Mechanism of graphene oxide formation

ACS Nano

Volumn 8, Issue 3, 2014, Pages 3060-3068

  Dimiev, Ayrat M ^a,d   Tour, James M ^a,b,c  

^a RICE UNIVERSITY   (United States)

^b Rice University   (United States)

^c RICE UNIVERSITY   (United States)

^d AZ Electronic Materials USA Corp   (United States)

Author keywords

graphene oxide; graphite; graphite intercalation compound

Indexed keywords

COMPOSITE FILMS; GRAPHENE; INTERCALATION; INTERCALATION COMPOUNDS; OXIDATION; REACTION INTERMEDIATES;

GRAPHENE OXIDES; INTENSIVE RESEARCH; INTERFACIAL INTERACTION; INTERMEDIATE PRODUCT; LIQUID REACTION; OXIDIZED GRAPHITES; OXIDIZING AGENTS; RATE DETERMINING STEP;

GRAPHITE;

EID: 84897008318     PISSN: 19360851     EISSN: 1936086X     Source Type: Journal    
DOI: 10.1021/nn500606a     Document Type: Article

References (36)

1. Dreyer, D. R.; Park, S.; Bielawski, W.; Ruoff, R. S. The Chemistry of Graphene Oxide Chem. Soc. Rev. 2010, 39, 228-240
2. Brodie, B. Note sur un Nouveau Procede pour la Purification et la Pesagregation du Graphite Ann. Chim. Phys. 1855, 45, 351-353
3. Zhu, Y.; James, D. K.; Tour, J. M. New Routes to Graphene, Graphene Oxide and Their Potential Applications Adv. Mater. 2012, 24, 4924-4955
4. Kim, J.; Cote, L. J.; Huang, J. Two Dimensional Soft Material: New Faces of Graphene Oxide Acc. Chem. Res. 2012, 45, 1356-1364
5. Jalili, R.; Aboutalebi, S. H.; Esrafilzadeh, D.; Konstantinov, K.; Moulton, E.; Razal, J. M.; Wallace, G. G. Organic Solvent Based Graphene Oxide Liquid Crystals: A Facile Route Toward the Next Generation of Self-Assembled Layer-by-Layer Multifunctional 3D Architectures ACS Nano 2013, 7, 3981-3990
6. Gudarzi, M. M.; Moghadam, M. H. M.; Sharif, F. Spontaneous Exfoliation of Graphite Oxide in Polar Aprotic Solvents as the Route to Produce Graphene Oxide-Organic Solvents Liquid Crystals Carbon 2013, 10.1016/j.carbon.2013.07.093
7. Hummers, W. S.; Offeman, R. E. Preparation of Graphitic Oxide J. Am. Chem. Soc. 1958, 80, 1339
8. Marcano, D. C.; Kosynkin, D. V.; Berlin, J. M.; Sinitskii, A.; Sun, Z.; Slesarev, A.; Alemany, L. B.; Lu, W.; Tour, J. M. Improved Synthesis of Graphene Oxide ACS Nano 2010, 4, 4806-4814
9. Li, J.-L.; Kudin, K. N.; McAllister, M. J.; Prudhomme, R. K.; Aksay, I. A.; Car, R. Oxygen-Driven Unzipping of Graphitic Materials Phys. Rev. Lett. 2006, 96, 176101-4
10. Sun, T.; Fabris, S. Mechanisms for Oxidative Unzipping and Cutting of Graphene Nano Lett. 2012, 12, 17-21
11. Shao, G.; Lu, Y.; Wu, F.; Yang, C.; Zeng, F.; Wu, Q. Graphene Oxide: the Mechanism of Oxidation and Exfoliation J. Mater. Sci. 2012, 47, 4400-4409
12. 13C NMR Study of Graphite Oxide Carbon 1991, 29, 469-474
13. Hontoria-Lucas, C.; Lopes-Peinado, A. J.; Lopez-Gonzalez, J. D.; Rojas-Cervantes, M. L.; Martin-Aranda, R. M. Study of Oxygen-Containing Groups in a Series of Graphite Oxides: Physical and Chemical Characterization Carbon 1995, 33, 1585-1592
14. Szabo, T.; Berkesi, O.; Forgo, P.; Josepovits, K.; Sanakis, Y.; Petridis, D.; Dekany, I. Evolution of Surface Functional Groups in a Series of Progressively Oxidized Graphite Oxide Chem. Mater. 2006, 18, 2740-2749
15. Krishnamoorthy, K.; Veerapandian, M.; Yun, K.; Kim, S.-J. The Chemical and Structural Analysis of Graphene Oxide with Different Degrees of Oxidation Carbon 2013, 53, 38-49
16. Dimiev, A. M.; Bachilo, S.; Saito, R.; Tour, J. M. Reversible Formation of Ammonium Persulfate-Sulfuric Acid Graphite Intercalation Compounds and Their Peculiar Raman Spectra ACS Nano 2012, 6, 7842-7849
17. Dimiev, A. M.; Cierotti, G.; Behabtu, N.; Zakhidov, D.; Pasquali, M.; Saito, R.; Tour, J. M. Direct, Real Time Monitoring of Stage Transitions in Graphite Intercalation Compounds ACS Nano 2013, 7, 2773-2780
18. 4 J. Mater. Res. 1986, 1, 361-367
19. 4-GICS Synth. Met. 1989, 34, 341-346
20. Inagaki, M.; Iwashita, N.; Kouno, E. Potential Change with Intercalation of Sulfuric Acid into Graphite by Chemical Oxidation Carbon 1990, 28, 49-55
21. Chen, C.-F.; Park, C.-H.; Boudouris, B. W.; Horng, J.; Geng, B.; Girit, C.; Zettl, A.; Crommie, M. F.; Segalman, R. A.; Louie, S. G. et al. Controlling Inelastic Light Scattering Quantum Pathways in Graphene Nature 2011, 471, 617-620
22. 3: Raman Determination of Fermi Level, Layer by Layer Decoupling, and Stability J. Am. Chem. Soc. 2011, 133, 5941-5946
23. Kudin, K. N.; Ozbas, B.; Schniepp, H. C.; Prud'homme, R. K.; Aksay, I. A.; Car, R. Raman Spectra of Graphite Oxide and Functionalized Graphene Sheets Nano Lett. 2008, 8, 36-41
24. Eigler, S.; Dotzer, C.; Hirsch, A. Visualization of Defect Densities in Reduced Graphene Oxide Carbon 2012, 50, 3666-3673
25. Glemser, V. O.; Schröder, H. Zur Kenntnis des Mangan(VII)-Oxyds Z. Anorg. Allg. Chem. 1953, 271, 293-304
26. Royer, D. J. Evidence for the Existence of the Permanganyl Ion in Sulfuric Acid Solutions of Potassium Permanganate J. Inorg. Nucl. Chem. 1961, 17, 159-167
27. Dzhabiev, T. S.; Denisov, N. N.; Moiseev, D. N.; Shilov, A. E. Formation of Ozone during the Reduction of Potassium Permanganate in Sulfuric Acid Solutions Russ. J. Phys. Chem. 2005, 79, 1755-1760
28. Eigler, S.; Enzelberger-Heim, M.; Grimm, S.; Hofmann, P.; Kroener, W.; Geworski, A.; Dotzer, C.; Röckert, M.; Xiao, J.; Papp, C.; Lytken, O.; Steinrück, H.-P.; Müller, P.; Hirsh, A. Wet Chemical Synthesis of Graphene Adv. Mater. 2013, 25, 3583-35
29. Jasinski, J. B.; Dumpala, S.; Sumanasekera, G. U.; Sunkara, M. K.; Ouseph, P. J. Observation and Interpretation of Adjacent Moiré Patterns of Different Shapes in Bilayer Graphene Appl. Phys. Lett. 2011, 99, 073104
30. Ryu, G. H.; Park, H. J.; Kim, N. Y.; Lee, Z. Atomic Resolution Imaging of Rotated Bilayer Graphene Sheets Using a Low kV Aberration-Corrected Transmission Electron Microscope Appl. Microsc. 2012, 42, 218-222
31. Mele, E. J. Interlayer Coupling in Rotationally Faulted Multilayer Graphenes J. Phys. D: Appl. Phys. 2012, 45, 154004
32. Lerf, A.; He, H.; Forster, M.; Klinowski, J. Structure of Graphite Oxide Revisited J. Phys. Chem. 1998, 102, 4477-4482
33. Erickson, K.; Erni, R.; Zonghoon Lee, Z.; Alem, N.; Will Gannett, A.; Zettl, A. Determination of the Local Chemical Structure of Graphene Oxide and Reduced Graphene Oxide Adv. Mater. 2010, 22, 4467-4472
34. Dimiev, A.; Kosynkin, D. V.; Alemany, L. B.; Chaguine, P.; Tour, J. M. Pristine Graphite Oxide J. Am. Chem. Soc. 2012, 134, 2815-2822
35. Dimiev, A.; Alemany, L.; Tour, J. M. Graphene Oxide. Origin of Acidity and Dynamic Structural Model ACS Nano 2012, 7, 576-588
36. Eigler, S.; Dotzer, C.; Hof, F.; Bauer, W.; Hirsch, A. Sulfur Species in Graphene Oxide Chem.-Eur. J. 2013, 19, 9490-9496