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We note that atmospheric water can be easily incorporated in the crystal structure during mechanochemical reactions. See ref. 5b LAG refers to the mechanical reaction aided by the addition of stoichiometric amounts of solvent The bond lengths of Cu-N are 2.060(3) Å and 2.069(3) Å, whereas the bond lengths of Cu-Cl being 2.249(2) Å and 2.250(1) Å We note that the methoxyl groups of L are disordered, with the C and O atoms of each methoxyl group displaying higher thermal parameters; in addition, one methoxyl group and its attached benzene ring were refined anisotropically over two positions with the occupancies given as 0.50/0.50 The short contacts are: (Cl1⋯O5w: 3.09(1) Å; Cl2⋯O1w: 3.188(9) Å) Although it has been shown that dehydrochlorination reactions in some cases are reversible, an irreversible transformation has also been reported. See ref. 7b
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