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Synthesis and characterization of two silver iodides with one- and three-dimensional hybrid structures constructed from Agâ̄Ag interactions and organic templates
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84892163247
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2]: C, 7.22; H, 1.26; N, 2.81%. Found 1: C, 7.20; H, 1.24; N, 2.85%
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2]: C, 7.22; H, 1.26; N, 2.81%. Found 1: C, 7.20; H, 1.24; N, 2.85%.
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22
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84892151740
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3, Z = 12, T = 298(2) K, Dc = 3.970 mg·m-3, F(000) = 10536, μ = 11.429 mm-1, 15,732 reflections measured, 1983 unique, (Rint = 0.0468) which were used in all calculations. R1 = 0.0488[I > 2σ(I)], wR2 = 0.1838 (all data) and S = 1.198. The crystallographic data sets were collected on a Bruker SMART CCD diffractometer with graphite monochromated MoKα radiation (λ = 0.71073 Å). Absorption corrections were performed by using SADABS program [23]. The structure was solved by direct method and refined by full-matrix least-squares techniques using the SHELXL-97 program [24]. Selected bond lengths (Å) and angles () for compound 1 are listed in Table S1, supporting information
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3, Z = 12, T = 298(2) K, Dc = 3.970 mg·m-3, F(000) = 10536, μ = 11.429 mm-1, 15,732 reflections measured, 1983 unique, (Rint = 0.0468) which were used in all calculations. R1 = 0.0488[I > 2σ(I)], wR2 = 0.1838 (all data) and S = 1.198. The crystallographic data sets were collected on a Bruker SMART CCD diffractometer with graphite monochromated MoKα radiation (λ = 0.71073 Å). Absorption corrections were performed by using SADABS program [23]. The structure was solved by direct method and refined by full-matrix least-squares techniques using the SHELXL-97 program [24]. Selected bond lengths (Å) and angles () for compound 1 are listed in Table S1, supporting information.
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Role of spacers and substituents in the self-assembly process: Syntheses and characterization of three novel silver(I)/iodine polymers
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