Pressure dynamics in metal-oxygen (metal-air) batteries: A case study on sodium superoxide cells

Journal of Physical Chemistry C

Volumn 118, Issue 3, 2014, Pages 1461-1471

  Hartmann, Pascal ^a,c   Grübl, Daniel ^b   Sommer, Heino ^c,d   Janek, Jürgen ^a,c   Bessler, Wolfgang G ^b   Adelhelm, Philipp ^a  

^a JUSTUS LIEBIG UNIVERSITY   (Germany)

^b OFFENBURG UNIVERSITY OF APPLIED SCIENCES   (Germany)

^c KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

^d BASF SE   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTROCHEMICAL PRESSURE; ELECTROCHEMICAL REACTIONS; ELECTROLYTE SOLUTIONS; GALVANOSTATIC CYCLING; IMPEDANCE SPECTROSCOPY; MICROKINETIC MODELS; OXYGEN TRANSPORT PROPERTIES; TRIFLUOROMETHANESULFONATE;

CONTINUUM MECHANICS; CYCLIC VOLTAMMETRY; DIFFUSION; ELECTRIC DISCHARGES; ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY; ELECTRODES; ELECTROLYTES; EXPERIMENTS; FUELS; METALS; SODIUM; TRANSPORT PROPERTIES;

OXYGEN;

EID: 84893075423     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp4099478     Document Type: Article

References (25)

1. Abraham, K. M.; Jiang, Z. A Polymer Electrolyte-Based Rechargeable Lithium/Oxygen Battery J. Electrochem. Soc. 1996, 143, 1-5
2. Peled, E.; Golodnitsky, D.; Mazor, H.; Goor, M.; Avshalomov, S. Parameter Analysis of a Practical Lithium-and Sodium-air Electric Vehicle Battery J. Power Sources 2011, 196, 6835-6840
3. 2 Batteries Adv. Energy Mater. 2012, 2, 801-815
4. 2) Battery Nat. Mater. 2013, 12, 228-32
5. 2) Battery Phys. Chem. Chem. Phys. 2013, 15, 11661-11672
6. Carter, G. F.; Templeton, D. H. Polymorphism of Sodium Superoxide J. Am. Chem. Soc. 1953, 75, 5247-5249
7. 1-δO Ber. Bunsen-Ges. Phys. Chem. 1994, 98, 1213-1223
8. McCloskey, B. D.; Bethune, D. S.; Shelby, R. M.; Girishkumar, G.; Luntz, A. C. Solvents' Critical Role in Nonaqueous Lithium-Oxygen Battery Electrochemistry J. Phys. Chem. Lett. 2011, 2, 1161-1166
9. 2 Batteries J. Phys. Chem. Lett. 2012, 3, 997-1001
10. Winn, E. The Temperature Dependence of the Self-Diffusion Coefficients of Argon, Neon, Nitrogen, Oxygen, Carbon Dioxide, and Methane Phys. Rev. 1950, 80, 1024-1027
11. Bessler, W. G.; Gewies, S.; Vogler, M. A New Framework for Physically Based Modeling of Solid Oxide Fuel Cells Electrochim. Acta 2007, 53, 1782-1800
12. Neidhardt, J. P.; Fronczek, D. N.; Jahnke, T.; Danner, T.; Horstmann, B.; Bessler, W. G. A Flexible Framework for Modeling Multiple Solid, Liquid and Gaseous Phases in Batteries and Fuel Cells J. Electrochem. Soc. 2012, 159, A1528-A1542
13. Horstmann, B.; Danner, T.; Bessler, W. G. Precipitation in Aqueous Lithium-oxygen Batteries: a Model-based Analysis Energy Environ. Sci. 2013, 6, 1299-1314
14. Camper, D.; Becker, C.; Koval, C.; Noble, R. Diffusion and Solubility Measurements in Room Temperature Ionic Liquids Ind. Eng. Chem. Res. 2006, 45, 445-450
15. 2 in Room-Temperature Ionic Liquids Using a Transient Thin-Liquid-Film Method Ind. Eng. Chem. Res. 2007, 46, 8166-8175
16. Kowert, B. A.; Dang, N. C. Diffusion of Dioxygen in n-Alkanes J. Phys. Chem. A 1999, 103, 779-781
17. Read, J.; Mutolo, K.; Ervin, M.; Behl, W.; Wolfenstine, J.; Driedger, A.; Foster, D. Oxygen Transport Properties of Organic Electrolytes and Performance of Lithium/Oxygen Battery J. Electrochem. Soc. 2003, 150, A1351-A1356
18. 2 Battery Using a Lithium nitrate/N,N-dimethylacetamide Electrolyte J. Am. Chem. Soc. 2013, 135, 2076-2079
19. 2 Batteries Using Amide-Based Electrolytes J. Phys. Chem. C 2013, 117, 11977-11988
20. 2 Electrochemistry on C and Its Kinetic Overpotentials: Some Implications for Li-Air Batteries J. Phys. Chem. C 2012, 116, 23897-23905
21. 2 Battery with Alkyl Carbonate Electrolytes J. Am. Chem. Soc. 2011, 133, 8040-8047
22. 2 Cells J. Am. Chem. Soc. 2013, 135, 494-500
23. Maricle, D. L.; Hodgson, W. G. Reduction of Oxygen to Superoxide Anion in Aprotic Solvents Anal. Chem. 1965, 37, 1562-1565
24. Barsoukov, E.; Macdonald, J. R. Impedance Spectroscopy Theory, Experiment, and Application, 2 nd ed.; John Wiley & Sons: Hoboken, NJ, 2005.
25. Bessler, W. G. A New Computational Approach for SOFC Impedance from Detailed Electrochemical Reaction-diffusion Models Solid State Ionics 2005, 176, 997-1011