Deuterium studies reveal a new mechanism for the formose reaction involving hydride shifts

Journal of the American Chemical Society

Volumn 136, Issue 10, 2014, Pages 3720-3723

  Appayee, Chandrakumar ^a   Breslow, Ronald ^a  

^a Department of Chemistry Columbia University ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

SYNTHESIS (CHEMICAL);

FORMOSE REACTION; GLYCOLALDEHYDES; NEW MECHANISMS; PREBIOTIC CONDITIONS;

CHEMISTRY;

DEUTERIUM; DIMER; FORMALDEHYDE; FORMOSE; PREBIOTIC AGENT; SUGAR; UNCLASSIFIED DRUG; ACETALDEHYDE; CARBOHYDRATE; FORMOSE SUGARS; GLYCOLALDEHYDE;

ARTICLE; BIOTRANSFORMATION; CATALYSIS; CHEMICAL ANALYSIS; CHEMICAL REACTION; DIMERIZATION; DRUG SYNTHESIS; ENANTIOMER; FORMOSE REACTION; ISOMERIZATION; ANALOGS AND DERIVATIVES; BIOGENESIS; CHEMISTRY;

ACETALDEHYDE; BIOGENESIS; CARBOHYDRATES; DEUTERIUM; DIMERIZATION; FORMALDEHYDE;

EID: 84896273790     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja410886c     Document Type: Article

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