Rhodium-catalysed [2 + 2 + 2] cyclotrimerization in an aqueous-organic biphasic system

Catalysts for Fine Chemical Synthesis: Metal Catalysed Carbon-Carbon Bond-Forming Reactions

Volumn 3, Issue , 2005, Pages 193-196

  Shinokubo, Hiroshi ^a   Oshima, Koichiro ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

Acetoxypalladation initiated carbonheteroatom multiple bond insertion protonolysis system; Alkyne cyclotrimerization; Carbon carbon multiple bond insertion; Carbon palladium bond; Carbon transition metal bonds; Eudesmanolides; Flash chromatography; Pauson khand reaction (PKR); Titanocene catalyzed cyclization of epoxygermacrolides

Indexed keywords

CATALYSIS; HYDROCARBONS; KETONES; MOLECULAR SIEVES; PALLADIUM COMPOUNDS; RHODIUM COMPOUNDS; TRANSITION METALS;

CYCLOTRIMERIZATION; EUDESMANOLIDES; FLASH CHROMATOGRAPHY; MULTIPLE BONDS; PAUSON-KHAND REACTIONS; TITANOCENES;

CYCLIZATION;

EID: 84895226563     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1002/0470862017.ch10     Document Type: Chapter

References (5)

1. Vollhardt, K. P. C. Angew. Chem., Int. Ed. Engl. 1984, 23, 539.
2. Kinoshita, H., Shinokubo, H. and Oshima, K. J. Am. Chem. Soc. 2003, 125, 7784.
3. For biphasic catalysis, see: Sinou, D. In Modern Solvent in Organic Synthesis, Knochel, P. (Ed.) Springer-Verlag, Berlin, 1999; p. 41.
4. Cornils, B. and Herrmann, W. A. Aqueous-Phase Organometallic Chemistry, Wiley-VCH: Weinheim, 1998.
5. Li, C.-J. and Chan, T.-H. Organic Reactions in Aqueous Media, John Wiley & Sons, New York, 1997.