Synthesis and performance of cyclomatrix polyphosphazene derived from trispiro-cyclotriphosphazene as a halogen-free nonflammable material

ACS Sustainable Chemistry and Engineering

Volumn 2, Issue 2, 2014, Pages 231-238

  Sun, Jian ^a   Yu, Zhengyang ^a   Wang, Xiaodong ^a   Wu, Dezhen ^a  

^a BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY   (China)

Author keywords

Characterization; Cyclomatrix polyphosphazene; Flammability characteristics; Synthesis; Thermal stability; Trispiro cyclotriphosphazene

Indexed keywords

CHEMICAL ANALYSIS; MASS SPECTROMETRY; MICROELECTRONICS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SYNTHESIS (CHEMICAL); THERMODYNAMIC STABILITY;

31P-NMR SPECTROSCOPY; CYCLOTRIPHOSPHAZENES; DECOMPOSITION TEMPERATURE; FLAME RETARDANT PROPERTIES; FLAMMABILITY CHARACTERISTICS; LIMITING OXYGEN INDEX; MICROELECTRONIC APPLICATIONS; POLYPHOSPHAZENES;

FOURIER TRANSFORM INFRARED SPECTROSCOPY;

EID: 84893223885     PISSN: None     EISSN: 21680485     Source Type: Journal    
DOI: 10.1021/sc400283d     Document Type: Article

References (29)

1. Pecht, M.; Deng, Y. Electronic device encapsulation using red phosphorus flame retardants Microelectron. Reliab. 2006, 46, 53-62
2. Chen-Yang, Y. W.; Lee, H. F. A flame-retardant phosphate and cyclotriphosphazene-containing epoxy resin: synthesis and properties J. Polym. Sci., Part A: Polym. Chem. 2000, 38, 972-981
3. Sun, D.; Yao, Y. Synthesis of three novel phosphorus-containing flame retardants and their application in epoxy resins Polym. Degrad. Stab. 2011, 96, 1720-1724
4. Wang, X.; Song, Lei.; Xing, W.-Y.; Lu, H.-D.; Hu, Y. An effective flame retardant for epoxy resins based on poly (DOPO substituted dihydroxyl phenyl pentaerythritol diphosphonate) Mater. Chem. Phys. 2011, 125, 536-541
5. Allauddin, S.; Narayan, R.; Raju, K. V. S. N. Synthesis and properties of alkoxysilane castor oil and their polyurethane/urea-silica hybrid coating films ACS Sustainable Chem. Eng. 2013, 1 (8) 910-918
6. Gao, F.; Tong, L.; Fang, Z. Effect of a novel phosphorous-nitrogen containing intumescent flame retardant on the fire retardancy and the thermal behavior of poly(butylene terephthalate) Polym. Degrad. Stab. 2006, 91, 1295-1299
7. Shieh, J.; Wang, C. Effect of the organophosphate structure on the physical and flame-retardant properties of an epoxy resin J. Polym. Sci., Part A: Polym. Chem. 2002, 40, 369-378
8. Gao, L.; Wang, D.; Wang, Y.; Wang, J.; Yang, B. A flame-retardant epoxy resin based on a reactive phosphorus-containing monomer of DODPP and its thermal and flame-retardant properties Polym. Degrad. Stab. 2008, 93, 1308-1315
9. Allcock, H. R. A perspective of polyphosphazene research J. Inorg. Organomet. Polym. Mater. 2006, 16, 277-294
10. Allcock, H. R. New approaches to hybrid polymers that contain phosphazene rings J. Inorg. Organomet. Polym. Mater. 2007, 17, 349-360
11. Krishunamushy, S. S.; Ramachandran, K.; Murthy, A. R.; Shaw, R. A.; Woods, M. Studies of phosphazenes. Part 10. Spirocyclic derivatives of cyclotriphosphazatrienes J. Chem. Soc., Dalton Trans. 1980, 840-844
12. Kumaraswamy, S.; Vijjulatha, M.; Muthiah, C.; Kumara Swamy, K. C.; Engelhardt, U. Synthesis, reactivity and structures of spirocyclic products derived from octachlorocyclotetraphosphazene: comparison with spirocyclic cyclotriphosphazenes and linear phosphazenes J. Chem. Soc., Dalton Trans. 1999, 891-900
13. Coles, S. J.; Davies, D. B.; Eaton, R. J.; Hursthouse, M. B.; KIlIc, A.; Shaw, R. A.; Uslu, A. The structural and stereogenic properties of pentaerythritoxybridged cyclotriphosphazene derivatives: Spiro-spiro, spiro-ansa and ansa-ansa isomers Dalton Trans. 2006, 1302-1312
14. Fushimi, T.; Allcock, H. R. Synthesis and optical properties of sulfur-containing monomers and cyclomatrix polyphosphazenes Dalton Trans. 2010, 39, 5349-5355
15. Zhang, J.; Zheng, H.; Bi, Y. High energy density compounds from cyclophosphazene. II. The preparation, structural characterization, and theoretical studies of 1,1-spiro(ethylenediamino)-3,3,5,5- tetrachlorocyclotriphosphazene and its nitration product Struct. Chem. 2008, 19, 297-305
16. Bhuvan Kumar, N. N.; Kumara Swamy, K. C. Single diastereomers of unsymmetrical tris-spirocyclic cyclotriphosphazenes based on 1,10-bi-2-naphthol: Synthesis and structures Chirality 2008, 20, 781-789
17. 3 with aromatic ortho dinucleophiles Inorg. Chem. 1994, 33, 3091-3095
18. Allcock, H. R. Phosphonitrilic compounds. II. Reactions of phosphonitrilic chlorides with cathechol and triethylamine J. Am. Chem. Soc. 1964, 86, 2591-2595
19. Allcock, H. R.; Kugel, R. L. Phosphonitrilic compounds. V. Cyclized products from the reactions of hexachlorocyclotriphosphazene (phosphonitrilic chloride trimer) with aromatic dihydroxy, dithiol, and diamino compounds Inorg. Chem. 1966, 5, 1016-1020
20. Allcock, H. R.; Brennan, D. J.; Allen, R. W. Reactions between hexachlorocyclotriphosphazene and hexamethylcyclotrisiloxane: polymerization, ring cleavage, and cross-linking Macromolecules 1985, 18, 139-144
21. Campbell, T. A.; Ivanova, O. S. 3D printing of multifunctional nanocomposites Nano Today 2013, 8, 119-120
22. Gbureck, U.; Hölzel, T.; Klammert, U.; Würzler, K.; Müller, F. A.; Barrale, J. E. Resorbable dicalcium phosphate bone substitutes prepared by 3D powder printing Adv. Funct. Mater. 2007, 17, 3940-3945
23. Allcock, H. R. Recent developments in polyphosphazene materials science Curr. Opin. Solid State Mater. Sci. 2006, 10, 231-240
24. Liu, J.; Wang, X.; Wu, D. Synthesis, characterization and curing properties of a novel cyclolinear phosphazene-based epoxy resin for halogen-free flame retardancy and high performance RSC Adv. 2012, 2, 5789-5799
25. Bai, Y.; Wang, X.; Wu, D. Novel cyclolinear cyclotriphosphazene-linked epoxy resin for halogen-free fire resistance: synthesis, characterization, and flammability characteristics Ind. Eng. Chem. Res. 2012, 51, 15064-15074
26. Nie, S.; Hu, Y.; Song, L.; He, Q.; Yang, D.; Chen, H. Synergistic effect between a char forming agent (CFA) and microencapsulated ammonium polyphosphate on the thermal and flame retardant properties of polypropylene Polym. Adv. Technol. 2008, 19, 1077-1083
27. Levchik, S. V.; Weil, E. D. A review of recent progress in phosphorus-based flame retardants J. Fire Sci. 2006, 24, 345-364
28. Allcock, H. R.; Taylor, J. P. Phosphorylation of phosphazenes and its effects on thermal properties and fire retardant behavior Polym. Eng. Sci. 2000, 40, 1177-1189
29. Sun, J.; Wang, X.; Wu, D. Novel spirocyclic phosphazene-based epoxy resin for halogen-free fire resistance: synthesis, curing behaviors, and flammability Characteristics Appl. Mater. Interfaces 2012, 4, 4047-4061