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When the experiment was performed in a 300mL glass Schlenk, the mixture color was changed into lime-green, demonstrating the formation of metallocene complex radical CpTi(III)Cl2
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Catalyst system: CpTiCl3/Zn/Is/MMA=8/12/1/300; monomer: MMA (3mL); radical polymerization of MMA was carried out at 90°C for 2.5h in 1,4-dioxane (IE=0.68, Mn=0.27×104, MWD=1.51).
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Catalyst system: CpTiCl3/Zn/Is/MMA=8/12/1/300; monomer: MMA (3mL); radical polymerization of MMA was carried out at 90°C for 2.5h in 1,4-dioxane (IE=0.68, Mn=0.27×104, MWD=1.51). When the experiment was performed in a 300mL glass Schlenk, the mixture color was changed into lime-green, demonstrating the formation of metallocene complex radical CpTi(III)Cl2.
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