Quasi-solid semi-interpenetrating polymer networks as electrolytes: Part I. Dependence of physicochemical characteristics and ion conduction behavior on matrix composition, cross-link density, chain length between cross-links, molecular entanglements, charge carrier concentration, and nature of anion

Journal of Physical Chemistry C

Volumn 118, Issue 1, 2014, Pages 159-174

  Bar, Nimai ^a,b,c   Ramanjaneyulu, Kota ^a,b,c   Basak, Pratyay ^a,b,c  

^a NATIONAL CHEMICAL LABORATORY   (India)

^b CSIR Network Institutes for Solar Energy (CSIR NISE)   (India)

^c ACADEMY OF SCIENTIFIC AND INNOVATIVE RESEARCH ACSIR   (India)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTROLYTE CONCENTRATION; ENERGY CONVERSION AND STORAGES; MOLECULAR ENTANGLEMENTS; PHYSICOCHEMICAL CHARACTERISTICS; POLYMER-POLYMER INTERACTION; SEMI-INTERPENETRATING POLYMER NETWORKS; SEMIINTERPENETRATING POLYMER NETWORKS (SEMI-IPNS); VOGEL-TAMMANN-FULCHER EQUATION;

CARRIER CONCENTRATION; CHAIN LENGTH; ENERGY CONVERSION; ETHERS; IONIC CONDUCTIVITY; MORPHOLOGY; NEGATIVE IONS; POLYMERS; SOLID ELECTROLYTES; SULFUR DIOXIDE; VIRTUAL STORAGE;

IONIC CONDUCTION IN SOLIDS;

EID: 84892572217     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp409533r     Document Type: Article

References (69)

1. International Energy Outlook 2009; Office of Integrated Analysis and Forecasting, U.S. Department of Energy: Washington, DC, 2009; http://www.eia.doe.gov/oiaf/ieo/index.html.
2. Lewis, N. S. Towards Cost-Effective Solar Energy Use Science 2007, 315, 798-801
3. Basic Research Needs for Solar Energy Utilization. Report of the Basic Energy Sciences Workshop on Solar Energy Utilization, April 18-21, 2005; Lewis, N. S.; Crabtree, G., Eds.; U.S. Department of Energy: Washington, DC, 2005.
4. Gratzel, M. Photoelectrochemical Cells Nature 2001, 414, 338-344
5. Alamgir, M.; Moulton, R. D.; Abraham, K. M. In Primary and Secondary Lithium Batteries. Abraham, K. M.; Salomon, M., Eds.; Electrochemical Society: Pennington, NJ, 1991.
6. Sutula, R. A.; Heitner, K. L.; Rogers, S. A.; Duong, T. Q.; Kirk, R. S.; Battaglia, V.; Henriksen, G.; McLarnon, F.; Kumar, B.; Schonefeld, C. Recent Accomplishments of the Electric and Hybrid Vehicle Energy Storage R&D Programs at the U.S. Department of Energy: A Status Report. Presented at the 17th International Electric Vehicle Symposium, Montreal, Canada, October 2000.
7. Sutula, R. A.; Heitner, K. L.; Barnes, J. A.; Duong, T. Q.; Kirk, R. S.; Battaglia, V.; Kumar, B.; Schonefeld, C. Current Status Report on U.S. Department of Energy Electric and Hybrid Electric Vehicle Energy Storage R&D Programs. Presented at the 18th International Electric Vehicle Symposium, Berlin, Germany, October 2001.
8. Fenton, D. E.; Parker, J. M.; Wright, P. V. Complexes of Alkali Metal Ions with Poly(ethylene oxide) Polymer 1973, 14, 589-589
9. Wright, P. V. Electrical conductivity in ionic complexes of poly(ethylene oxide) Br. Polym. J. 1975, 7, 319-327
10. Wright, P. V. An Anomalous Transition to a Lower Activation Energy for dc Electrical Conduction above the Glass-Transition Temperature J. Polym. Sci., Polym. Phys. Ed. 1976, 14, 955-957
11. Armand, M. B.; Chabagno, J. M.; Duclot, M. J. Extended Abstracts, Second International Conference on Solid Electrolytes, St. Andrews, Scotland, 1978.
12. Armand, M. B.; Chabagano, J. M.; Duclot, M. J. In Fast Ion Transport in Solids: Electrodes Electrolytes, Proceedings of the International Conference on Fast Ion Transport in Solids, Electrodes, and Electrolytes, Lake Geneva, WI, May 21-25, 1979; Vashishta, P.; Mundy, J. N.; Shenoy, G. K., Eds.; Elsevier/North-Holland: New York, 1979; p 131.
13. Watanabe, M.; Ogata, N. In Polymer Electrolyte Reviews; Elsiever: London, 1987.
14. Ratner, M. A. In Polymer Electrolyte Reviews-1; MacCallum, J. R.; Vincent, C. A., Eds. Elsevier Applied Science: New York, 1987; Vol. 1.
15. Ratner, M. A.; Shriver, D. F. Ion Transport in Solvent-Free Polymers Chem. Rev. 1988, 88, 109-124
16. Gray, F. M. In Solid Polymer Electrolytes-Fundamentals and Technological Applications; VCH: Weinhem, Germany, 1991.
17. Gray, F. M. Polymer Electrolytes; The Royal Society of Chemistry: Cambridge, UK, 1997.
18. Jean, Li.; Pratt, L. M.; Khan, I. M. Poly(ethylene oxide)/ Poly(2vinylpyridne)/Lithium Perchlorate Blends as Solid Polymer Electrolytes: Composition/Property/Structure Interrelationship J. Polym. Sci., Part A: Polym. Chem. 1995, 33, 1657-1663
19. Acosta, J. L.; Morales, E. Ionic Conductive Polymer Systems based on Polyether and Polyphosphazene Blends J. Appl. Polym. Sci. 1996, 60, 1185-1191
20. Leveque, M.; Le Nest, J. F.; Gandini, A.; Cheradame, H. Ionic Transport Numbers in Polyether Networks containing different Metal Salts Makromol. Chem., Rapid Commun. 1983, 4, 497-502
21. Zhang, Z.; Fang, S. J. Ionic Conductivity and Physical Stability Study of Gel Network Polymer Electrolytes J. Appl. Polym. Sci. 2000, 77, 2957-2962
22. Ichikawa, K.; Dickinson, L. C.; MacKnight, W. J.; Watanabe, M.; Ogata, N. Ionic Motions in Network Polymers Containing Lithium Perchlorate Polymer 1992, 33, 4699-4704
23. Florjanczyk, Z.; Krawiec, W.; Wieczorek, W.; Siekierski, M. Highly Conducting Solid Electrolytes based on Poly(ethylene oxide- co -propylene oxide) J. Polym. Sci., Part B: Polym. Phys. 1995, 33, 629-635
24. Allcock, H. R.; O Connor, S. J. M.; Olmeijer, D. L.; Napierala, M. E.; Cameron, C. G. Polyphosphazenes Bearing Branched and Linear Oligoethyleneoxy Side Groups as Solid Solvents for Ionic Conduction Macromolecules 1996, 29, 7544-7552
25. Kobayashi, N.; Uchiyama, M.; Shigehara, K.; Tsuchida, E. Ionically High Conductive Solid Electrolytes Composed of Graft Copolymer-Lithium Salt Hybrids J. Phys. Chem. 1985, 89, 987-991
26. Robitaille, C.; Prud'homme, J. Thermal and Mechanical Properties of a Poly(ethylene oxide- b -isoprene- b -ethylene oxide) Block Polymer Complexed with Sodium Thiocyanate Macromolecules 1983, 16, 665-671
27. Watanabe, M.; Sanui, K.; Ogata, N.; Kobayashi, T.; Ohtaki, Z. Ionic Conductivity and Mobility in Network Polymers from Poly(propylene oxide) containing Lithium Perchlorate J. Appl. Phys. 1985, 57, 123-128
28. Clericuzio, X.; Boueve, J. P.; Vicedo, T. Ambient Temperature Rechargeable Polymer-Electrolyte Batteries J. Power Sources 1993, 43, 195-208
29. Clericuzio, M.; Parker, W. O.; Soprani, J. M.; Andrieu, X. Ionic Diffusivity and Conductivity of Plasticized Polymer Electrolytes: PMFG-NMR and Complex Impedance Studies Solid State Ionics 1995, 82, 179-192
30. Alamgir, M.; Abraham, K. M. In Lithium Batteries-New Materials, Developments and Perspectives; Pistoia, G., Ed. Elsevier: Amsterdam, 1994.
31. Sheldon, M. H.; Glasse, M. D.; Lantham, R. J.; Linford, R. C. The Effect of Plasticiser on Zinc Polymer Electrolytes Solid State Ionics 1989, 34, 135-138
32. Leo, C. J.; Rao, G. V. S.; Chowdari, B. V. R. Studies on Plasticized PEO-Lithium Triflate-Ceramic Filler Composite Electrolyte System Solid State Ionics 2002, 148, 159-171
33. Kim, Y. T.; Smotkin, E. S. The Effect of Plasticizers on Transport and Electrochemical Properties of PEO-based Electrolytes for Lithium Rechargeable Batteries Solid State Ionics 2002, 149, 29-37
34. Kato, Y.; Hasumi, K.; Yokoyama, S.; Yabe, T.; Ikuta, H.; Uchimoto, Y.; Wakihara, M. Polymer Electrolyte Plasticized with PEG-Borate Ester having High Ionic Conductivity and Thermal Stability Solid State Ionics 2002, 150, 355-361
35. Basak, P.; Manorama, S. V. PEO-PU/PAN Semi-Interpenetrating Polymer Networks for SPEs: Influence of Physical Properties on the Electrical Characteristics Solid State Ionics 2004, 167, 113-121
36. Basak, P.; Manorama, S. V. Poly(ethylene oxide)-Polyurethane/ Poly(acrylonitrile) Semi-Interpenetrating Polymer Networks for Solid Polymer Electrolytes: Vibrational Spectroscopic Studies in Support of Electrical Behavior Eur. Polym. J. 2004, 40, 1155-1162
37. Basak, P.; Manorama, S. V.; Singh, R. K.; Prakash, O. Investigations on the Mechanisms of Ionic Conductivity in PEO-PU/PAN Semi-interpenetrating Polymer Network-Salt Complex Polymer Electrolytes: An Impedance Spectroscopy Study J. Phys. Chem. B 2005, 109, 1174-1182
38. 4Salt- Complexes J. Macromol. Sci., Pure Appl. Chem. 2006, A43, 369-382
39. Basak, P.; Parkash, O.; Chatterji, P. R. Solid Polymer Electrolytes: Interpenetrating Polymer Networks doped with Lithium Perchlorate J. Macromol. Sci., Pure Appl. Chem. 2001, A38 (4) 399-415
40. Ramanjaneyulu, K.; Bar, N.; Shah, Md. S. A. S.; Manorama, S. V.; Basak, P. Semi-Interpenetrating Polymer Networks as Solid Polymer Electrolytes: Effects of Ion-Dissociation, Crosslink Density and Oligomeric Entanglements on the Conductivity Behavior in Poly(ethylene oxide)-Polyurethane/Poly(acrylonitrile) Matrix J. Power Sources 2012, 217, 29-36
41. Shah, Md. S. A. S.; Basak, P.; Manorama, S. V. Polymer Nanocomposites as Solid Electrolytes: Evaluating Ion-Polymer and Polymer-Nanoparticle Interactions in PEG-PU/PAN Semi-IPNs and Titania Systems J. Phys. Chem. C 2010, 114, 14281-14289
42. Edman, L. Ion Association and Ion Solvation Effects at the Crystalline-Amorphous Phase Transition in PEO-LiTFSI J. Phys. Chem. B 2000, 104, 7254-7258
43. Wang, F. C.; Feve, M.; Lam, T. M.; Pascault, J. P. FTIR Analysis of Hydrogen Bonding in Amorphous Linear Aromatic Polyurethanes. I. Influence of Temperature J. Polym. Sci., Part B: Polym. Phys. 1994, 32, 1305-1313
44. Wang, F. C.; Feve, M.; Lam, T. M.; Pascault, J. P. FTIR Analysis of Hydrogen Bonding in Amorphous Linear Aromatic Polyurethanes. II. Influence of Styrene Solvent J. Polym. Sci., Part B: Polym. Phys. 1994, 32, 1315-1320
45. Chintapalli, S.; Zea, C.; Frech, R. Characterization Studies on High Molecular Weight PEO-Ammonium Triflate Complexes Solid State Ionics 1996, 92, 205-212
46. 2 Solutions Phys. Chem. Chem. Phys. 2004, 6, 537-542
47. Bishop, A. G.; MacFarlane, D. R.; McNaughton, D.; Forsyth, M. FT-IR Investigation of Ion Association in Plasticized Solid Polymer Electrolytes J. Phys. Chem. 1996, 100, 2237-2243
48. 2 Nanoparticles in Polymer Electrolytes: Surface Interactions Solid State Ionics 2004, 170, 73-78
49. + Ion Pairs J. Phys. Chem. A 1999, 103, 7474-7480
50. Casalbore-Miceli, G.; Yang, M. J.; Camaioni, N.; Mari, C. -M.; Li, Y.; Sun, H.; Ling, M. Investigations on the Ion Transport Mechanism in Conducting Polymer Films Solid State Ionics 2000, 131, 311-321
51. Di Noto, V. Electrical Spectroscopy Studies of Lithium and Magnesium Polymer Electrolytes Based on PEG400 J. Phys. Chem. B 2002, 106, 11139-11154
52. x Electrolytic Complexes: Studies Based on Electrical Spectroscopy J. Phys. Chem. B 2001, 105, 4584-4595
53. 2) x Polymer Electrolytes: Studies based on Electrical Spectroscopy Solid State Ionics 2002, 147, 309-316
54. 6 J. Phys. Chem. B 2000, 104, 10116-10125
55. MaCallum, J. R; Vincent, C. A. Polymer Electrolytes Reviews; Elsevier: London, 1987, (Vol 1), 1989 (Vol 2).
56. 2NH (HTFSI) J. Phys. Chem. A 1998, 102, 3249-3258
57. Kim, S. C.; Klempner, K. C.; Frisch, H. L. Polyurethane Interpenetrating Polymer Networks. II. Density and Glass Transition Behavior of Polyurethane-Poly(methyl methacrylate) and Polyurethane-Polystyrene IPN's Macromolecules 1976, 9, 263-266
58. Yenwo, G. M.; Sperling, L. H.; Pulido, J.; Manson, J. A.; Conde, A. Castor Oil based Interpenetrating Polymer Networks, IV. Mechanical Behavior Polym. Eng. Sci. 1977, 17, 251-256
59. Sperling, L. H. In Interpenetrating Polymer Networks; Klempner, D.; Sperling, L. H.; Utrachi, L. A., Eds.; Advances in Chemistry Series, American Chemical Society: Washington, DC, 1994, Vol. 239.
60. Ganaray, J. S.; Karekar, R. N.; Skaria, S.; Ranjan, C. R.; Ponratham, S. Studies on Comb-like Polymer Blend with Poly(ethylene oxide)-Lithium Perchlorate Salt Complex Electrolyte Polymer 1997, 38 (14) 3709-3712
61. Ganaraj, J. S.; Karekar, R. N.; Skaria, S.; Ponaratham, S. New Polymer Electrolyte for Solid State Lithium Batteries Bull. Electrochem. 1996, 12 (11-12) 738
62. Kim, S. J.; Park, S. J.; Kim, I. Y.; Chung, T. D.; Kim, H. C.; Kim, S. I. Thermal Characteristics of Interpenetrating Polymer Networks composed of Poly(vinyl alcohol) and Poly(N -isopropylacrylamide) J. Appl. Polym. Sci. 2003, 90, 881-885
63. Cascaval, C. N.; Rosu, D.; Ciobanu, C. Thermal Degradation of Semi-Interpenetrating Polymer Networks based on Polyurethane and Epoxy Maleate of Bisphenol A Polym. Test. 2003, 22, 45-49
64. Fainleib, A.; Kozak, N.; Grigoryeva, O.; Nizelskii, Y.; Grytesenko, V.; Pissis, P.; Boiteux, G. Structure-Thermal Property Relationships for Polycyanurate-Polyurethane linked Interpenetrating Polymer Networks Polym. Degrad. Stab. 2002, 76, 393-399
65. Neilsen, L. E. Mechanical Properties of Polymers and Composites; Marcel Dekker Inc.; NewYork, 1974; Vol 1.
66. Cowie, J. M. G.; Cree, S. H. Electrolytes Dissolved in Polymers Annu. Rev. Phys. Chem. 1989, 40, 85-113
67. Watanabe, M.; Nishimoto, A. Effects of Network Structures and Incorporated Salt Species on Electrochemical Properties of Polyether-based Polymer Electrolytes Solid State Ionics 1995, 79, 306-312
68. Cosaert, K.; Eeckhout, E.; Goethals, E.; Prez, F. D.; Guegan, P.; Cheradame, H. Poly(ethylene oxide) Containing Segmented Networks As Precursors for Ion-Conducting Solid-State Materials Polym. Int. 2002, 51, 1231-1237
69. Polymer Handbook, 3rd ed.; Brandruo, J.; Emmergut, E. H., Eds.; Wiley: New York, 1989; p. VI-72.