaceuticals carbamazepine, diclofenac, ibuprofen, and propyphenazone in miscible- displacement experiments. J. Contam. Hydrol. 2006, 83(1-2), 53-69.
2. Polar, J.A. The fate of pharmaceuticals after wastewater treatment. Fla. Water Resour. J. 2007, 6, 26-31.
3. Mompelat, S.; Lebot, B.; Thomas, O. Occurrence and fate of pharmaceutical products and by-products, from resource to drinking water. Environ. Int. 2009, 35, 803-814.
4. Martinez-Bueno, M.J.; Aguera, A.; Gomez, M.J.; Hernando, M.D.; Garcia-Reyes, J.F.; Fernandez-Alba, A.R. Application of LC/quadrupole-linear ion trap mass spectrometry and time of flight mass spectrometry to the determination of pharmaceuticals and related contaminants in wastewater. Anal. Chem. 2007, 79, 9372-9384.
5. Benotti, M.J.; Trenholm, R.A.; Vanderford, B.J.; Holady, J.C.; Stanford, B.D.; Snyder, S.A. Pharmaceuticals and endocrine disrupting compounds in U.S. drinking water. Environ. Sci. Technol. 2009, 43, 597-603.
6. Daughton, C.G.; Ternes, T.A. Pharmaceuticals and personal care products in the environment: agents of subtle change? Environ. Health Persp. 1999, 107, 907-938.
7. Clara, M.; Kreuzinger, N.; Strenn, B.; Gans, O.; Kroiss, H. The solids retention time-a suitable design parameter to evaluate the capacity of wastewater treatment plants to remove micropollutants. Water Res. 2005, 39, 97-106.
8. RxList. The Internet Drug Index. WebMP: Atlanta, GA, 2006. Available at http://www.rxlist.com
9. Clara, M.; Strenn, B.; Kreuzinger, N. Carbamazepine as a possible anthropogenic marker in the aquatic environment: investigations on the behavior of carbamazepine in wastewater treatment and during groundwater infiltration. Water Res. 2004, 38, 947-954.
10. González, T.; Domínguez, J.R.; Palo, P.; Sánchez-Martín, J. Development and optimization of the BDD-electrochemical oxidation of the antibiotic trimethoprim in aqueous solution. Desalination 2011, 280(1-3), 197-202.
11. Domínguez, J.R.; González, T.; Palo, P.; Sánchez-Martín, J.; Rodrigo, M.A.; Sáez, C. Electrochemical degradation of a real pharmaceutical effluent. Water Air Soil Pollut. 2012, 223, 2685-2694.
12. Domínguez, J.R.; González, T.; Palo, P.; Sánchez-Martín, J. Electrochemical advanced oxidation of carbamazepine on boron-doped diamond anodes. Influence of operating variables. Ind. Eng. Chem. Res. 2010, 49, 8353-8359.
13. Hupert, M.; Muck, A.; Wang, J.; Stotter, J.; Cvackova, Z.; Hay-mond, S.; Show, Y.; Swain, G. Conductive diamond thin-films in electrochemistry. Diam. Relat. Mater. 2003, 12, 1940-1949.
14. Chen, G. Electrochemical technologies in wastewater treatment. Sep. Purif. Technol. 2004, 38, 11-41.
15. Marselli, B.; García-Gomez, J.; Michaud, P.A.; Rodrigo, M.A.; Comninellis, Ch. Electrogeneration of hydroxyl radicals on boron-doped diamond electrodes. J. Electrochem. Soc. 2003, 150, D79-D83.
16. Panizza, M.; Cerisola, G. Application of diamond electrodes to electrochemical processes. Electrochim. Acta 2005, 51, 191-199.
17. Brillas, E.; Calpe, J.C.; Casado, J. Mineralization of 2, 4-D by advanced electrochemical oxidation processes. Water Res. 2000, 34, 2253-2262.
18. Martínez-Huitle, C.A.; Ferro, S. Electrochemical oxidation of organic pollutants for the wastewater treatment: direct and indirect processes. Chem. Soc. Rev. 2006, 35, 1324-1340.
19. Sánchez-Martín, J.; Beltrán-Heredia, J.; Delgado-Regañ, A.; Rodríguez-González, M.A.; Rubio-Alonso, F. Optimization of tannin rigid foam as adsorbents in wastewater treatment. Ind. Crop. Prod. 2009, 49(1), 507-514.
20. Beltrán-Heredia, J.; Sánchez-Martín, J.; Martín-García, L. Multiparameter quantitative optimization in the synthesis of a novel coagulant derived from tannin extracts for water treatment. Water Air Soil Poll. 2012, 223(5), 2277-2286.
21. Kumar, V.; Porkodi, K.; Rocha, F. Isotherms and thermodynamics by linear and non-linear regression analysis for the sorption of methylene blue onto activated carbon: comparison of various error functions. J. Hazard. Mater. 2001, 151(2-3), 794-804.
22. Palo, P.; Domínguez, J.R.; Sánchez-Martín, J. Ozonation of a Car-bamazepine effluent. Designing the operational parameters under economic considerations. Water Air Soil Poll. 2012, 223(9), 5999-6007.
23. González, T.; Domínguez, J.R.; Palo, P.; Sánchez-Martín, J.; Cuerda-Correa, E.M. Development and optimization of the BDD-Electrochemical oxidation of the antibiotic Trimethoprim in aqueous solution. Desalination 2011, 280(1-3), 197-202.
24. Montgomery, D.C. Design and Analysis of Experiments, 8th ed.; Wiley and Sons: New York, 2012.