Vapor-phase polymerization of nanofibrillar poly(3,4- ethylenedioxythiophene) for supercapacitors

ACS Nano

Volumn 8, Issue 2, 2014, Pages 1500-1510

  D'Arcy, Julio M ^a,b   El Kady, Maher F ^c,d   Khine, Pwint P ^c   Zhang, Linghong ^c   Lee, Sun Hwa ^a,b   Davis, Nicole R ^a,b   Liu, David S ^a,b   Yeung, Michael T ^c   Kim, Sung Yeol ^a,b,e   Turner, Christopher L ^c   Lech, Andrew T ^c   Hammond, Paula T ^a,b   Kaner, Richard B ^c,f  

^a Department of Chemical Engineering ^*  (United States)

^b MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

^c UNIVERSITY OF CALIFORNIA   (United States)

^d CAIRO UNIVERSITY   (Egypt)

^e Kyungpook National University   (South Korea)

^f University of California   (United States)

Author keywords

conducting polymer; nanofibers; poly(3,4 ethylenedioxythiophene); supercapacitor; vapor phase polymerization

Indexed keywords

FUSED HETEROCYCLIC RINGS; NANOFIBER; POLY(3,4 ETHYLENE DIOXYTHIOPHENE); POLY(3,4-ETHYLENE DIOXYTHIOPHENE); POLYMER;

ARTICLE; CHEMISTRY; POLYMERIZATION;

BICYCLO COMPOUNDS, HETEROCYCLIC; NANOFIBERS; POLYMERIZATION; POLYMERS;

EID: 84894636411     PISSN: 19360851     EISSN: 1936086X     Source Type: Journal    
DOI: 10.1021/nn405595r     Document Type: Article

References (39)

1. Simon, P.; Gogotsi, Y. Materials for Electrochemical Capacitors Nat. Mater. 2008, 7, 845-854
2. Yang, Y.; Zhang, L.; Li, S.; Yang, W.; Xu, J.; Jiang, Y.; Wen, J. Electrochemical Performance of Conducting Polymer and Its Nanocomposites Prepared by Chemical Vapor Phase Polymerization Method J. Mater. Sci.: Mater. Electron. 2013, 24, 2245-2253
3. Pandey, G. P.; Rastogi, A. C.; Westgate, C. R. All-Solid-State Supercapacitors with Poly(3,4-ethylenedioxythiophene)-Coated Carbon Fiber Paper Electrodes and Ionic Liquid Gel Polymer Electrolyte J. Power Sources 2014, 245, 857-865
4. Hsu, Y.-K.; Chen, Y.-C.; Lin, Y.-G.; Chen, L.-C.; Chen, K.-H. Direct-Growth of Poly(3,4-ethylenedioxythiophene) Nanowires/Carbon Cloth as Hierarchical Supercapacitor Electrode in Neutral Aqueous Solution J. Power Sources 2013, 242, 718-724
5. Patra, S.; Munichandraiah, N. Supercapacitor Studies of Electrochemically Deposited PEDOT on Stainless Steel Substrate J. Appl. Polym. Sci. 2007, 106, 1160-1171
6. Liu, R.; Cho, S. I.; Lee, S. B. Poly(3,4-ethylenedioxythiophene) Nanotubes as Electrode Materials for a High-Powered Supercapacitor Nanotechnology 2008, 19, 215710-215717
7. Kim, J.-Y.; Kwon, M.-H.; Min, Y.-K.; Kwon, S.; Ihm, D.-W. Self-Assembly and Crystalline Growth of Poly(3,4-ethylenedioxythiophene) Nanofilms Adv. Mater. 2007, 19, 3501-3506
8. Aradilla, D.; Estrany, F.; Armelin, E.; Alemán, C. Ultraporous Poly(3,4-ethylenedioxythiophene) for Nanometric Electrochemical Supercapacitor Thin Solid Films 2012, 520, 4402-4409
9. Xie, X. N.; Wang, J.; Lee, K. K.; Loh, K. P. Supercapacitive Energy Storage Based on Ion-Conducting Channels in Hydrophilized Organic Network J. Polym. Sci., Part B: Polym. Phys. 2011, 49, 1234-1240
10. Gogotsi, Y.; Simon, P. True Performance Metrics in Electrochemical Energy Storage Science 2011, 334, 917-918
11. Laforgue, A. All-Textile Flexible Supercapacitors Using Electrospun Poly(3,4-ethylenedioxythiophene) Nanofibers J. Power Sources 2011, 196, 559-564
12. Im, S. G.; Gleason, K. K. Systematic Control of the Electrical Conductivity of Poly(3,4-ethylenedioxythiophene) via Oxidative Chemical Vapor Deposition Macromolecules 2007, 40, 6552-6556
13. Winther-Jensen, O.; Desai, S.; Shepherd, R. L.; Innis, P. C.; Winther-Jensen, B.; Forsyth, M.; Wallace, G. G.; MacFarlane, D. R. Ion Effects in Redox Cycling of Conducting Polymer Based Electrochromic Materials Electrochem. Commun. 2010, 12, 1505-1508
14. Mozer, A. J.; Panda, D. K.; Gambhir, S.; Romeo, T. C.; Winther-Jensen, B.; Wallace, G. G. Flexible and Compressible Goretex-PEDOT Membrane Electrodes for Solid-State Dye-Sensitized Solar Cells Langmuir 2009, 26, 1452-1455
15. Chen, C.-C.; Dou, L.; Zhu, R.; Chung, C.-H.; Song, T.-B.; Zheng, Y. B.; Hawks, S.; Li, G.; Weiss, P. S.; Yang, Y. Visibly Transparent Polymer Solar Cells Produced by Solution Processing ACS Nano 2012, 6, 7185-7190
16. Winther-Jensen, B.; Winther-Jensen, O.; Forsyth, M.; Macfarlane, D. R. High Rates of Oxygen Reduction over a Vapor Phase-Polymerized PEDOT Electrode Science 2008, 321, 671-674
17. Cao, Y.; Kovalev, A. E.; Xiao, R.; Kim, J.; Mayer, T. S.; Mallouk, T. E. Electrical Transport and Chemical Sensing Properties of Individual Conducting Polymer Nanowires Nano Lett. 2008, 8, 4653-4658
18. Im, S. G.; Kusters, D.; Choi, W.; Baxamusa, S. H.; van de Sanden, M. C. M.; Gleason, K. K. Conformal Coverage of Poly(3,4-ethylenedioxythiophene) Films with Tunable Nanoporosity via Oxidative Chemical Vapor Deposition ACS Nano 2008, 2, 1959-1967
19. Martin, D. C.; Wu, J.; Shaw, C. M.; King, Z.; Spanninga, S. A.; Richardson-Burns, S.; Hendricks, J.; Yang, J. The Morphology of Poly(3,4-ethylenedioxythiophene) Polym. Rev. 2010, 50, 340-384
20. Lee, J. A.; Shin, M. K.; Kim, S. H.; Kim, S. J.; Spinks, G. M.; Wallace, G. G.; Ovalle-Robles, R.; Lima, M. D.; Kozlov, M. E.; Baughman, R. H. Hybrid Nanomembranes for High Power and High Energy Density Supercapacitors and Their Yarn Application ACS Nano 2011, 6, 327-334
21. Trujillo, N. J.; Barr, M. C.; Im, S. G.; Gleason, K. K. Oxidative Chemical Vapor Deposition (oCVD) of Patterned and Functional Grafted Conducting Polymer Nanostructures J. Mater. Chem. 2010, 20, 3968-3972
22. Bhattacharyya, D.; Yang, R.; Gleason, K. K. High Aspect Ratio, Functionalizable Conducting Copolymer Nanobundles J. Mater. Chem. 2012, 22, 17147-17152
23. Laforgue, A.; Robitaille, L. Deposition of Ultrathin Coatings of Polypyrrole and Poly(3,4-ethylenedioxythiophene) onto Electrospun Nanofibers Using a Vapor-Phase Polymerization Method Chem. Mater. 2010, 22, 2474-2480
24. Kwon, O. S.; Park, E.; Kweon, O. Y.; Park, S. J.; Jang, J. Novel Flexible Chemical Gas Sensor Based on Poly(3,4-ethylenedioxythiophene) Nanotube Membrane Talanta 2010, 82, 1338-1343
25. Yang, X.-M.; Shang, S.-M.; Li, L.; Tao, X.-M.; Yan, F. Vapor Phase Polymerization of 3,4-ethylenedioxythiophene on Flexible Substrate and Its Application on Heat Generation Polym. Adv. Technol. 2011, 22, 1049-1055
26. Fabretto, M.; Zuber, K.; Hall, C.; Murphy, P.; Griesser, H. J. The Role of Water in the Synthesis and Performance of Vapour Phase Polymerised PEDOT Electrochromic Devices J. Mater. Chem. 2009, 19, 7871-7878
27. Chelawat, H.; Vaddiraju, S.; Gleason, K. Conformal, Conducting Poly(3,4-ethylenedioxythiophene) Thin Films Deposited Using Bromine as the Oxidant in a Completely Dry Oxidative Chemical Vapor Deposition Process Chem. Mater. 2010, 22, 2864-2868
28. Jang, K.-S.; Kim, D. O.; Lee, J.-H.; Hong, S.-C.; Lee, T.-W.; Lee, Y.; Nam, J.-D. Synchronous Vapor-Phase Polymerization of Poly(3,4- ethylenedioxythiophene) and Poly(3-hexylthiophene) Copolymer Systems for Tunable Optoelectronic Properties Org. Electron. 2010, 11, 1668-1675
29. Kim, T.-W.; Woo, H.-Y.; Jung, W.-G.; Ihm, D.-W.; Kim, J.-Y. On the Mechanism of Conductivity Enhancement in Plasma Treated Poly(3,4- ethylenedioxythiophene) Films Thin Solid Films 2009, 517, 4147-4151
30. Zou, R.; Guo, X.; Yang, J.; Li, D.; Peng, F.; Zhang, L.; Wang, H.; Yu, H. Selective Etching of Gold Nanorods by Ferric Chloride at Room Temperature CrystEngComm 2009, 11, 2797-2803
31. Yang, D.-Q.; Sacher, E. Core/Shell Formation of Gold Nanoparticles Induced on Exposure to N, N-Dimethylformamide: Chemical and Morphological Changes J. Phys. Chem. C 2007, 111, 14320-14326
32. Deegan, R. D. Pattern Formation in Drying Drops Phys. Rev. E 2000, 61, 475-485
33. Winther-Jensen, B.; Forsyth, M.; West, K.; Andreasen, J. W.; Bayley, P.; Pas, S.; MacFarlane, D. R. Order-Disorder Transitions in Poly(3,4- ethylenedioxythiophene) Polymer 2008, 49, 481-487
34. Subramanian, P.; Clark, N.; Winther-Jensen, B.; MacFarlane, D.; Spiccia, L. Vapour-Phase Polymerization of Pyrrole and 3,4-Ethylenedioxythiophene Using Iron(III) 2,4,6-Trimethylbenzenesulfonate Aust. J. Chem. 2009, 62, 133-139
35. Winther-Jensen, B.; West, K. Vapor-Phase Polymerization of 3,4-Ethylenedioxythiophene: A Route to Highly Conducting Polymer Surface Layers Macromolecules 2004, 37, 4538-4543
36. Bubnova, O.; Khan, Z. U.; Malti, A.; Braun, S.; Fahlman, M.; Berggren, M.; Crispin, X. Optimization of the Thermoelectric Figure of Merit in the Conducting Polymer Poly(3,4-ethylenedioxythiophene) Nat. Mater. 2011, 10, 429-433
37. Dou, L.; You, J.; Yang, J.; Chen, C.-C.; He, Y.; Murase, S.; Moriarty, T.; Emery, K.; Li, G.; Yang, Y. Tandem Polymer Solar Cells Featuring a Spectrally Matched Low-Bandgap Polymer Nat. Photonics 2012, 6, 180-185
38. Yang, Y.; Yu, G.; Cha, J. J.; Wu, H.; Vosgueritchian, M.; Yao, Y.; Bao, Z.; Cui, Y. Improving the Performance of Lithium-Sulfur Batteries by Conductive Polymer Coating ACS Nano 2011, 5, 9187-9193
39. El-Kady, M. F.; Strong, V.; Dubin, S.; Kaner, R. B. Laser Scribing of High-Performance and Flexible Graphene-Based Electrochemical Capacitors Science 2012, 335, 1326-1330