Is the original Kissinger equation obsolete today?

Journal of Thermal Analysis and Calorimetry

Volumn 115, Issue 2, 2014, Pages 1961-1967

  Svoboda, Roman ^a   Málek, Jiří ^a  

^a UNIVERSITY OF PARDUBICE   (Czech Republic)

Author keywords

Complex processes; Deconvolution; Isoconversion methods; Kissinger equation

Indexed keywords

APPARENT ACTIVATION ENERGY; COMPLEX PROCESSES; ISOCONVERSION METHOD; KINETIC ANALYSIS; KISSINGER; KISSINGER EQUATION; QUALITATIVE INFORMATION;

CALORIMETRY; DECONVOLUTION; THERMAL EFFECTS; THERMOANALYSIS;

ACTIVATION ENERGY;

EID: 84893687074     PISSN: 13886150     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10973-013-3486-4     Document Type: Article

References (16)

1. Kissinger HE. Reaction kinetics in differential thermal analysis. Anal Chem. 1957;29:1702-6.
2. Friedman HL. Kinetics of thermal degradation of char-forming plastics from thermogravimetry. Application to a phenolic plastic. New York: Wiley Subscription Services, Inc., A Wiley Company; 1964.
3. Starink MJ. The determination of activation energy from linear heating rate experiments: a comparison of the accuracy of isoconversion methods. Thermochim Acta. 2003;404:163-76.
4. Vyazovkin S, Burnham AK, Criado JM, Pérez-Maqueda LA, Popescu C, Sbirrazzuoli N. ICATC Kinetics Committee recommendations for performing kinetic computations on thermal analysis data. Thermochim Acta. 2011;520:1-19.
5. Johnson WA, Mehl KF. Reaction kinetics in processes of nucleation and growth. Trans Am Inst Min (Metall) Eng. 1939;135:416-42.
6. Avrami M. Kinetics of phase change I - general theory. J Chem Phys. 1939;7:1103-12.
7. Avrami M. Kinetics of phase change. II - transformation-time relations for random distribution of nuclei. J Chem Phys. 1940;7:212-24.
8. Avrami M. Granulation, phase change, and microstructure - kinetics of phase change III. J Chem Phys. 1941;7:177-84.
9. Svoboda R, Málek J. Interpretation of crystallization kinetics results provided by DSC. Thermochim Acta. 2011;526:237-51.
10. Svoboda R, Málek J. Extended study of crystallization kinetics for Se-Te glasses. J Therm Anal Calorim. 2013;111:161-71.
11. 5 glass. J Non-Cryst Sol. 2012;358:276-84.
12. Svoboda R, Málek J. Crystallization kinetics of a-Se, part 1. Interpretation of kinetic functions. J Therm Anal Calorim. 2013;. doi: 10.1007/s10973-012-2922-1.
13. Svoboda R, Málek J. Crystallization kinetics of a-Se, part 2. Deconvolution of a complex process: the final answer. J Therm Anal Calorim. 2013;. doi: 10.1007/s10973-013-3219-8.
14. Svoboda R, Málek J. Kissinger equation versus glass transition phenomenology. J Therm Anal Cal. 2013;114:285-93.
15. Svoboda R, Málek J. Glass transition in polymers: (In)correct determination of activation energy. Polymer. 2013;54:1504-11.
16. Svoboda R, Málek J. Applicability of Fraser-Suzuki function in kinetic analysis of complex processes. J Therm Anal Cal. 2013;111:1045-56.