Supramolecular porphyrins as electrocatalysts

N4-Macrocyclic Metal Complexes

Volumn , Issue , 2006, Pages 255-314

  Araki, Koiti ^a   Toma, Henrique Eisi ^a  

^a UNIVERSITY OF SÃO PAULO   (Brazil)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84892113323     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1007/978-0-387-28430-9_6     Document Type: Chapter

References (214)

1. Wojaczynski, J. and L. Latos-Grazynski (2000). Poly- and oligometalloporphyrins associated through coordination. Coord. Chem. Rev. 204, 113-171.
2. Imamura, T. and K. Fukushima (2000). Self-assembly of metallopyridylporphyrin oligomers. Coord. Chem. Rev. 198, 133-156.
3. Sanders, J.K.M. (2000). Coordination chemistry of oligoporphyhrins. In K.M. Kadish, K.M. Smith, and R. Guilard (eds.), The Porphyrin Handbook. Academic Press, New York, pp. 347-368.
4. Chambron, J.C., V. Heitz, and J.P. Sauvage (2000). Non-covalent multiporphyrin assemblies. In K.M. Kadish, K.M. Smith, and R. Guilard, (eds.), The Porphyrin Handbook. Academic Press, New York, pp. 1-42.
5. Toma, H.E. and K. Araki (2000). Supramolecular assemblies of ruthenium complexes and porphyrins. Coord. Chem. Rev. 196, 307-329.
6. Toma, H.E., K. Araki, A.D.P. Alexiou, S. Nikolaou, and S. Dovidauskas (2001). Monomeric and extended oxo-centered triruthenium clusters. Coord. Chem. Rev. 219, 187-234.
7. Baldini, L. and C.A. Hunter (2000). Self-assembly of porphyrin arrays. Adv. Inorg. Chem. 53, 213-259.
8. Prodi, A., M.T. Indelli, C.J. Kleverlaan, E. Alessio, and F. Scandola (2002). Energy transfer pathways in pyridylporphyrin metal adducts and side-to-face arrays. Coord. Chem. Rev. 229, 51-58.
9. Fleischer, E.B. and A.M. Shachter (1991). Coordination oligomers and a coordination polymer of zinc tetraarylporphyrins. Inorg. Chem. 30, 3763-3769.
10. Anderson, H.L., A. Bashall, K. Henrick, M. McPartlin, and J.K.M. Sanders (1994). Crystal-structure of a supramolecular dimer formed by π-π interactions between 2 interlocked cyclic zinc porphyrin trimers. Angew. Chem. Int. Ed. Engl. 33, 429-431.
11. Anderson, S., H.L. Anderson, and J.K.M. Sanders (1995). The roles of templates in the syntheses of porphyrin oligomers. J. Chem. Soc. Perkin Trans. 1 2255-2267.
12. Anderson, H.L., S. Anderson, and J.K.M. Sanders (1995). Ligand-binding by butadiyne-linked porphyrin dimers, trimers and tetramers, J. Chem. Soc. Perkin Trans. 1 2231-2245.
13. Anderson, S., H.L. Anderson, and J.K.M. Sanders (1995). Template-directed synthesis of linear and cyclic butadiyne-linked porphyrin oligomers up to a linear octamer. J. Chem. Soc. Perkin Trans. 1 2247-2254.
14. Anderson, H.L., C.J. Walter, A. Vidalferran, R.A. Hay, P.A. Lowden, and J.K.M. Sanders (1995). Octatetrayne-linked porphyrins-stretched cyclic dimers and trimers with very spacious cavities. J. Chem. Soc. Perkin Trans. 1 2275-2279.
15. Anderson, H.L. and J.K.M. Sanders (1995). Enzyme mimics based on cyclic porphyrin oligomers-strategy, design and exploratory synthesis. J. Chem. Soc. Perkin Trans. 1 2223-2229.
16. Rempel, U., B. Vonmaltzan, and C. von Borczyskowski (1991). Picosecond timeresolved investigation of singlet energy-transfer in porphyrin hetero dimers. J. Lumin. 48-49, 415-418.
17. Rempel, U., B. Vonmaltzan, and C. von Borczyskowski (1992). Electron-transfer in self-organized porphyrin-quinone compounds on a picosecond time scale. J. Lumin. 53, 175-178.
18. Rempel, U., B. Vonmaltzan, and C. von Borczyskowski (1993). Temperature and solvent dependent charge-transfer in self-organized porphyrin-quinone compounds. Pure Appl. Chem. 65, 1681-1685.
19. Chernook, A.V., U. Rempel, C. von Borczyskowski, A.M. Shulga, and E.I. Zenkevich (1996). Formation and optical properties of self-organized pentameric porphyrin arrays. Chem. Phys. Lett. 254, 229-241.
20. Rempel, U., B. Vonmaltzan, and C. von Borczyskowski (1995). Competition between charge-transfer via superexchange and thermally activated energy-transfer in porphyrinheterodimer-quinone systems. Chem. Phys. Lett. 245. 253-261.
21. Chernook, A.V., A.M. Shulga, E.I. Zenkevich, U. Rempel, and C. von Borczyskowski (1996). Complexation and interchromophoric interactions in self-organized porphyrin and chlorin triads. J. Phys. Chem. 100, 1918-1926.
22. Zenkevich, E.I., C. von Borczyskowski, A.M. Shulga, S. Bachilo, U. Rempel, and A. Willert (2002). Self-assembled nanoscale photomimetic models: Structure and related dynamics. Chem. Phys. 275, 185-209.
23. Zenkevich, E.I., A.M. Shulga, S.M. Bachilo, U. Rempel, J. von Richthofen, and C. von Borczyskowski (1998). Energy and charge-transfer dynamics in self-organized multimolecular arrays. J. Lumin. 76-77, 354-358.
24. Willert, A., S. Bachilo, U. Rempel, A. Shulga, E. Zankevich, and C. von Borczyskowski (1999). Efficient low temperature charge transfer in a self-assembled porphyrin aggregate. J. Photochem. Photobiol. A 126, 99-109.
25. Rempel, U., S. Meyer, B. von Maltzan, and C. von Borczyskowski (1998). Energy transfer and distance independent charge separation in self-organized porphyrin- quinone aggregates. J. Lumin. 78, 97-110.
26. Michelsen, U. and C.A. Hunter (2000). Self-assembled porphyrin polymers. Angew. Chem. Int. Ed. Engl. 39, 764-767.
27. Takahashi, R. and Y. Kobuke (2003). Hexameric macroring of gable-porphyrins as a light-harvesting antenna mimic. J. Am. Chem. Soc. 125, 2372-2373.
28. Inaba, Y. and Y. Kobuke (2004). Synthesis of a complementary dimer from mono(imidazolyl)-substituted cobalt(II) porphyrin as a new artificial T-form hemoglobin. Tetrahedron 60, 3097-3107.
29. Ogawa, K. and Y. Kobuke (2000). Formation of a giant supramolecular porphyrin array by self-coordination. Angew. Chem. Int. Ed. Engl. 39, 4070-4073.
30. Kobuke, Y. and K. Ogawa (2003). Porphyrin supramolecules for artificial photosynthesis and molecular photonic/electronic materials. Bull. Chem. Soc. Jpn 76, 689-708.
31. Nagata, N., S. Kugimiya, and Y. Kobuke (2000). Antenna functions of 5, 15- bis(imidazol-4-yl)-10, 20-bis(4-dodecyloxyphenyl)-porphyrin supramolecular assembly through imidazole-imidazole hydrogen bonding. Chem. Commun. 1389-1390.
32. Nagata, N., S. Kugimiya, E. Fujiwara, and Y. Kobuke (2003). Staircase-form assembly with 5, 15-bis(imidazol-4-yl)porphinatogallium steps. New J. Chem. 27, 743-747.
33. Ikeda, C., E. Fujiwara, A. Satake, and Y. Kobuke (2003). Long rod-like array of bis(imidazolyl)porphyrinatocobalt(III) by successive complementary coordination. Chem. Commun. 616-617.
34. Kobuke, Y. and H. Miyaji (1996). Supramolecular stacks of bis(imidazolyl)porphyrin through metal coordination. Bull. Chem. Soc. Jpn 69, 3563-3569.
35. Rubtsov, I.V., Y. Kobuke, H. Miyaji, and K. Yoshihara (1999). Energy transfer in a porphyrin chelate assembly. Chem. Phys. Lett. 308, 323-328.
36. Ikeda, C., A. Satake, and Y. Kobuke (2003). Proofs of macrocyclization of gable porphyrins as mimics of photosynthetic light-harvesting complexes. Org. Lett. 5, 4935- 4938.
37. Nomoto, A. and Y. Kobuke (2002). Photocurrent generation system incorporated with antenna function. Chem. Commun. 1104-1105.
38. Kimura, A., K. Funatsu, T. Imamura, H. Kido, and Y. Sasaki (1995). Vertically Linked Ruthenium(II) Porphyrin Oligomers. Chem. Lett. 207-208.
39. Funatsu, K., A. Kimura, T. Imamura, A. Ichimura, and Y. Sasaki (1997). Perpendicularly arranged ruthenium porphyrin dimers and trimers. Inorg. Chem. 36, 1625-1635.
40. Funatsu, K., T. Imamura, A. Ichimura, and Y. Sasaki (1998). Novel cofacial ruthenium( II) porphyrin dimers and tetramers. Inorg. Chem. 37, 4986-4995.
41. Funatsu, K., T. Imamura, A. Ichimura, and Y. Sasaki (1998). Synthesis and properties of cyclic ruthenium(II) porphyrin tetramers. Inorg. Chem. 37, 1798-1804.
42. Kariya, N., T. Imamura, and Y. Sasaki (1998). Synthesis and properties of osmium(II) porphyrin oligomers linked by 3-pyridylporphyrins. Inorg. Chem. 37, 1658-1660.
43. Kariya, N., T. Imamura, and Y. Sasaki (1997). Synthesis, characterization, and spectral properties of new perpendicularly linked osmium(II) porphyrin oligomers. Inorg. Chem. 36, 833-839.
44. 2SO complexes. Chem. Commun. 12, 1411-1412.
45. Prodi, A., M.T. Indelli, C.J. Kleverlaan, F. Scandola, E. Alessio, T. Gianferrara, and L.G. Marzilli (1999). Side-to-face ruthenium porphyrin arrays: Photophysical behavior of dimeric and pentameric systems. Chem. Eur. J. 5, 2668-2679.
46. Alessio, E., S. Geremia, S. Mestroni, E. Iengo, I. Srnova, and M. Slouf (1999). Solution and solid state structure of a canted, side-to-face, bis(porphyrin) adduct. Inorg. Chem. 38, 869-875.
47. Alessio, E., S. Geremia, S. Mestroni, I. Srnova, M. Slouf, T. Gianferrara, and A. Prodi (1999). Porphyrin "flying-saucers": Solid state and solution structure of a novel pentameric array of axially-ligated canted porphyrins. Inorg. Chem. 38, 2527-2529.
48. Prodi, A., C.J. Kleverlaan, M.T. Indelli, F. Scnadola, E. Alessio, and E. Iengo (2001). Photophysics of pyridylporphyrin Ru(II) adducts: Heavy-atom effects and intramolecular decay pathways, Inorg. Chem. 40, 3498-3504.
49. Mak, C.C., N. Bampos, and J.K.M. Sanders (1999). Ru(II)-centred porphyrin pentamers as coordination building blocks for large porphyrin arrays. Chem. Commun. 1085-1086.
50. Stulz, E., S.M. Scott, A.D. Bond, S.J. Teat, and J.K.M. Sanders (2003). Selection and amplification of mixed-metal porphyrin cages from dynamic combinatorial libraries. Chem. Eur. J. 9, 6039-6048.
51. Darling, S.L., E. Stulz, N. Feeder, N. Bampos, and J.K.M. Sanders (2000). Phosphine-substituted porphyrins as supramolecular building blocks. New J. Chem. 24, 261-264.
52. Stulz, E., S.M. Scott, Y.F. Ng, A.D. Bond, S.J. Teat, S.L. Darling, N. Feeder, and J.K.M. Sanders (2003). Construction of multiporphyrin arrays using ruthenium and rhodium coordination to phosphines. Inorg. Chem. 42, 6564-6574.
53. Chichak, K. and N.R. Branda (1999). Self-assembly of a linear multicomponent porphyrin array through axial coordination. Chem. Commun. 523-524.
54. 8, which recognizes an organic-molecule in aqueous-media. J. Am. Chem. Soc. 112, 5645-5647.
55. 8 (M = Pd or Pt) as inorganic cyclophane-their ability for molecular recognition. Tetrahedron Lett. 32, 5589-5592.
56. 2+ and 4, 4'-bipyridine. Chem. Lett. 1031-1032.
57. 2+ and bis(4-pyridyl)-substituted bidentate ligands-remarkable ability for molecular recognition of electron-rich aromatic guests. J. Am. Chem. Soc. 115, 1574-1576.
58. Fujita, M., Y.J. Kwon, M. Miyazawa, and K. Ogura (1994). One-dimensional coordinate polymer involving heptacoordinate cadmium(II) ions. J. Chem. Soc. Chem. Commun. 1977-1978.
59. Fujita, M. and G. Ogura (1996). Supramolecular self-assembly of macrocycles, catenanes, and cages through coordination of pyridine-based ligands to transition metals. Bull. Chem. Soc. Jpn 69, 1471-1482.
60. Fujita, M. and K. Ogura (1996). Transition-metal-directed assembly of well-defined organic architectures possessing large voids: From macrocycles to [2]catenanes. Coord. Chem. Rev. 148, 249-264.
61. Olenyuk, B., J.A. Whiteford, A. Fechtenkotter, and P.J. Stang (1999). Self-assembly of nanoscale cuboctahedra by coordination chemistry. Nature 398, 796-799.
62. Olenyuk, B., A. Fechtenkotter, and P.J. Stang (1998). Molecular architecture of cyclic nanostructures: Use of coordination chemistry in the building of supermolecules with predefined geometric shapes. J. Chem. Soc. Dalton Trans. 1707-1728.
63. Manna, J., C.J. Kuehl, J.A. Whiteford, P.J. Stang, D.C. Muddiman, S.A. Hofstadler, and R.D. Smith (1997). Nanoscale tectonics: Self-assembly, characterization, and chemistry of a novel class of organoplatinum square macrocycles. J. Am. Chem. Soc. 119, 11611-11619.
64. Stang, P.J. and B. Olenyuk (1997). Self-assembly, symmetry, and molecular architecture: Coordination as the motif in the rational design of supramolecular metallacyclic polygons and polyhedra. Acc. Chem. Res. 30, 502-518.
65. Fan, J., J.A. Whiteford, B. Olenyuk, M.D. Levin, P.J. Stang, and E.B. Fleischer (1999). Self-assembly of porphyrin arrays via coordination to transition metal bisphosphine complexes and the unique spectral properties of the product metallacyclic ensembles. J. Am. Chem. Soc. 121, 2741-2752.
66. Slone R.V., K.D. Benkstein, S. Belanger, J.T. Hupp, I.A. Guzei, and A.L. Rheingold (1998). Luminescent transition-metal-containing cyclophanes ("molecular squares"): Covalent self-assembly, host-guest studies and preliminary nanoporous materials applications. Coord. Chem. Rev. 171, 221-243.
67. Leininger, S., B. Olenyuk, and P.J. Stang (2000). Self-assembly of discrete cyclic nanostructures mediated by transition metals. Chem. Rev. 100, 853-907.
68. Stang, P.J. (1998). Molecular architecture: Coordination as the motif in the rational design and assembly of discrete supramolecular species-Self- assembly of metallacyclic polygons and polyhedra. Chem. Eur. J. 4, 19-27.
69. Alessio, E., M. Macchi, S.L. Heath, and L.G. Marzilli (1997). Ordered supramolecular porphyrin arrays from a building block approach utilizing pyridylporphyrins and peripheral ruthenium complexes and identification of a new type of mixed-metal building block. Inorg. Chem. 36, 5614-5623.
70. Alessio, E., E. Ciani, E. Iengo, V.Y. Kukushkin, and L.G. Marzilli (2000). Stepwise assembly of unsymmetrical supramolecular arrays containing porphyrins and coordination compounds. Inorg. Chem. 39, 1434-1443.
71. Elemans, J., A.E. Rowan, and R.J.M. Nolte (2003). Mastering molecular matter. Supramolecular architectures by hierarchical self-assembly. J. Mater. Chem. 13, 2661-2670.
72. Belanger, S., M.H. Keefe, J.L. Welch, and J.T. Hupp (1999). Rapid derivatization of mesoporous thin-film materials based on Re(I) zinc-porphyrin 'molecular squares': selective modification of mesopore size and shape by binding of aromatic nitrogen donor ligands. Coord. Chem. Rev. 192, 29-45.
73. Yuan, H.P., L. Thomas, and L.K. Woo (1996). Synthesis and characterization of mono-, bis-, and tetrakis-pyridyltriarylporphyrin Pd(II) and Pt(II) supramolecular assemblies. Molecular structure of a Pd-linked bisporphyrin complex. Inorg. Chem. 35, 2808-2817.
74. Iengo, E., B. Milani, E. Zangrando, S. Geremia, and E. Alessio (2000). Novel ruthenium building blocks for the efficient modular construction of heterobimetallic molecular squares of porphyrins. Angew. Chem. Int. Ed. Engl. 39, 1096-1099.
75. Iengo, E., R. Minatel, B. Milani, L.G. Marzilli, and E. Alessio (2001). Metalmediated self-assembly of molecular squares of porphyrins rimmed with coordination compounds. Eur. J. Inorg. Chem. 609-612.
76. Iengo, E., E. Zangrando, S. Geremia, R. Graff, B. Kieffer, and E. Alessio (2002). Two-point self-coordination of a dizinc(II) bispyridylporphyrin ruthenium complex leading selectively to a discrete molecular assembly: Solution and solid-state characterization. Chem. Eur. J. 8, 4670-4674.
77. C.M. Drain, R. Fischer, E.G. Nolen, and J.M. Lehn (1993). Self-assembly of a bisporphyrin supramolecular cage induced by molecular recognition between complementary hydrogen-bonding sites. J. Chem. Soc. Chem. Commun. 243-245.
78. Drain, C.M. and J.M. Lehn (1994). Self-assembly of square multiporphyrin arrays by metal-ion coordination. J. Chem. Soc. Chem. Commun. 2313-2315.
79. Stang, P.J., J. Fan, and B. Olenyuk (1997). Molecular architecture via coordination: Self-assembly of cyclic cationic porphyrin aggregates via transition-metal bisphosphane auxiliaries. Chem. Commun. 1453-1454.
80. Belanger, S. and J.T. Hupp (1999). Porphyrin-based thin-film molecular materials with highly adjustable nanoscale porosity and permeability characteristics. Angew. Chem. Int. Ed. Engl. 38, 2222-2224.
81. Slone, R.V. and J.T. Hupp (1997). Synthesis, characterization, and preliminary host-guest binding studies of porphyrinic molecular squares featuring factricarbonylrhenium( I) chloro corners. Inorg. Chem. 36, 5422.
82. Aspley, C.J., J.R.L. Smith, R.N. Perutz, and D. Pursche (2002). Synthesis and photochemistry of free base and zinc tetraaryl porphyrins mono-substituted with tungsten pentacarbonyl via a pyridine linker. J. Chem. Soc. Dalton Trans. 170-180.
83. Drain, C.M., F. Nifiatis, A. Vasenko, and J.D. Batteas (1998). Porphyrin tessellation by design: Metal-mediated self-assembly of large arrays and tapes. Angew. Chem. Int. Ed. Engl. 37, 2344-2347.
84. Drain, C.M., J.D. Batteas, G.W. Flynn, T. Milic, N. Chi, D.G. Yablon, and H. Sommers (2002). Designing supramolecular porphyrin arrays that self-organize into nanoscale optical and magnetic materials. Proc. Natl. Acad. Sci. USA, 99, 6498- 6502.
85. Czaplewski, K.F., J.T. Hupp, and R.Q. Snurr (2001). Molecular squares as molecular sieves: Size-selective transport through porous-membrane-supported thin-film materials. Adv. Mater. 13, 1895-1897.
86. Sauvage, J.P., J.P. Collin, J.C. Chambron, S. Guillerez, C. Coudret, V. Balzani, F. Barigelletti, L. Decola, and L. Flamigni (1994). Ruthenium(II) and osmium(II) bis(terpyridine) complexes in covalently-linked multicomponent systems-synthesis, electrochemical-behavior, absorption-spectra, and photochemical and photophysical properties. Chem. Revs. 94, 993-1019.
87. Iengo, E., E. Zangrando, E. Alessio, J.C. Chambron, V. Heitz, L. Flamigni, and J.P. Sauvage (2003). A functionalized noncovalent macrocyclic multiporphyrin assembly from a dizinc(II) bis-porphyrin receptor and a free-base dipyridylporphyrin. Chem. Eur. J. 9, 5879-5887.
88. Andersson, M., M. Linke, J.C. Chambron, J. Davidsson, V. Heitz, L. Hammarstrom, and J.P. Sauvage (2002). Long-range electron transfer in porphyrin-containing 2-rotaxanes: Tuning the rate by metal cation coordination. J. Am. Chem. Soc. 124, 4347-4362.
89. Paul, D., J.A. Wytko, M. Koepf, and J. Weiss (2002). Design and synthesis of a self-assembled photochemical dyad based on selective imidazole recognition. Inorg. Chem. 41, 3699-3704.
90. Ochsenbein, P., M. Bonin, K. Schenk, J. Froidevaux, J. Wytko, E. Graf, and J. Weiss (1999). X-ray structures of a phenanthroline-strapped porphyrin and its dihydrated zinc(II) complex: Convergent distal hydrogen bonds and "CH center dot center dot center dot O" interactions. Eur. J. Inorg. Chem. 1175-1179.
91. Hungerford, G., M. van der Auweraer, and D.B. Amabilino (2001). Intramolecular fluorescence quenching in porphyrin-bearing (2)catenates. J. Porph. Phthalocyan. 5, 633-644.
92. Chambron, J.C., A. Harriman, V. Heitz, and J.P. Sauvage (1993). Effect of the spacer moiety on the rates of electron-transfer within bis-porphyrin- stoppered rotaxanes. J. Am. Chem. Soc. 115, 7419-7425.
93. Chambron, J.C., A. Harriman, V. Heitz, and J.P. Sauvage (1993). Ultrafast photoinduced electron-transfer between porphyrinic subunits within a bis(porphyrin)- stoppered rotaxane. J. Am. Chem. Soc. 115, 6109-6114.
94. Chambron, J.C., V. Heitz, J.P. Sauvage, J.L. Pierre, and D. Zurita (1995). Bisporphyrins containing diimine chelates of variable geometry as spacer. Tetrahedron Lett. 36, 9321-9324.
95. Brun, A.M., S.J. Atherton, A. Harriman, V. Heitz, and J.P. Sauvage (1992). Photophysics of entwined porphyrin conjugates-competitive exciton annihilation, energy-transfer, electron-transfer, and superexchange processes. J. Am. Chem. Soc. 114, 4632-4639.
96. Hungerford, G., M. Van der Auweraer, J.C. Chambron, V. Heitz, J.P. Sauvage, J.L. Pierre, and D. Zurita (1999). Intramolecular energy transfer in bis-porphyrins containing diimine chelates of variable geometry as spacers. Chem. Eur. J. 5, 2089-2100.
97. Tomohiro, Y., A. Satake, and Y. Kobuke (2001). Synthesis of bipyridylene-bridged bisporphyrin by nickel-mediated coupling reaction: ON-OFF control of cofacial porphyrin unit by reversible complexation. J. Org. Chem. 66, 8442-8446.
98. Sessler, J.L., V.L. Capuano, and A.K. Burrell (1993). Orthogonal Ru(bpy)3 complexes in mesosubstituted porphyrins. Inorg. Chim. Acta 204, 93-101.
99. Kus, P., G. Knerr, and L. Czuchajowski (1991). Diporphyrinyl derivatives of 1, 10- phenanthroline and 2, 2-bipyridyl. J. Heterocycl. Chem. 28, 7-11.
100. 2 -complexed 2, 2'-bipyridine spacer. J. Chem. Soc. Perkin Trans. 1 1226-1231.
101. Cheng, K.F., C.M. Drain, and K. Grohmann (2003). Porphyrins linked directly to the 5, 5- positions of 2, 2-bipyridine: A new supramolecular building block and switch. Inorg. Chem. 42, 2075-2083.
102. Collin, J.P., A. Harriman, V. Heitz, F. Odobel, and J.P. Sauvage (1994). Photoinduced electron-transfer and energy-transfer processes occurring within porphyrin-metal- bisterpyridyl conjugates. J. Am. Chem. Soc. 116, 5679-5690.
103. Harriman, A., F. Odobel, and J.-P. Sauvage (1995). Multistep electron transfer between porphyrin modules assembled around a ruthenium center. J. Am. Chem. Soc. 117, 9461-9472.
104. Collin, J.P., A. Harriman, V. Heitz, F. Odobel, and J.P. Sauvage (1996). Transition metal-assembled multiporphyrinic systems as models of photosynthetic reaction centre. Coord. Chem. Rev. 148, 63-69.
105. Flamigni, L., N. Armaroli, F. Barigelletti, V. Balzani, J.P. Collin, J.O. Dalbavie, V. Heitz, and J.P. Sauvage (1997). Photoinduced processes in dyads made of a porphyrin unit and a ruthenium complex. J. Phys. Chem. B 101, 5936-5943.
106. Flamigni, L., F. Barigelletti, N. Armaroli, J.P. Collin, J.P. Sauvage, and J.A.G. Williams (1998). Photoinduced processes in highly coupled multicomponent arrays based on a ruthenium(II)bis(terpyridine) complex and porphyrins. Chem. Eur. J. 4, 1744-1754.
107. Flamigni, L., F. Barigelletti, N. Armaroli, B. Ventura, J.P. Collin, J.P. Sauvage, and J.A.G.Williams (1999). Triplet-triplet energy transfer between porphyrins linked via a ruthenium(II) bisterpyridine complex. Inorg. Chem. 38, 661-667.
108. Flamigni, L., I.M. Dixon, J.P. Collin, and J.P. Sauvage (2000). A Zn(II) porphyrin- Ir(III) bis-terpyridine-Au(III) porphyrin triad with a charge-separated state in the microsecond range. Chem. Commun. 2479-2480.
109. Dixon, I.M., and J.P. Collin (2001). Synthesis and properties of diads based on tetraaryl porphyrins and ruthenium bis-terpyridine-type complexes. J. Porph. Phthalocyan. 5, 600-607.
110. Flamigni, L., G. Marconi, I.M. Dixon, J.P. Collin, and J.P. Sauvage (2002). Switching of electron- to energy-transfer by selective excitation of different chromophores in arrays based on porphyrins and a polypyridyl iridium complex. J. Phys. Chem. B 106, 6663-6671.
111. Uyeda, H.T., Y.X. Zhao, K. Wostyn, I. Asselberghs, K. Clays, A. Persoons, and M.J. Therien (2002). Unusual frequency dispersion effects of the nonlinear optical response in highly conjugated (polypyridyl)metal-(porphinato)zinc(II) chromophores. J. Am. Chem. Soc. 124, 13806-13813.
112. Toma, H.E. and K. Araki (1988). Spectroelectrochemical behavior of a polymetallated porphyrin. Proc. VI Braz. Symp. Electrochem. Electroanal. 183-190.
113. Toma, H.E., and K. Araki (1990). Synthesis and properties of a new polymetallated iron porphyrin. J. Chem. Res. S 82-83.
114. Araki, K., and H.E. Toma (1991). Synthesis and electrochemical-behavior of a tetrametallated cobalt porphyrin. Inorg. Chim. Acta 179, 293-296.
115. Araki, K., P.S. Santos, and H.E. Toma (1993). Electronic and resonance ramanspectra of a multibridged iron porphyrin. Spectrosc. Lett. 26, 1417-1426.
116. Collman, J.P., P. Denisevich, Y. Konai, M. Marrocco, C. Koval, and F.C. Anson (1980). Electrode catalysis of the four-electron reduction of oxygen to water by dicobalt face-to-face porphyrins. J. Am. Chem. Soc. 102, 6027-6036.
117. Collman, J.P., C.S. Bencosme, R.R. Durand, R.P. Kreh, and F.C.Anson (1983). Mixed-metal face-to-face porphyrin dimers. J. Am. Chem. Soc. 105, 2699-2703.
118. Collman, J.P., F.C. Anson, C.E. Barnes, C.S. Bencosme, T. Geiger, E.R. Evitt, R.P. Kreh, K. Meier, and R.B. Pettman (1983). Further-studies of the dimeric beta-linked face-to-face 4 porphyrin-FTF4. J. Am. Chem. Soc. 105, 2694-2699.
119. 5groups are coordinated. J. Am. Chem. Soc. 113, 9564-9570.
120. Araki, K., and H.E. Toma (1993). Synthesis and characterization of a multibridged porphyrin complex containing peripheral bis(bipyridine)- ruthenium(II) groups. J. Coord. Chem. 30, 9-17.
121. Araki, K. (1989). Preparation and Properties of New Polymetallated Porphyrins. Master. Institute of Chemistry, University of Sao Paulo.
122. Araki, K., L. Angnes, C.M.N. Azevedo, and H.E. Toma (1995). Electrochemistry of a tetraruthenated cobalt porphyrin and its use in modified electrodes as sensors of reducing analytes. J. Electroanal. Chem. 397, 205-210.
123. Araki, K., M.J. Wagner, and M.S. Wrighton (1996). Layer-by-layer growth of electrostatically assembled multilayer porphyrin films. Langmuir 12, 5393-5398.
124. Araki, K., A.L. Araujo, M.M. Toyama, M. Franco, C.M.N. Azevedo, L. Angnes, and H.E. Toma (1998). Spectroscopic and electrochemical study of a tetrapyridylporphyrin modified with four bis-(1, 10-phenanthroline) chlororuthenium(II) complexes. J. Porph. Phthalocyan. 2, 467-472.
125. Toma, H.E., K. Araki, and E.O. Silva (1998). Synthesis and characterization of a novel dodecanuclear porphyrin ruthenium cluster. Monats. Chem. 129, 975-984.
126. Winnischofer, H., S.D. Lima, K. Araki, and H.E. Toma (2003). Electrocatalytic activity of a new nanostructured polymeric tetraruthenated porphyrin film for nitrite detection. Anal. Chim. Acta 480, 97-107.
127. Araki, K., P. Losco, F.M. Engelmann, H. Winnischofer, and H.E. Toma (2001). Modulation of vectorial energy transfer in the tetrakis[tris(bipyridine) ruthenium(II)]porphyrinate zinc complex. J. Photochem. Photobiol. A 142, 25-30.
128. Winnischofer, H., F.M. Engelmann, H.E. Toma, K. Araki, and H.R. Rechenberg (2002). Acid-base and spectroscopic properties of a novel supramolecular porphyrin bonded to four pentacyanoferrate(II) groups. Inorg. Chim. Acta 338, 27-35.
129. Araki, K., H.Winnischofer, H.E.B. Viana, M.M. Toyama, F.M. Engelmann, I. Mayer, A.L.B. Formiga, and H.E. Toma (2004). Enhanced electrochemical and electrocatalytic activity of a new supramolecular manganese-porphyrin species containing four bis(bipyridine)(aqua)ruthenium(II) complexes. J. Electroanal. Chem. 562, 145-152.
130. + groups. J. Photochem. Photobiol. A 118, 11-17.
131. Lo Schiavo, S., S. Serroni, F. Puntoriero, G. Tresoldi, and P. Piraino (2002). Synthesis and characterization of dirhodium(II, II)-porphyrin-based multiredox systems. Eur. J. Inorg. Chem. 79-86.
132. + groups. J. Porph. Phthalocyan. 6, 33-42.
133. Araki, K. and H.E. Toma (1991). Spectroelectrochemical analysis of overlapping redox processes in a tetrametallated iron porphyrin. J. Electroanal. Chem. 297, 301-307.
134. Shi, C.N. and F.C. Anson (1994). Electrocatalysts for the 4-electron reduction of dioxygen based on adsorbed cobalt tetrapyridylporphyrin molecules linked by aquaamine complexes of ruthenium(II). Inorg. Chim. Acta 225, 215-227.
135. 2O by tetraruthenated cobalt meso-tetrakis(4- pyridyl)porphyrin adsorbed on graphiteelectrodes. Inorg. Chem. 31, 5078-5083.
136. Shi, C.N. and F.C. Anson (1994). Potential-dependence of the reduction of dioxygen as catalyzed by tetraruthenated cobalt tetrapyridylporphyrin. Electrochim. Acta 39, 1613-1619.
137. Shi, C.N. and F.C. Anson (1995). Comparison of the catalytic reduction of dioxygen by 5, 10, 15, 20-tetrakis((pentaammineruthenino(II))-4-pyridyl) porphyrinato cobalt(II) in solution and on graphite electrode surfaces. Inorg. Chem. 34, 4554-4561.
138. 5 centers are coordinated. Inorg. Chem. 32, 2107-2113.
139. Franco, C. and G. McLendon (1984). Bimetallic porphyrins: Synthesis and rapid intramolecular electron transfer of meso-tritolyl[N-(pentaammineruthenium) - pyridyl]porphyrin. Inorg. Chem. 23, 2370-2372.
140. Dovidauskas, S., K. Araki, and H.E. Toma (2000). Electrochemical and binding properties of a meso-tetra(4-pyridyl)porphyrinatozinc supermolecule containing four μ3-oxo-triruthenium acetate clusters. J. Porph. Phthalocyan. 4, 727-735.
141. Dovidauskas, S., H.E. Toma, K. Araki, H.C. Sacco, and Y. Iamamoto (2000). (5, 10, 15, 20-Tetra(4-pyridil)porphinato)manganes(III) acetate modified by four μ3-oxo-triruthenium acetate clusters: Synthesis, characterization, electrochemical behavior and catalytic activity. Inorg. Chim. Acta 305, 206-213.
142. 3-oxo-ruthenium acetate clusters. J. Electroanal. Chem. 498, 152-160.
143. Lo Schiavo, S., G. Pocsfalvi, S. Serroni, P. Cardiano, and P. Piraino (2000). Selfassembly of square molecular boxes containing dirhodium(II, II) units. Eur. J. Inorg. Chem. 6, 1371-1375.
144. Araki, K., P.S. Santos, L.F.C. de Oliveira, and H.E. Toma (1995). Resonance-raman spectra of a supramolecular species containing 4 ruthenium(II) bipyridine complexes attached to zinc tetrapyridyl porphynate. Spectrosc. Lett. 28, 118-126.
145. Adams, D.M., L. Brus, C.E.D. Chidsey, S. Creager, C. Creutz, C.R. Kagan, P.V. Kamat, M. Lieberman, S. Lindsay, R.A. Marcus, R.M. Metzger, M.E. Michel-Beyerle, J.R. Miller, M.D. Newton, D.R. Rolison, O. Sankey, K.S. Schanze, J. Yardley, and X. Zhu (2003). Charge transfer on the nanoscale: Current status. J. Phys. Chem. B 107, 6668-6697.
146. Araki, K. (1994).Supramolecular Properties of Polynuclear Porphyrins. PhD. Institute of Chemistry, University of Sao Paulo.
147. Araki, K. and H.E. Toma (1994). Luminescence, spectroelectrochemistry and photoelectrochemical properties of a tetraruthenated zinc porphyrin. J. Photochem. Photobiol. A Chem. 83, 245-250.
148. Araki, K. and H.E. Toma (1999). Electrochemistry of a tetraruthenated iron porphyrin and its electrostatically assembled bilayered films. Electrochim. Acta 44, 1577-1583.
149. Araki, K. and H.E. Toma (1994). Spectroelectrochemistry and electrocatalytic properties of a tetraruthenated nickel porhyrin. J. Chem. Res. (M) 1501-1515.
150. Araki, K. and H.E. Toma (1994). Spectroelectrochemistry and electrocatalytic properties of a tetraruthenated nickel porphyrin. J. Chem. Res. S 290-290.
151. Gunter, M.J. and P. Turner (1991). Metalloporphyrins as models for the cytochromes P-450. Coord. Chem. Rev. 108, 115-161.
152. Meunier, B. (1992). Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage. Chem. Rev. 92, 1411-1456.
153. Iamamoto, Y. M.D., Assis, K.J. Ciuffi, C.M.C. Prado, B.Z. Prellwitz, M. Moraes, O.R. Nascimento, and H.C. Sacco (1997). Manganese(III) porphyrins: Catalytic activity and intermediate studies in homogeneous systems. J. Mol. Catal. A: Chem. 116, 365-374.
154. Iamamoto, Y., Y.M. Idemori, and S. Nakagaki (1995). Cationic ironporphyrins as catalyst in comparative oxidation of hydrocarbons-homogeneous and supported on inorganic matrices systems. J. Mol. Cat. A 99, 187-193.
155. Groves, J.T., J.B. Lee, and S.S. Marla (1997). Detection and characterization of an oxomanganese(V) porphyrin complex by rapid-mixing stopped-flow spectrophotometry. J. Am. Chem. Soc. 119, 6269-6273.
156. Groves, J.T., S.J. Crowley, and K.V. Shalyaev (1998). Paramagnetic H-1-NMR relaxation probes of stereoselectivity in metalloporphyrin catalyzed olefin epoxidation. Chirality 10, 106-119.
157. Bedioui, F., J. Devynck, and C. Bied-Charreton (1995). Immobilization of metalloporphyrins in electropolymerized films: Design and applications. Acc. Chem. Res. 28, 30-36.
158. Groves, J.T. (2000). Reactivity and mechanisms of metalloporphyrin- catalyzed oxidations. J. Porph. Phthalocyan. 4, 350-352.
159. Mansuy, D. (1993). Activation of alkanes-the biomimetic approach. Coord. Chem. Rev. 125, 129-141.
160. Bonnet, M., L. Schmid, A. Baiker, and F. Diederich (2002). A new mesoporous hybrid material: Porphyrin-doped aerogel as a catalyst for the epoxidation of olefins. Adv. Funct. Mater. 12, 39-42.
161. Guo, C.C., J.X. Song, X.B. Chen, and G.F. Jiang (2000). A new evidence of the highvalent oxo-metal radical cation intermediate and hydrogen radical abstract mechanism in hydrocarbon hydroxylation catalyzed by metalloporphyrins. J. Mol. Cat. A 157, 31-40.
162. Schenning, A., J.H.L. Spelberg, D.H.W. Hubert, M.C. Feiters, and R.J.M. Nolte (1998). A supramolecular cytochrome P450 mimic. Chem. Eur. J. 4, 871-880.
163. Mansuy, D. and P. Battioni (2000). Diversity of reactions catalyzed by heme-thiolate proteins. In K.M. Kadish, K.M. Smith, and R. Guilard (eds), The Porphyrin Handbook. Academic Press, New York, pp. 1-15.
164. Groves, J.T., K. Shalyaev, and J. Lee (2000). Oxometalloporphyrins in oxidative catalysis. In K.M. Kadish, K.M. Smith, and R. Guilard (eds), The Porphyrin Handbook. Academic Press, New York, pp. 17-40.
165. Suslick, K.S., (2000). Shape-selective oxidation by metalloporphyrins. In K.M. Kadish, K.M. Smith, and R. Guilard (eds), The Porphyrin Handbook. Academic Press, New York, pp. 41-63.
166. Weiss, R., A. Gold, A.X. Trautwein, and J. Terner (2000). High-valent iron and manganese complexes of porphyrins and related macrocycles. In K.M. Kadish, K.M. Smith, and R. Guilard (eds), The Porphyrin Handbook. Academic Press, New York, pp. 65-96.
167. Watanabe, Y. (2000). High-valent intermediates. In K.M. Kadish, K.M. Smith, and R. Guilard (eds), The Porphyrin Handbook. Academic Press, New York, pp. 97-117.
168. Meunier, B., A. Robert, G. Pratirel, and J. Bernadou (2000). Metalloporphyrins in catalytic oxidations and oxidative DNA cleavage. In K.M. Kadish, K.M. Smith, and R. Guilard (eds), The Porphyrin Handbook. Academic Press, New York, pp. 119-187.
169. Jin, N. and J.T. Groves (1999). Unusual kinetic stability of a ground-state singlet oxomanganese(V) porphyrin. Evidence for a spin state crossing effect. J. Am. Chem. Soc. 121, 2923-2924.
170. Sorokin, A., A. Robert, and B. Meunier (1993). Intramolecular kinetic isotope effects in alkane hydroxilations catalyzed by manganese and iron porphyrin complexes. J. Am. Chem. Soc. 115, 7293-7299.
171. Merlau, M.L., W.J. Grande, S.T. Nguyen, and J.T. Hupp (2000). Enhanced activity of manganese(III) porphyrin epoxidation catalysts through supramolecular complexation. J. Mol. Cat. A 156, 79-84.
172. Belvedere, S. and R. Breslow (2001). Regioselective oxidation of steroids by a manganese porphyrin carrying metal coordinating groups. Bioorg. Chem. 29, 321-331.
173. Collman, J.P., C.J. Sunderland, and R. Boulatov (2002). Biomimetic studies of terminal oxidases: Trisimidazole picket metalloporphyrins. Inorg. Chem. 41, 2282-2291.
174. 2 reduction by synthetic monometallic Fe porphyrins. Inorg. Chem. 42, 4807-4809.
175. Collman, J.P., R. Boulatov, I.M. Shiryaeva, and C.J. Sunderland (2002). Distal Cu ion protects synthetic heme/Cu analogues of cytochrome oxidase against inhibition by CO and cyanide. Angew. Chem. Int. Ed. Engl. 41, 4139-4142.
176. 2 reduction by synthetic analogues of the heme/Cu site of cytochrome oxidase incorporated in a lipid film. Angew. Chem. Int. Ed. Engl. 41, 3487-3489.
177. Boulatov, R., J.P. Collman, I.M. Shiryaeva, and C.J. Sunderland (2002). Functional analogues of the dioxygen reduction site in cytochrome oxidase: Mechanistic aspects and possible effects of Cu-B. J. Am. Chem. Soc. 124, 11923-11935.
178. Shiryaeva, I.M., J.P. Collman, R. Boulatov, and C.J. Sunderland (2003). Nonideal electrochemical behavior of biomimetic iron porphyrins: Interfacial potential distribution across multilayer films. Anal. Chem. 75, 494-502.
179. Collman, J.P., M. Marrocco, P. Denisevich, C. Koval, and F.C. Anson (1979). Potent catalysis of the electroreduction of oxygen to water by dicobalt porphyrin dimers adsorbed on graphite-electrodes. J. Electroanal. Chem. 101, 117-122.
180. Steiger, B. and F.C. Anson (1994). New electrocatalysts for the 4-electron reduction of dioxygen based on (5, 10, 15- tris(pentaamineruthenium(II)-4-cyanophenyl)-20-(1- methylpyridinium-4-yl) porphyrinato)cobalt(II) immobilized on graphite-electrodes. Inorg. Chem. 33, 5767-5779.
181. 2. Inorg. Chem. 36, 4138-4140.
182. Anson, F.C., C.N. Shi, and B. Steiger (1997). Novel multinuclear catalysts for the electroreduction of dioxygen directly to water. Acc. Chem. Res. 30, 437-444.
183. Winnischofer, H., V.Y. Otake, S. Dovidauskas, M. Nakamura, H.E. Toma, and K. Araki (2004). Supramolecular tetracluster-cobalt porphyrin: A four electron-transfer catalyst for dioxygen reduction. Electrochim. Acta 49, 3711-3718.
184. Hutchison, J.E., T.A. Postlethwaite, C.H. Chen, K.W. Hathcock, R.S. Ingram, W. Ou, R.W. Linton, R.W. Murray, D.A. Tyvoll, L.L. Chng, and J.P. Collman (1997). Electrocatalytic activity of an immobilized cofacial diporphyrin depends on the electrode material. Langmuir 13, 2143-2148.
185. Collman, J.P., M.S. Ennis, D.A. Offord, L.L. Chng, and J.H. Griffin (1996). Electrocatalytic reduction of dioxygen by diruthenium cofacial diporphyrins axially-bound to a gold-supported, self-assembled monolayer. Inorg. Chem. 35, 1751-1752.
186. Collman, J.P., C.J. Sunderland, K.E. Berg, M.A. Vance, and E.I. Solomon (2003). Spectroscopic evidence for a heme-superoxide/Cu(I) intermediate in a functional model of cytochrome C oxidase. J. Am. Chem. Soc. 125, 6648-6649.
187. 2 with electropolymerized films of vinyl-terpyridine complexes of Fe, Ni and Co. Inorg. Chim. Acta 225, 285-295.
188. Bard, A.J. (1994). Integrated Chemical Systems. A Chemical Approach to Nanotechnology. John Wiley & Sons, Inc., New York.
189. Murray, R.W.(1984). In A.J. Bard (ed), Electroanalytical Chemistry. Marcel Dekker, New York, p. 191.
190. Murray, R.W., A.G. Ewing, and R.A. Durst (1987). Chemically modified electrodes: Molecular design for electroanalysis. Anal. Chem. 59, 379A-390A.
191. Arrigan, D.W.M. and L. Le Bihan (1999). A study of L-cysteine adsorption on gold via electrochemical desorption and copper(II) ion complexation. Analyst 124, 1645-1649.
192. Mandler, D. and I. Turyan (1996). Applications of self-assembled monolayers in electroanalytical chemistry. Electroanalysis 8, 207-213.
193. Abatti, D., M.E.D. Zaniquelli, Y. Iamamoto, and Y.M. Idemori (1997). Porphyrin LB film as a catalyst for alkene epoxidation. Thin Solid Films 310, 296-302.
194. Blair, T.L., J.R. Allen, S. Daunert, and L.G. Bachas (1993). Potentiometric and fiber optic sensors for pH based on an electropolymerized cobalt porphyrin. Anal. Chem. 65, 2155-2158.
195. Bettelheim, A., B.A. White, and R.W. Murray (1987). Electrocatalysis of dioxygen reduction in aqueous acid and base by multimolecular layer films of electropolymerized cobalt tetra(ortho-aminophenyl)porphyrin. J. Electroanal. Chem. 217, 271-286.
196. Macor, K.A., Y.O. Su, L.A. Miller, and T.G. Spiro (1987). Electrochemical and resonance raman spectroscopic characterization of polyaniline and polyaniline- metalloporphyrin electrode films. Inorg. Chem. 26, 2594-2598.
197. Daunert, S., S. Wallace, A. Florido, and L.G. Bachas (1991). Anion-selective electrodes based on electropolymerized porphyrin films. Anal. Chem. 63, 1676-1679.
198. Kliza, D.M. and M.E. Meyerhoff (1992). Potentiometric anion response of poly(tetrakis (p-aminophenyl)porphyrin film modified electrodes. Electroanalysis 4, 841-849.
199. Hayon, J., A. Raveh, and A. Bettelheim (1993). Electrocatalytic properties of chemically polymerized films of cobalt, iron and manganese tetrakis(o-aminophenyl) porphyrins. J. Electroanal. Chem. 359, 209-221.
200. Younathan, J., K.S. Wood, and T.J. Meyer (1992). Electrocatalytic reduction of nitrite and nitrosyl by iron(III) protoporphyrin-IX dimethyl ester immobilized in an electropolymerized film. Inorg. Chem. 31, 3280-3285.
201. Macor, K.A. and T.G. Spiro (1983). Porphyrin electrode films prepared by electrooxidation of metalloprotoporphyrins. J. Am. Chem. Soc. 105, 5601-5607.
202. Macor, K.A. and T.G. Spiro (1984). Oxidative electrochemistry of electropolymerized metalloporphyrin films. J. Electroanal. Chem. 163, 223-236.
203. Araki, K., L. Angnes, and H.E. Toma (1995). Rectifying properties and photoconductivity of tetraruthenated nickel porphyrin films. Adv. Materials 7, 554-559.
204. Angnes, L., C.M.N. Azevedo, K. Araki, and H.E. Toma (1996). Electrochemical detection of NADH and dopamine in flow analysis based on tetraruthenated porphyrin modified electrodes. Anal. Chim. Acta 329, 91-95.
205. Quintino, M.S.M., K. Araki, H.E. Toma, and L. Angnes (2002). Batch injection analysis utilizing modified electrodes with tetraruthenated porphyrin films for acetaminophen quantification. Electroanalysis 14, 1629-1634.
206. Azevedo, C.M.N., K. Araki, L. Angnes, and H.E. Toma (1998). Electrostatically assembled films for improving the properties of tetraruthenated porphyrin modified electrodes. Electroanalysis 10, 467-471.
207. da Rocha, J.R.C., G.J.F. Demets, M. Bertotti, K. Araki, and H.E. Toma (2002). Charge transfer at electrostatically assembled tetraruthenated porphyrin modified electrodes. J. Electroanal. Chem. 526, 69-76.
208. Kunitake, M., N. Batina, and K. Itaya (1995). Monolayers of 4-TMPyP on Au-111) surface by STM. Langmuir 11, 2337-2340.
209. Toyama, M.M., G.J.F. Demets, K. Araki, and H.E. Toma (2000). Highly conductive electrostatically assembled porphyrazine films. Electrochem. Commun. 2, 749-753.
210. Azevedo, C.M.N., K. Araki, H.E. Toma, and L. Angnes (1999). Determination of sulfur dioxide in wines by gas-diffusion flow injection analysis utilizing modified electrodes with electrostatically assembled films of tetraruthenated porphyrin. Anal. Chim. Acta 387, 175-180.
211. da Rocha, J.R.C., L. Angnes, M. Bertotti, K. Araki, and H.E. Toma (2002). Amperometric detection of nitrite and nitrate at tetraruthenated porphyrin-modified electrodes in a continuous-flow assembly. Anal. Chim. Acta 452, 23-28.
212. Fussa-Rydel, O., H.-T. Zhang, J.T. Hupp, and C.R. Leidner (1989). Electrochemical assembly of metallopolymeric films via reaction of coordinated 5-chlorophenanthroline. Inorg. Chem. 28, 1533-1537.
213. 2 by supramolecules containing zinc porphyrins and ruthenium-polypyridyl complexes. Inorg. Chem. 43, 396-398.
214. 2 films. Photochem. Photobiol. Sci. 3, 56-62.