The mechanism of hydrocarbon oxygenate reforming: C-C bond scission, carbon formation, and noble-metal-free oxide catalysts

ChemSusChem

Volumn 7, Issue 1, 2014, Pages 77-81

  Lykhach, Yaroslava ^a   Neitzel, Armin ^a   Ševčíková, Klára ^b   Johánek, Viktor ^b   Tsud, Nataliya ^b   Skála, Tomáš ^b   Prince, Kevin C ^c,d   Matolín, Vladimír ^b   Libuda, Jörg ^a  

^a UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

^b CHARLES UNIVERSITY   (Czech Republic)

^c SINCROTRONE TRIESTE   (Italy)

^d IOM CNR LABORATORIO TASC   (Italy)

Author keywords

Catalytic reforming; Ceria; Heterogeneous catalysis; Photoelectron spectroscopy; Platinum

Indexed keywords

CARBON FORMATION; CATALYST SURFACES; MODEL CATALYSTS; MOLECULAR UNDERSTANDING; OXIDE CATALYSTS; REACTANT MOLECULES; REACTION PATHWAYS; SURFACE CARBON;

CATALYSIS; CATALYTIC REFORMING; CERIUM COMPOUNDS; COVALENT BONDS; ETHYLENE GLYCOL; HYDROCARBONS; PHOTOELECTRON SPECTROSCOPY; PLATINUM; POLYOLS;

CATALYSTS;

ACETIC ACID; ALCOHOL; CARBON; CERIC OXIDE; CERIUM; CERIUM OXIDE; ETHYLENE GLYCOL; PLATINUM;

ARTICLE; CATALYSIS; CATALYTIC REFORMING; CHEMISTRY; HETEROGENEOUS CATALYSIS; X RAY PHOTOELECTRON SPECTROSCOPY;

CATALYTIC REFORMING; CERIA; HETEROGENEOUS CATALYSIS; PHOTOELECTRON SPECTROSCOPY; PLATINUM;

ACETIC ACID; CARBON; CATALYSIS; CERIUM; ETHANOL; ETHYLENE GLYCOL; PLATINUM;

EID: 84893872936     PISSN: 18645631     EISSN: 1864564X     Source Type: Journal    
DOI: 10.1002/cssc.201301000     Document Type: Article

References (43)

1. a) U. Eberle, M. Felderhoff, F. Schüth, Angew. Chem. 2009, 121, 6732-6757;
2. Angew. Chem. Int. Ed. 2009, 48, 6608-6630;
3. D. Chen, L. He, ChemCatChem 2011, 3, 490-511;
4. G. W. Huber, S. Iborra, A. Corma, Chem. Rev. 2006, 106, 4044-4098;
5. M. Balat, Int. J. Hydrogen Energy 2008, 33, 4013-4029.
6. a) J. D. Holladay, J. Hu, D. L. King, Y. Wang, Catal. Today 2009, 139, 244-260;
7. R. M. Navarro, M. A. Pena, J. L. G. Fierro, Chem. Rev. 2007, 107, 3952-3991;
8. N. Muradov, Int. J. Hydrogen Energy 2001, 26, 1165-1175.
9. a) R. D. Cortright, R. R. Davda, J. A. Dumesic, Nature 2002, 418, 964-967;
10. N. Z. Muradov, T. N. Veziroglu, Int. J. Hydrogen Energy 2008, 33, 6804-6839.
11. L. Garcia, R. French, S. Czernik, E. Chornet, Appl. Catal. A 2000, 201, 225-239.
12. B. M. Güell, G. van Rossum, W. P. M. van Swaaij, S. R. A. Kersten, L. Lefferts, K. Seshan, Appl. Catal. B 2011, 101, 587-597.
13. C. R. Henry, Surf. Sci. Rep. 1998, 31, 235-325.
14. a) H.-J. Freund, G. Meijer, M. Scheffler, R. Schlogl, M. Wolf, Angew. Chem. 2011, 123, 10242-10275;
15. Angew. Chem. Int. Ed. 2011, 50, 10064-10094;
16. M. Bàumer, J. Libuda, K. M. Neyman, N. Rosch, G. Rupprechter, H. J. Freund, Phys. Chem. Chem. Phys. 2007, 9, 3541-3558;
17. H.-J. Freund, Surf. Sci. 2002, 500, 271-299.
18. a) J. D. Grunwaldt, C. Kiener, C. Wogerbauer, A. Baiker, J. Catal. 1999, 181, 223-232;
19. C. Copüret, M. Chabanas, R. P. Saint-Arroman, J. Basset, Angew. Chem. 2003, 115, 164-191;
20. Angew. Chem. Int. Ed. 2003, 42, 156-181;
21. M. Sterrer, H.-J. Freund, Catal. Lett. 2013, 143, 375-385.
22. D. Neves, H. Thunman, A. Matos, L. Tarelho, A. Gomez-Barea, Prog. Energy Combust. Sci. 2011, 37, 611-630.
23. a) B. M. Güell, I. Babich, K. P. Nichols, J. G. E. Gardeniers, L. Lefferts, K. Seshan, Appl. Catal. B 2009, 90, 38-44;
24. C. Rioche, S. Kulkarni, F. C. Meunier, J. P. Breen, R. Burch, Appl. Catal. B 2005, 61, 130-139.
25. C. A. Mullen, A. A. Boateng, Energy Fuels 2008, 22, 2104-2109.
26. a) G. N. Vayssilov, Y. Lykhach, A. Migani, T. Staudt, G. P. Petrova, N. Tsud, T. Skála, A. Bruix, F. Illas, K. C. Prince, V. Matolín, K. M. Neyman, J. Libuda, Nat. Mater. 2011, 10, 310-315;
27. V. Matolín, I. Matolinova, L. Sedlacek, K. C. Prince, T. Skala, Nanotechnology 2009, 20, 215706.
28. D. R. Mullins, S. D. Senanayake, T.-L. Chen, J. Phys. Chem. C 2010, 114, 17112-17119.
29. A. F. Lee, D. E. Gawthrope, N. J. Hart, K. Wilson, Surf. Sci. 2004, 548, 200-208.
30. a) T. Fuhrmann, M. Kinne, B. Trànkenschuh, C. Papp, J. F. Zhu, R. Denecke, H.-P. Steinrück, New J. Phys. 2005, 7, 107;
31. X.-L. Zhou, X.-Y. Zhu, J. M. White, Surf. Sci. 1988, 193, 387-416.
32. J. G. Wang, W. X. Li, M. Borg, J. Gustafson, A. Mikkelsen, T. M. Pedersen, E. Lundgren, J. Weissenrieder, J. Klikovits, M. Schmid, B. Hammer, J. N. Andersen, Phys. Rev. Lett. 2005, 95, 2561021-2561024.
33. a) J. Stubenrauch, E. Brosha, J. M. Vohs, Catal. Today 1996, 28, 431-441;
34. F. C. Calaza, T.-L. Chen, D. R. Mullins, S. H. Overbury, in 242nd National Meeting of the American-Chemical-Society (ACS), ACS, Denver, CO, 2011;
35. E. L. Quah, J. N. Wilson, H. Idriss, Langmuir 2010, 26, 6411-6417;
36. K. S. Kim, M. A. Barteau, J. Catal. 1990, 125, 353-375;
37. C. Xu, B. E. Koel, J. Chem. Phys. 1995, 102, 8158-8166.
38. T.-L. Chen, D. R. Mullins, J. Phys. Chem. C 2011, 115, 13725-13733.
39. a) D. R. Mullins, M. D. Robbins, J. Zhou, Surf. Sci. 2006, 600, 1547-1558;
40. V. Matolín, J. Libra, M. Škoda, N. Tsud, K. C. Prince, T. Skála, Surf. Sci. 2009, 603, 1087-1092.
41. a) A. M. da Silva, K. R. de Souza, G. Jacobs, U. M. Graham, B. H. Davis, L. V. Mattos, F. B. Noronha, Appl. Catal. B 2011, 102, 94-109;
42. J. R. Rostrup-Nielsen, J. Sehested, J. K. Norskov in Adv. Catal., Vol. 47 (Eds.: B. C. Gates, H. Knozinger), Academic Press, 2002, pp. 65-139.
43. M. Salciccioli, W. Yu, M. A. Barteau, J. G. Chen, D. G. Vlachos, J. Am. Chem. Soc. 2011, 133, 7996-8004.