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Volumn 20, Issue 2, 2014, Pages 419-425

Synthesis of 4-arms hydroxy-functionalized PMMA-b-PE through combining free radical polymerization with coordination polymerization

Author keywords

4 Arms hydroxy functionalized copolymer; Block copolymer; Coordination polymerization; Free radical polymerization; One pot strategy

Indexed keywords

COORDINATION POLYMERIZATION; ETHYLENE PRESSURE; METALLOCENE COMPLEXES; MOLAR RATIO; MONOMER ADDITION; NMR ANALYSIS; ONE POT; POLYMERIZATION CONDITIONS;

EID: 84891869104     PISSN: 1226086X     EISSN: 22345957     Source Type: Journal    
DOI: 10.1016/j.jiec.2013.04.036     Document Type: Article
Times cited : (7)

References (29)
  • 12
    • 84891856989 scopus 로고    scopus 로고
    • When the experiment was performed in a 300mL glass Schlenk, the mixture color was changed into lime-green, demonstrating the formation of metallocene complex radical CpTi(III)Cl2
    • Catalyst system: CpTiCl3/Zn/Is/MMA=8/12/1/300; monomer: MMA (3mL); radical polymerization of MMA was carried out at 90°C for 2.5h in 1,4-dioxane (IE=0.68, Mn=0.27×104, MWD=1.51).
    • Catalyst system: CpTiCl3/Zn/Is/MMA=8/12/1/300; monomer: MMA (3mL); radical polymerization of MMA was carried out at 90°C for 2.5h in 1,4-dioxane (IE=0.68, Mn=0.27×104, MWD=1.51). When the experiment was performed in a 300mL glass Schlenk, the mixture color was changed into lime-green, demonstrating the formation of metallocene complex radical CpTi(III)Cl2.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.