Kinetic study of hydrogen sulfide absorption in aqueous chlorine solution

Chemical Engineering Research and Design

Volumn 92, Issue 2, 2014, Pages 191-204

  Vilmain, Jean Baptiste ^a,c   Courousse, Valérie ^a,c   Biard, Pierre François ^a,b,c   Azizi, Mohamed ^a,c   Couvert, Annabelle ^a,c  

^a UNIV RENNES   (France)

^b UNIVERSITÉ DE RENNES 1   (France)

^c UNIVERSITÉ EUROPÉENNE DE BRETAGNE   (France)

Author keywords

Absorption; Chlorine; Hydrogen sulfide; Kinetics; Mass transfer; Scrubber

Indexed keywords

CHEMICAL ABSORPTION; GAS-LIQUID REACTORS; HYDROGEN SULFIDE ABSORPTION; HYPOCHLORITE ANION; KINETICS AND MECHANISM; MASS TRANSFER RATE; OXIDATION MECHANISMS; REACTIVE ABSORPTION;

ABSORPTION; CHLORINE; ENZYME KINETICS; GAS ABSORPTION; HYDROGEN SULFIDE; KINETICS; LIQUIDS; MASS TRANSFER; OXIDANTS; OXIDATION; REACTION KINETICS; SCRUBBERS; SULFUR DETERMINATION; WATER ABSORPTION;

DESULFURIZATION;

EID: 84893006279     PISSN: 02638762     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cherd.2013.07.015     Document Type: Article

References (54)

1. Aieta E.M., Roberts P.V. Application of mass transfer theory to the kinetics of a fast gas-liquid reaction: chlorine hydrolysis. Environ. Sci. Technol. 1986, 20:44-50.
2. Asadi Kalameh H., Karamali A., Anitescu C., Rabczuk T. High velocity impact of metal sphere on thin metallic plate using smooth particle hydrodynamics (SPH) method. Front. Struct. Civ. Eng. 2012, 6:101-110.
3. Beltrán F.J. Ozone Reaction Kinetics for Water and Wastewater Systems 2004, CRC Press, Boca Raton.
4. 2 à l'échelle du laboratoire, ENSCR 2009, 229. University of Rennes 1, Rennes.
5. Biard P.-F., Couvert A. Overview of mass transfer enhancement factor determination for acidic and basic compounds absorption in water. Chem. Eng. J. 2013, 222:444-453.
6. Biard P.-F., Couvert A., Renner C., Levasseur J.-P. Wet scrubbing intensification applied to hydrogen sulphide removal in waste water treatment plant. Can. J. Chem. Eng. 2010, 88:682-687.
7. Biard P.-F., Couvert A., Renner C., Zozor P., Bassivière S., Levasseur J.-P. Hydrogen sulphide removal in waste water treatment plant by compact oxidative scrubbing in Aquilair Plus™ process. Wat. Pract. Technol. 2009, 4. 10.2166/wpt.2009.2023.
8. Bonnin C. Les sources de nuisances olfactives dans les stations de traitement des eaux usées résiduaires, et leur traitement par lavage à l'eau chlorée en milieu basique, Ecole Nationale Supérieure de Chimie de Rennes 1991, 191. Université de Rennes I, Rennes.
9. Busca G., Chiara P. Technologies for the abatement of sulphide compounds from gaseous streams: a comparative overview. J. Loss. Prev. Proc. Indust. 2003, 16:363-371.
10. Calderbank P. Physical rate processes in industrial fermentation - Part I: the interfacial area in gas-liquid contacting with mechanical agitation. Chem. Eng. Res. Des. 1958, 36:443-463.
11. Calderbank P.H. Physical rate processes in industrial fermentation - Part II: mass transfer coefficients in gas-liquid contacting with and without mechanical agitation. Chem. Eng. Res. Des. 1959, 37:173-185.
12. Chang C.S., Rochelle G.T. Mass transfer enhanced by equilibrium reactions. Ind. Eng. Chem. Fund. 1982, 21:379-385.
13. Chao M. The diffusion coefficients of hypochlorite, hypochlorous acid, and chlorine in aqueous media by chronopotentiometry. J. Electrochem. Soc. 1968, 115:1172.
14. 2S in NaOCl caustic aqueous solution. Environ. Prog. 2001, 20:175-181.
15. Choppin A.R., Faulkenberry L.C. The oxidation of aqueous sulfide solutions by hypochlorites. J. Am. Chem. Soc. 1937, 59:2203-2207.
16. Deborde M., Von Gunten U. Reactions of chlorine with inorganic and organic compounds during water treatment - Kinetics and mechanisms. A critical review. Water Res. 2008, 42:13-51.
17. 2. Chem. Eng. Sci. 2003, 58:3589-3600.
18. Eigen M. Proton transfer, acid-base catalysis, and enzymatic hydrolysis. Part I: elementary processes. Angew. Chem. Int. Ed. Engl. 1964, 3:1-19.
19. 2O at high temperatures. J. Phys. Chem. Ref. Data 2003, 32:903-916.
20. Foussard J.-N., Debellefontaine H. Thermodynamic basis for the solubility and diffusivity of ozone in water, IOA International specialised symposium, fundamental and engineering concepts for ozone reactor design, Toulouse 2000, 35-38.
21. Gostelow P., Parsons S.A., Stuetz R.M. Odour measurements for sewage treatment works. Water Res. 2001, 35:579-597.
22. Hikita H., Asai S. Gas absorption with (m, n)th order irreversible chemical reaction. Int. Chem. Eng. 1964, 4:332-340.
23. Hoffmann A., Mackowiak J., Gorak A., Haas M., Loning J., Runowski T., Hallenberger K. Standardization of mass transfer measurements: a basis for the description of absorption processes. Chem. Eng. Res. Des. 2007, 85:40.
24. Jia Y., Zhong Q., Fan X., Wang X. Kinetics of oxidation of total sulfite in the ammonia-based wet flue gas desulfurization process. Chem. Eng. J. 2010, 164:132-138.
25. Jing G., Zhou L., Zhou Z. Characterization and kinetics of carbon dioxide absorption into aqueous tetramethylammonium glycinate solution. Chem. Eng. J. 2012, 181-182:85-92.
26. Joshi J., Pandit A., Sharma M. Mechanically agitated gas-liquid reactors. Chem. Eng. Sci. 1982, 37:813-844.
27. Kangas J., Jäppinen P., Savolainen H. Exposure to hydrogen sulfide, mercaptans and sulfur dioxide in pulp industry. AIHA J. 1984, 45:787-790.
28. Kerc A., Olmez S.S. Ozonation of odorous air in wastewater treatment plants. Ozone Sci. Eng. 2010, 32:199-203.
29. Kohl A.L., Nielsen R. Gas Purification 1997, Gulf Professional Publishing.
30. Kucka L., Kenig E.Y., Górak A. Kinetics of the gas-liquid reaction between carbon dioxide and hydroxide ions. Ind. Eng. Chem. Res. 2002, 41:5952-5957.
31. Langlais B., Reckhow D.A., Brink D.R. Ozone in Water Treatment. Chelsea, MI, United States 1991, Lewis Publishers, United States.
32. La in gas-liquid reactor. Chem. Eng. Proc. 1994, 33:247-260.
33. Le Sauze N., Laplanche A., Martin G., Paillard H. A process of washing and ozonation to deodorize an atmosphere contaminated by sulfides. Ozone Sci. Eng. 1991, 13:331-347.
34. Lee S.Y., Pang Tsui Y. Succeed at gas/liquid contacting. Chem. Eng. Prog. 1999, 95:23-49.
35. Morris J.C. Kinetics of Reactions Between Aqueous Chlorine and Nitrogen Compounds 1967, John Wiley & Sons, New York, NY.
36. Onda K., Sada E., Kobayashi T., Fujine M. Gas absorption accompanied by complex chemical reactions - III parallel chemical reactions. Chem. Eng. Sci. 1970, 25:1023-1031.
37. Perry R.H., Green D.W. Perry's Chemical Engineers' Handbook 1997, McGraw-Hill, New York. 7th ed.
38. Rappert S., Müller R. Odor compounds in waste gas emissions from agricultural operations and food industries. Waste Manag. 2005, 25:887-907.
39. Rejl J., Linek V., Moucha T., Valenz L. Methods standardization in the measurement of mass transfer characteristics in packed absorption columns. Chem. Eng. Res. Des. 2009, 87:695-704.
40. RESI Gas-liquid mass transfer in gassed mechanically agitated vessels 2013, http://www.resi.com.tw/Mixing/08DOC.pdf.
41. Roustan M. Transferts gaz-liquide dans les procédés de traitement des eaux et des effluents gazeux 2003, Lavoisier, Paris.
42. 2 absorption into aqueous solutions of blended MDEA-MEA. Chem. Eng. J. 2012, 209:501-512.
43. Smet E., Langenhove H.V. Abatement of volatile organic sulfur compounds in odorous emissions from the bio-industry. Biodegradation 1998, 9:273-284.
44. Smet E., Lens P., Langenhove H.V. Treatment of waste gases contaminated with odorous sulfur compounds. Crit. Rev. Environ. Sci. Tech. 1998, 28:89-117.
45. Sotelo J.L., Beltrán F.J., Gonzalez M., Garcia-Araya J.F. Ozonation of aqueous solutions of resorcinol and phloroglucinol. 2. Kinetic study. Ind. Eng. Chem. Res. 1991, 30:222-227.
46. Staehelin J., Hoigne J. Decomposition of ozone in water: rate of initiation by hydroxide ions and hydrogen peroxide. Environ. Sci. Technol. 1982, 16:676-681.
47. Tamimi A., Rinker E.B., Sandall O.C. Diffusion coefficients for hydrogen sulfide, carbon dioxide, and nitrous oxide in water over the temperature range 293-368K. J. Chem. Eng. Data 1994, 39:330-332.
48. 2 into aqueous blends of alkanolamines prepared from renewable resources. Chem. Eng. Sci. 2007, 62:7344-7350.
49. Vaidya P.D., Kenig E.Y. Gas-Liquid reaction kinetics: a review of determination methods. Chem. Eng. Comm. 2007, 194:1543-1565.
50. 2 absorption kinetics by aqueous solutions of N,N-diethylethanolamine and N-ethylethanolamine. Chem. Eng. Technol. 2009, 32:556-563.
51. van Swaaij W.P.M., Versteeg G.F. Mass transfer accompanied with complex reversible chemical reactions in gas-liquid systems: an overview. Chem. Eng. Sci. 1992, 47:3181-3195.
52. Wang T.X., Margerum D.W. Kinetics of reversible chlorine hydrolysis: temperature dependence and general-acid/base-assisted mechanisms. Inorg. Chem. 1994, 33:1050-1055.
53. Whitman W.G. A preliminary experimental confirmation of the two-film theory of gas absorption. Chem. Met. Eng. 1923, 29:146-148.
54. Yin H., Wu S., Ejeta M. CalSim-II Model Sensitivity Analysis Study: Technical Memorandum Report 2005, California Department of Water Resources, Bay-Delta Office.