Non-noble electrocatalysts for the PEM fuel cell oxygen reduction reaction

PEM Fuel Cell Electrocatalysts and Catalyst Layers: Fundamentals and Applications

Volumn , Issue , 2008, Pages 715-757

  Lee, Kunchan ^a   Zhang, Lei ^a   Zhang, Jiujun ^a  

^a NATIONAL RESEARCH COUNCIL CANADA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84892070053     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1007/978-1-84800-936-3_15     Document Type: Chapter

References (168)

1. Larminie J, Dick A. Fuel cell systems explained. New York: John Wiley & Sons Ltd; 2000.
2. Arita M. Technical issues of fuel cells systems for automotive application. Fuel Cells 2002;2:10-14.
3. Sato N. Environmental science and energy technologies of automotive engineering in the 21st century. Oyo Butsuri 2003;72:857-64.
4. Gasteiger HA, Kocha SS, Sompalli B, Wagner FT. Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs. Appl Catal B 2005;56:9-35.
5. Kinoshita K. Electrochemical oxygen technology. New York: John Wiley & Sons Ltd, 1992:1-112.
6. Zhang L, Zhang J, Wilkinson DP, Wang H. Progress in preparation of non-noble electrocatalysts for PEM fuel cell reactions. J Power Sources 2006;156:171-82.
7. Bezerra CWB, Zhang L, Liu H, Lee K, Marques ALB, Marques EP, et al. A review of heat-treatment effects on activity and stability of PEM fuel cell catalysts for oxygen reduction reaction. J Power Sources 2007;173:891-908.
8. Jasinski R. A new fuel cell cathode catalyst. Nature 1964;201:1212-13.
9. Zagal JH. Macrocycles. In: Vielstich W, Gasteiger HA, editors. Handbook of fuel cells-fundamental, technology and applications, volume 2. New York: John Wiley & Sons Ltd, 2003;37:544-54.
10. Beck F. The redox mechanism of the chelate-catalysed oxygen cathode. J Appl Electrochem 1977;7:239-45.
11. Zagal JH. Metallophthalocyanines as catalysts in electrochemical reactions. Coord Chem Rev 1992;119:89-136.
12. 4 macrocycles as electrocatalysts for the cathodic reduction of oxygen. Mater Chem Phys 1989;22:457-75.
13. Alt H, Binder M, Sandstede G. Mechanism of the electrocatalytic reduction of oxygen on metal chelates. J Catal 1973;28:8-19.
14. Jiang R, Xu L, Jin R, Dong S. Chemically modified electrode XI: Preparation and stability of metallotetraphenylporphyrin adsorbed on glassy carbon electrode. Fenxi Huaxue 1985;13:270-75.
15. Durand RR, Bencosme CS, Collman JP, Anson FC. Mechanistic aspects of the catalytic reduction of dioxygen by cofacial metalloporphyrins. J Am Chem Soc 1983;105:2710-18.
16. Chang CK, Liu HY, Abdalmuhdai I. Mechanistic aspects of the catalytic reduction of dioxygen by cofacial diporphyrin catalysts. J Am Chem Soc 1984;106:2725-6.
17. van der Putten A, Elzing A, Visscher W, Barendrecht E, Harcourt RD. Increased valence theory and the four electron reduction of molecular oxygen to water. J Mol Struct (Thermochem) 1988;180:309-18.
18. Oyama N, Anson FC. Catalysis of electrode processes by multiply-charged metal complexes electrostatically bound to polyelectrolyte coatings on graphite electrodes, and the use of polymer-coated rotating disk electrodes in diagnosing kinetic and conduction mechanisms. Anal Chem 1980;52:1192-8.
19. Collman JP, Denisevich P, Konai Y, Marrocco M, Koval C, Anson FC. Electrode catalysis of the four-electron reduction of oxygen to water by dicobalt face-to-face porphyrins. J Am Chem Soc 1980;102:6027-36.
20. Chu D, Jiang R. Novel electrocatalysts for direct methanol fuel cells. Solid State Ionics 2002;148:591-9.
21. Biloul A, Contamin O, Scarbeck G, Savy M, Palys B, Riga J, et al. Oxygen reduction in acid media: influence of the activity of CoNPc(1,2) bilayer deposits in relation to their attachment to the carbon black support and role of surface groups as a function of heat treatment. J Electroanal Chem 1994;365:239-46.
22. Matter PH, Ozkan US. Non-metal catalysts for dioxygen reduction in an acidic electrolyte. Catal Lett 2006;109:115-23.
23. Drazic DM, Ledinski ZV, Zecevic SK. Transition metal catalysts for porous carbon air-electrodes in neutral chloride electrolytes. J Appl Electrochem 1983;13:337-40.
24. Li J, Wu X, Yuan R, Lin H, Yu R. Cobalt phthalocyanine derivatives as neutral carriers for nitrite-sensitive poly(vinyl chloride) membrane electrodes. The Analyst 1994;119:1363-6.
25. Castellani AM, Gonclaves JE, Gushiken Y. The use of carbon paste electrodes modified with cobalt tetrasulfonated phthalocyanine adsorbed in silica/titania for the reduction of oxygen. J New Mater Electrochem Syst 2002;5:169-72.
26. Jahnke H, Schonbron M, Zimmerman G. Organic Dyestuffs as catalysts for fuel cells. Top Curr Chem 1976;61:133-81.
27. Kretzschmar C, Wiesiner K. Study of the operation of tungsten carbide anode and iron phthalocyanine cathodes in fuel cells with a sulphuric acid electrolyte. Elektrokhimiya 1978;14:1330-4.
28. Biloul A, Gouerec P, Savy M, Scarbeck G, Besse S, Riga J. Oxygen electrocatalysis under fuel cell conditions: behaviour of cobalt porphyrins and tetraazaannulene analogues. J Appl Electrochem 1996;26:1139-46.
29. Zhong W, Dong X, Chen S, Lin W. A new non-noble metal electro-catalyst for the reduction of oxygen. Battery Bimonthly 2003;33:245-8.
30. Faubert G, Lalande G, Cote R, Guay D, Dodelet JP, Weng LT, et al. Heat-treated iron and cobalt tetraphenylporphyrins adsorbed on carbon black: Physical characterization and catalytic properties of these materials for the reduction of oxygen in polymer electrolyte fuel cells. Electrochim Acta 1996;41:1689-701.
31. Lalande G, Cote R, Tamizhmani G, Guay D, Dodelet JP, Dignard-Bailey L, et al. Physical, chemical and electrochemical characterization of heat-treated characterization of heat-treated tetracarboxylic cobalt phthalocyanine adsorbed on carbon black as electrocatalyst for oxygen reduction in polymer electrolyte fuel cells. Electrochim Acta 1995;40:2635-46.
32. Bron M, Fiechter S, Hilgendorff M, Bogdanoff P. Catalysts for oxygen reduction from heat-treated carbon-supported iron phenantroline complexes. J Appl Electrochem 2002;32:211-16.
33. Iliev I, Gamburtsev S, Kaisheva A. Optimization of the pyrolysis temperature of carbon-CoTMPP catalysts for air electrodes in alkaline media. J Power Sources 1986;17:345-52.
34. Vasudevan P, Santosh, Mann N, Tyagi S. Transition metal complexes of porphyrins and phthalocyanines as electrocatalysts for dioxygen reduction. Transition Met Chem 1990;15:81-90.
35. van Veen JAR, Colijin HA, van Baar JF. On the effect of a heat treatment on the structure of carbon-supported metalloporphyrins and phthalocyanines. Electrochim Acta 1988;33:801-4.
36. Weng LT, Bertrand P, Lalande G. Surface characterization by time-of-flight SIMS of a catalyst for oxygen electroreduction: pyrolyzed cobalt phtholcyanine-on-carbon black. Appl Surf Sci 1995;84:9-21.
37. Bae IT, Tryk DA, Scherson DA. Effect of heat treatment on the redox properties of iron porphyrins adsorbed on high area carbon in acid electrolytes: An in Situ Fe K-Edge X-ray Absorption Near-Edge Structure Study. J Phys Chem B 1998;102:4114-17.
38. 2 reduction in PEM fuel cells: Activity and active site structural information for catalysts obtained by the pyrolysis at high temperature of Fe precursors. J Phys Chem B 2000;104:11238-47.
39. Bogdanoff P, Herrmann I, Hilgendorff M Dorbandt I, Fiechter S, Tributsch H. Probing structural effects of pyrolysed CoTMPP-based electrocatalysts for oxygen reduction via new preparation strategies. J New Mater Electrochem Syst 2004;7:85-92.
40. Bouwkamp AL, Visscher W, Veen JA. Electrochemical reduction of oxygen: an alternative method to prepare active CoN4 catalysts. Electrochim Acta 1999;45:379-86.
41. Faubert G, Cote R, Guay D, Dodelet JP, Denes G, Poleunis C, et al. Activation and characterization of Fe-based catalysts for the reduction of oxygen in polymer electrolyte fuel cells. Electrochim Acta 1998;43:1969-84.
42. Gupta S, Tryk D, Bae I, Aldred W, Yeager E. Heat-treated polyacrylonitrile-based catalysts for oxygen electroreduction. J Appl Electrochem 1989;19:19-27.
43. Fournier J, Lalande G, Cote R, Guay D, Dodelet JP. Activation of various Fe-based precursors on carbon black and graphite supports to obtain catalysts for the reduction of oxygen in fuel cells. J Electrochem Soc 1997;144:218-226.
44. Ohms D, Herzog S, Franke R, Neumann V, Wiesener K. Influence of metal ions on the electrocatalytic oxygen reduction of carbon materials prepared from pyrolyzed polyacrylonitrile. J Power Sources 1992;38:327-34.
45. Lalande G, Cotre R, Duay D, Dodelet JP, Weng LT, Bertrand P. Is nitrogen important in the formulation of Fe-based catalysts for oxygen reduction in solid polymer fuel cells? Electrochim Acta 1997;42:1379-88.
46. Martin Alves MC, Tourillon G. Influence of complexation processes on the catalytic properties of some polymer-based cobalt compounds for oxygen electroreduction. J Phys Chem 1996;100:7566-72.
47. Sirk AHC, Campbell SA, Birss VI. Oxygen reduction by sol derived Co, N, C, Obased catalysts for use in proton exchange membrane fuel cells. Electrochemical and Solid-State Letters 2005;8:A104-7.
48. He P, Lefevre M, Faubert G, Dodelet JP. Oxygen reduction catalysts for polymer electrolyte fuel cells from the pyrolysis of various transition metal acetates adsorbed on 3,4,9,10-perylenetetracarboxylic dianhydride. J New Mater Electrochem Syst 1999;2:243-51.
49. Wei G, Wainright JS, Savinell RF. Catalytic activity for oxygen reduction reaction of catalysts consisting of carbon, nitrogen and cobalt. J New Mater Electrochem Syst 2000;3:121-29.
50. Wang H, Cote R, Faubert G, Guay D, Dodelet JP. Effect of the pre-treatment of carbon black supports on the activity of Fe-based electrocatalysts for the reduction of oxygen. J Phys Chem B 1999;103:2042-9.
51. Jaouen F, Marcotte S, Dodelet JP, Lindbergh G. Oxygen reduction catalysts for polymer electrolyte fuel cells from the pyrolysis of iron acetate adsorbed on various carbon supports. J Phys Chem B 2003;107:1376-86.
52. Lalande G, Tamizhmani G, Cote R, Dignard-Bailey L, Trudeau ML, Schulz R, et al. Influence of loading on the activity and stability of heat-treated carbon-supported cobalt phthalocyanine electrocatalysts in solid polymer electrolyte fuel cells. J Electrochem Soc 1995;142:1162-8.
53. 2+ acetate adsorbed 3,4,9, loperylenetetracarboxylic dianhydride. Electrochim Acta 1999;44:2589-603.
54. Tamizhmani G, Dodelet JP, Guay D, Lalande G, Capuano GA. Electrocatalytic activity of nafion-lmpregnated pyrolyzed cobalt phthalocyanine. J Electrochem Soc 1994;141:41-5.
55. van der Putten A, Elzing A, Visscher W, Barendrecht E. Oxygen reduction on pyrolysed carbon-supported transition metal chelates. J Electroanal Chem 1986;205:233-44.
56. Ye S, Vijh AK. Non-noble metal-carbonized aerogel composites as electrocatalysts for the oxygen reduction reaction. Electrochem Commun 2004;5:272-5.
57. Liu H, Song C, Tang Y, Zhang J. High-surface-area CoTMPP/C synthesized by ultrasonic spray pyrolysis for PEM fuel cell electrocatalysts. Electrochim Acta 2007;52:4532-8.
58. Bashyam R, Zelenay P. A class of non-precious metal composite catalysts for fuel cells. 2006;443:63-6.
59. Mazza F, Trassatti S. Tungsten, titanium, and tantalum carbides and titanium nitrides as electrodes in redox systems. J Electrochem Soc 1963;110:847-9.
60. Binder H, Kohling A, Kuhn W, Lindner W, Sandstede G. Tungsten carbide electrodes for fuel cells with acid electrolyte. Nature 1969;224:1299-300.
61. Bennett LH, Cuthill JR, McAlister AJ, Erickson NE. Electronic structure and catalytic behavior of tungsten carbide. Science 1974;184:56365.
62. Ross PN Jr, Stonehart P. Surface characterization of catalytically active tungsten carbide (WC). J Catal 1975;39:298-301.
63. Colton RJ, Huang JTJ, Rabalais JW. Electronic structure of tungsten carbide and its catalytic behavior. Chem Phys Lett 1975;34:337-9.
64. Voinov M, Buhler D, Tannenberger H. Oxygen reduction on tungsten carbide. J Electrochem Soc 1971;118:1137-8.
65. Levy RB, Boudart M. Platinum-like behavior of tungsten carbide in surface catalysis. Science 1973;181:547-9.
66. Bohm H. Adsorption und anodische oxydation von wasserstoff an wolframcarbid. Electrochim Acta 1970;15:1273-80.
67. Ross PN Jr, Stonehart P. The relation of surface structure to the electrocatalytic activity of tungsten carbide. J Catal 1977;48:42-59.
68. Sokolsky DV, Palanker VS, Baybatyrov EN. Electrochemical hydrogen reactions on tungsten carbide. Electrochim Acta 1975;20:71-7.
69. Zoltowski P. The mechanism of the activation process of the tungsten carbide electrode. Electrochim Acta 1986;31:103-11.
70. Okamoto H, Kawamura G, Ishikawa A, Kudo T. Activation of (W, Mo)C methanol anodic oxidation catalysts using alkaline solution. J Electrochem Soc 1987;134:1649-53.
71. x thin films by RF sputtering and their electrocatalytic property for anodic methanol oxidation. J Electrochem Soc 1990;137:871-6.
72. Bonoel G, Musuex E, Lelercq L, Tassin N. Study of hydrogen oxidation on carbides. Electrochim Acta 1991;36:1543-7.
73. McIntyre DR, Burstein GT, Vossen A. Effect of carbon monoxide on the electrooxidation of hydrogen by tungsten carbide. J Power Sources 2002;107:67-73.
74. Vijh AK, Jacques R, Belanger G. The electrochemical reduction of oxygen on cobaltcemented tungsten carbide. J Power Sources 1983;9:1-10.
75. Lee K, Ishihara A, Mitsushima S, Kamiya N, Ota KI. Stability and electrocatalytic activity for oxygen reduction in WC+Ta catalyst. Electrochim Acta 2004;49:3479-85.
76. Lee K, Ishihara A, Mitsushima S, Kamiya N, Ota KI. Transition metal carbides for new cathode material of polymer electrolyte fuel cell. Electrochemical Society Proceeding Volume 2004-21, Proton Conducting Membrane Fuel Cells IV, 2004;213-20.
77. McIntyre DR, Vossen A, Wilde JR, Burstein GT. Electrocatalytic properties of a nickel-tantalum-carbon alloy in an acidic electrolyte. J Power Sources 2002;108:1-7.
78. Yang R, Bonakdarpour A, Dhan Jr. Investigation of sputtered Ta-Ni-C as an electrocatalyst for the oxygen reduction reaction. J Electrochem Soc 2007;154:B1-7.
79. Giner J, Swette L. Oxygen reduction on titanium nitride in alkaline electrolyte. Nature 1966;211:1291-2.
80. Azuma M, Kashihara M, Nakato Y, Tsubomura H. Reduction of oxygen to water on cobalt-nitride thin film electrodes prepared by the reactive RF sputtering technique. J Electroanal Chem 1988;250:73-82.
81. Zhong H, Zhang H, Liu G, Liang Y, Hu J, Yi B. A novel non-noble electrocatalyst for PEM fuel cell based on molybdenum nitride. Electrochem Commun 2006;8:707-12.
82. Zhong H, Zhang H, Liang Y, Zhang J, Wang M, Wang X. A novel non-noble electrocatalyst for oxygen reduction in proton exchange membrane fuel cells. J Power Sources 2007;164:572-7.
83. 2N(100) surface: Formation of NdCdO species? A density functional study. J Phys Chem B 2000;104:11972-11976.
84. Ishihara A, Lee K, Doi S, Mitsushima S, Kamiya N, Hara M, et al. Tantalum oxynitride for a novel cathode of PEFC. Electrochemical and Solid-State Letters 2005;8:A201-3.
85. Yato K, Doi S, Ishihara A, Mitsushima S, Kamiya N, Ota KI. Effect of heat treatment of titanium oxynitride as platinum-free electrocatalyst on oxygen reduction reaction. Suiso Enerugi Shisutemu 2006;31:58-65.
86. Doi S, Ishihara A, Mitsushima S, Kamiya N, Ota KI. Zirconium-based compounds for cathode of polymer electrolyte fuel cell. J Electrochem Soc 2007;154:B362-9.
87. Doi S, Liu Y, Ishihara A, Mitsushima S, Kamiya N, Ota K. Zirconium nitride and oxynitride for new cathode of polymer electrolyte fuel cell. ECS Transactions 2006;1:17-25.
88. Ishihara A, Doi S, Liu Y, Mitsushima S, Kamiya N, Ota K. Tantalum nitride and oxynitride for new cathode of polymer electrolyte fuel cell. ECS Transactions 2006;1:51-60.
89. Lee K. Ph.D dissertation, Yokohama National University, 2004.
90. Kim JH, Ishihara A, Mitsushima S, Kamiya N, Ota KI. Catalytic activity of titanium oxide for oxygen reduction reaction as a non-platinum catalyst for PEFC. Electrochim Acta 2007;52:2492-7.
91. Domen K. Report code number 100010143. New Energy and Industrial Technology Development Organization (NEDO), Strategic development of PEFC technologies for practical application, development of technology for next-generation fuel cells, development of alternative(low-cost) precious metal catalyst, FY 2005-2006 progress reports;2007. Available from: http://www.tech.nedo.go.jp/servlet/TopPageServlet?KENSAKU=HOKOKUSYO& kensakuHoho=Barcode-Kensaku&db=n&SERCHBARCODE=100010143.
92. Kim JH, Ishihara A, Mitsushima S, Kamiya N, Ota KI. Oxygen reduction reaction of Ta-C-N prepared by reactive sputtering with heat treatment. Electrochemistry 2007;75:166-8.
93. Kim JH, Ishihara A, Mitsushima S, Kamiya N, Ota KI. New non-platinum cathode based on chromium for PEFC. Chem Lett 2007;36:514-15.
94. Easton EB, Bonakdarpour A, Dahn Jr. Fe-C-N oxygen reduction catalysts prepared by combinatorial sputter deposition. Electrochemical and Solid-State Letters 2006;9:A463-7.
95. Yang R, Bonakdarpour A, Easton EB, Stoffyn-Egli P, Dahn Jr. Co-C-N oxygen reduction catalysts prepared by combinatorial magnetron sputter deposition. J Electrochem Soc 2007;154:A275-82.
96. Yang R, Stevens K, Bonakdarpour A, Dahn Jr. Dependence of the activity of sputtered Co-C-N oxygen reduction electrocatalysts on heat-treatment temperature. J Electrochem Soc 2007;154:B893-901.
97. Atanasoski R. Novel approach to non-precious metal cataysts. DOE hydrogen program, FY 2007 Annual progress report;2007;820-24. Available from: http://www.hydrogen.energy.gov/pdfs/progress07/v-e-1-atanasoski.pdf
98. Alonso-Vante N, Tributsch H. Energy conversion catalysis using semiconducting transition metal cluster compounds. Nature 1986;323:431-2.
99. Alonso-Vante N. Chevrel phases and chalcogenides. In: Vielstich W, Gasteiger HA, editors. Handbook of fuel cells-fundamental, technology and applications, volume 2. New York: John Wiley & Sons Ltd; 2003;36:534-43.
100. Lee K, Zhang L, Zhang J. A novel methanol-tolerant Ir-Se chalcogenide electrocatalyst for oxygen reduction. J Power Sources 2007;165:108-13.
101. Gochi-Ponce Y, Alonso-Nunez G, Alonso-Vante N. Synthesis and electrochemical characterization of a novel platinum chalcogenide electrocatalyst with an enhanced tolerance to methanol in the oxygen reduction reaction. Electrochem Commun 2006;8:1487-91.
102. Reeve RW, Christensen PA, Hamnett A, Haydock SA, Roy SC. Methanol tolerant oxygen reduction catalysts based on transition metal sulfides. J Electrochem Soc 1998;145:3463-3471.
103. Fischer C, Alonso-Vante N, Fiechter S, Tributsch H. Electrocatalytic properties of mixed transition metal tellurides (Chevrel-phases) for oxygen reduction. J Appl Electrochem 1995;25:1004-8.
104. Baresel VD, Sarholz W, Scharner P, Schmitz. Transition metal chalcogenides as oxygen catalysts for fuel cells. Ber Bunsen-Ges Phys Chem 1974;78:608-11.
105. Behret H, Binder H, Sandstede G. Electrocatalytic oxygen reduction with thiospinels and other sulphides of transition metals. Electrochim Acta 1973;20:111-17.
106. Behret H, Binder H, Clauberg W, Sandstede G. Comparison of the reaction mechanisms of electrocatalytic oxygen reduction using transition metal thiospinels and chelates. Electrochim Acta 1978;23:1023-9.
107. Campbell S. Development of transition metal/chalcogen based cathode catalysts for PEM fuel cells. DOE hydrogen program, FY 2004 annual progress report 2004:389-91;
108. FY 2005 annual progress report 2005:850-53;
109. FY 2006 annual progress report 2006:799-803;
110. FY 2007 annual merit review proceedings 2007:FC6. Available from: http://www.hydrogen.energy.gov/annual-progress.html.
111. 2: Quantum chemistry predictions. J Phys Chem B 2006;110:936-41.
112. Susac D, Sode A, Zhu L, Wong PC, Teo M, Bizzotto D, et al. A methodology for investigating new nonprecious metal catalysts for PEM fuel cells. J Phys Chem B 2006;110:10762-70.
113. Lee K, Zhang L, Zhang J. Ternary non-noble metal chalcogenide (W-Co-Se) as electrocatalyst for oxygen reduction reaction. Electrochem Commun 2007;9:1704-8.
114. Brenet JP. Electrochemical behaviour of metallic oxides. J Power Sources 1979;4:183-90.
115. Seiyama T, Yamazoe N. Perovskite-type oxides and their applicability to catalysis: properties in relation to the defect structure. Kagaku 1982;37:314-16.
116. Arai H. Current status and future prospect for catalyst technology. Shokubai 1988;30:598-602.
117. Yamazoe N, Teraoka Y. Oxide catalysts. Kikan Kagaku Sosetsu 1988;3:36-43.
118. Yamazoe N, Teraoka Y. Oxidation Catalysis of perovskites-relationships to bulk structure and composition (valency, defect, etc.). Catal Today 1990;8:175-99.
119. Klissurski D, Uzunova E. Review synthesis and features of binary cobalite spinels. J Mater Sci 1994;29:285-93.
120. Yasuda H, Misono M. Catalysis of perovskite. Kikan Kagaku Sosetsu 1997;32:149-58.
121. Roberts GL. A review of mixed-transition metal oxides as potential bifunctional electrode. Reviews in Process Chemistry and Engineering 2000;3:151-74.
122. Pena MA, Fierro JLG. Chemical structures and performance of perovskite oxides. Chem Rev 2001;101:1981-2017.
123. 3 in an aqueous alkaline solution. J Electrochem Soc 1975;122:159-63.
124. 3 (Ln=lanthanoid, M=calcium, strontium, and barium). Electrochemistry 1976;44:503-7.
125. Kudo T, Obayashi H, Yoshida M. Rare earth cobaltites as oxygen electrode materials for alkaline solution. J Electrochem Soc 1977;124:321-5.
126. 3 (A=Na, K. Rb) in concentrated alkaline solution. Electrochemistry 2000;68:112-18.
127. Hyodo T, Hayashi M, Miura N, Yamazoe N. Catalytic activities of rare-earth manganites for cathodic reduction of oxygen in alkaline solution. J Electrochem Soc 1996;143:L266-7.
128. 2. J Solid State Chem 1975;14:395-406.
129. Klissurski D, Uzunova E. Review synthesis and features of binary cobalite spinels. J Mater Sci 1994;29:285-93.
130. Wen TC, Kang HM. Co-Ni-Cu ternary spinel oxide-coated electrodes for oxygen evolution in alkaline solution. Electrochim Acta 1998;43:1729-45.
131. Trasatti S. Electrocatalysis in the anodic evolution of oxygen and chlorine. Electrochim Acta 1984;29:1503-12.
132. 4 (0 < x < 1.8) en milieu legerement acide. J Appl Electrochem 1977;7:383-93.
133. 4+ en sites ocatedriques. J Appl Electrochem 1977;7:395-406.
134. 4. J Appl Electrochem 1980;10:433-9.
135. Parkinson B, Decker F, Juliao JF, Abramovich M, Chagas HC. The reduction of molecular oxygen at single crystal rutile electrodes. Electrochim Acta 1980;25:521-5.
136. Mentus SV. Oxygen reduction on anodically formed titanium dioxide. Electrochim Acta 2004;50:27-32.
137. Baez VB, Graves JE, Pletcher D. The reduction of oxygen on titanium oxide electrodes. J Electroanal Chem 1992;340:273-86.
138. Liu Y, Ishihara A, Mitsushima S, Kamiya N, Ota KI. Zirconium oxide for PEFC cathodes. Electrochemical and Solid-State Letters 2005;8:A400-2.
139. Liu Y, Ishihara A, Mitsushima S, Kamiya N, Ota KI. Transition metal oxides as DMFC cathodes without platinum. J Electrochem Soc 2007;154:B664-9.
140. 3-x of oxygen reduction in alkaline solution. Electrochemistry 1984;52:174-9.
141. Hyodo T, Hayashi M, Mitsutake S, Miura N, Yamazoe N. Oxygen reduction activities of praseodymium manganites in alkaline solution. J Ceramic Soc Japan 1997;105:412-17.
142. 3 dispersed on carbon support. Electrochemical and Solid-State Letters 2005;8:A270-2.
143. Meadowcroft DB. Low-cost oxygen electrode material. Nature 1970;226:847-8.
144. Tseung ACC, Bevan HL. A reversible oxygen electrode. J Electroanal Chem 1973;45:429-38.
145. 3-y experimental results and related properties. J Electroanal Chem 1978;88:353-61.
146. Obayashi H, Kudo T. Perovskite-type compounds as electrode catalysts for cathodic reduction of oxygen. Mater Res Bull 1978;133:1409-13.
147. 3 in alkaline solution. J Power Sources 1983;10:319-31.
148. 3 by using XRD, TG and TPR. Kongop Hwahak 1996;7:543-64.
149. 3 for oxygen reduction. Wuji Cailiao Xuebao 1999;14:618-22.
150. 3 bifunctional oxygen electrode. Huaxue Xuebao 2005;63:363-71.
151. 4+λ air electrode catalyst for oxygen reduction. Heilongjian Daxue Ziran Kexue Xuebao 2005;22:481-4.
152. Savy M. Oxygen reduction in alkaline solution on semiconducting cobalt oxide electrodes. Electrochim Acta 1968;13:1359-76.
153. 4) spinel in an alkaline solution. Elektrokhimiya 1978;14:1504-9.
154. Bagotzky VS, Shumilova NA, Khrushcheva EI. Electrochemical oxygen reduction on oxide catalysts. Electrochim Acta 1976;21:919-24.
155. 2NiO and related oxides. Electrochim Acta 1974;19:493-8.
156. 4). Elektrokhimiya 1976;12:504-7.
157. 4 prepared by the method of chemical spray pyrolysis for electrocatalysis Part IV. The electrocatalysis of oxygen reduction. J Electroanal Chem 1991;314:241-57.
158. Sugawara M, Ohno M, Matsuki K. Oxygen reduction catalysis of Mn-Co spinel oxides on a graphite electrode in alkaline solution. J Mater Chem 1997;7:833-6.
159. 4 system. Electrochim Acta 1998;44:1491-7.
160. 4 for alkaline fuel cell. J Power Sources 2002;106:109-15.
161. 4 [M=Co, Fe, (CoFe)] as electrocatalyst for oxygen evolution/reduction in alkaline solution. J Appl Electrochem 1999;29:1351-4.
162. Ortiz J, Gautier JL. Oxygen reduction on copper chromium manganites. Effect of oxide composition on the reaction mechanism in alkaline solution. J Electroanal Chem 1995;391:111-18.
163. 4. Electrocatalytical properties for the oxygen evolution reaction and oxygen reduction reaction in alkaline media. Electrochim Acta 2001;46:3373-80.
164. Matsuda Y, Yamashita K, Takasu Y. Characteristics of manganese dioxide-active carbon as an oxygen electrode in alkaline-type fuel cells. Electrochemistry 1983;51:925-30.
165. Yang J, Xu JJ. Nanoporous amorphous manganese oxide as electrocatalyst for oxygen reduction in alkaline solutions. Electrochem Commun 2003;5:306-11.
166. Calegaro ML, Lima FHB, Ticianelli EA. Oxygen reduction reaction on nanosized manganese oxide particles dispersed on carbon in alkaline solutions. J Power Sources 2006;158:735-9.
167. 2 catalysts supported on binary carbons. Int J Hydrogen Energy 2006;31:2076-87.
168. 2 bonded to a protonexchange membrane. Electrochim Acta 1995;40:303-7.