Preservation of NOM-metal complexes in a modern hyperalkaline stalagmite: Implications for speleothem trace element geochemistry

Geochimica et Cosmochimica Acta

Volumn 128, Issue , 2014, Pages 29-43

  Hartland, Adam ^a   Fairchild, Ian J ^b   Müller, Wolfgang ^c   Dominguez Villar, David ^d  

^a UNIVERSITY OF WAIKATO   (New Zealand)

^b UNIVERSITY OF BIRMINGHAM   (United Kingdom)

^c UNIVERSITY OF LONDON   (United Kingdom)

^d CENTRO NACIONAL DE INVESTIGACIÓN SOBRE LA EVOLUCIÓN HUMANA CENIEH   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS SOLUTION; CALCITE; CONCENTRATION (COMPOSITION); INDUCTIVELY COUPLED PLASMA METHOD; ISOTOPIC RATIO; ORGANIC MATTER; PH; PRECIPITATION (CHEMISTRY); SEDIMENT CHEMISTRY; SPELEOTHEM; STABLE ISOTOPE; STALAGMITE; TOTAL ORGANIC CARBON; TRACE ELEMENT;

DERBYSHIRE; ENGLAND; POOLE [ENGLAND]; UNITED KINGDOM;

EID: 84891798845     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.gca.2013.12.005     Document Type: Article

References (29)

1. Aiken G.R., Hsu-Kim H., Ryan J.N. Influence of dissolved organic matter on the environmental fate of metals, nanoparticles, and colloids. Environ. Sci. Technol. 2011, 45:3196-3201.
2. Baker A., Caseldine C.J., Gilmour M.A., Charman D., Proctor C.J., Hawkesworth C.J., Phillips N. Stalagmite luminescence and peat humification records of palaeomoisture for the last 2500 years. Earth Planet. Sci. Lett. 1999, 165:157-162.
3. Baker A., Proctor C.J., Barnes W.L. Variations in stalagmite luminescence laminae structure at Poole's Cavern, England, AD 1910-1996: calibration of a palaeoprecipitation proxy. Holocene 1999, 9:683-688.
4. Baker A., Smart P.L., Edwards R.L., Richards D.A. Annual growth banding in a cave stalagmite. Nature 1993, 364:518-520.
5. Benedetti M.F., VanRiemsdijk W.H., Koopal L.K., Kinniburgh D.G., Gooddy D.C., Milne C.J. Metal ion binding by natural organic matter: from the model to the field. Geochim. Cosmochim. Acta 1996, 60:2503-2513.
6. Borsato A., Frisia S., Fairchild I.J., Somogyi A., Susini J. Trace element distribution in annual stalagmite laminae mapped by micrometer-resolution X-ray fluorescence. Implications for incorporation of environmentally significant species. Geochim. Cosmochim. Acta 2007, 71:1494-1512.
7. + in calcites and selected aragonites. Geochim. Cosmochim. Acta 1985, 49:713-725.
8. Chada V.G.R., Hausner D.B., Strongin D.R., Rouff A.A., Reeder R.J. Divalent Cd and Pb uptake on calcite [10(1)over-bar4} cleavage faces: an XPS and AFM study. J. Colloid Interface Sci. 2005, 288:350-360.
9. Clark I.D., Fontes J.C., Fritz P. Stable isotope disequilibria in travertine from high pH waters: laboratory investigations and field observations from Oman. Geochim. Cosmochim. Acta 1992, 56:2041-2050.
10. 2+ adsorption complexes at the calcite surface. An X-ray absorption spectroscopy study. Geochim. Cosmochim. Acta 2006, 70:2715-2725.
11. Fairchild I.J., Baker A. Speleothem Science: From Process to Past Environments 2012, Wiley-Blackwell.
12. Fairchild I.J., Baker A., Borsato A., Frisia S., Hinton R.W., McDermott F., Tooth A.F. Annual to sub-annual resolution of multiple trace-element trends in speleothems. J. Geol. Soc. 2001, 158:831-841.
13. Fairchild I.J., Hartland A. Trace element variations in stalagmites: controls by climate and by karst system processes. Ion Partitioning in Ambient Temperature Aqueous Systems: From Fundamentals to Applications in Climate Proxies and Environmental Geochemistry 2010, European Mineralogical Union, Oviedo. H. Stoll, M. Prieto (Eds.).
14. Fairchild I.J., Spotl C., Frisia S., Borsato A., Susini J., Wynn P.M., Cauzid J., Eimf Petrology and geochemistry of annually laminated stalagmites from an Alpine cave (Obir, Austria): seasonal cave physiology. Geol. Soc. London Spec. Publ. 2010, 336:295-321.
15. Fairchild I.J., Treble P.C. Trace elements in speleothems as recorders of environmental change. Quatern. Sci. Rev. 2009, 28:449-468.
16. Fein J.B. The effects of ternary surface complexes on the adsorption of metal cations and organic acids onto mineral surfaces. Water-Rock Interactions, Ore Deposits, and Environmental Geochemistry. A Tribute to David A. Crerar 2002, 462. The Geochemical Society, St. Louis. S.A. Wood (Ed.).
17. Frisia S., Fairchild I.J., Fohlmeister J., Miorandi R., Spotl C., Borsato A. Carbon mass-balance modelling and carbon isotope exchange processes in dynamic caves. Geochim. Cosmochim. Acta 2011, 75:380-400.
18. Godelitsas A., Astilleros J.M., Hallam K., Harissopoulos S., Putnis A. Interaction of calcium carbonates with lead in aqueous solutions. Environ. Sci. Technol. 2003, 37:3351-3360.
19. Hartland A., Fairchild I.J., Lead J.R., Baker A. Fluorescent properties of organic carbon in cave dripwaters: effects of filtration, temperature and pH. Sci. Total Environ. 2010, 408:5940-5950.
20. Hartland A., Fairchild I.J., Lead J.R., Borsato A., Baker A., Frisia S., Baalousha M. From soil to cave: transport of trace metals by natural organic matter in karst dripwaters. Chem. Geol. 2012, 304-305:68-82.
21. Hartland A., Fairchild I.J., Lead J.R., Dominguez-Villar D., Baker A., Gunn J., Baalousha M., Ju-Nam Y. The dripwaters and speleothems of Poole's Cavern: a review of recent and ongoing research. Cave Karst Sci. 2010, 36:37-46.
22. Hartland A., Fairchild I.J., Lead J.R., Zhang H., Baalousha M. Size, speciation and lability of NOM-metal complexes in hyperalkaline cave dripwater. Geochim. Cosmochim. Acta 2011, 75:7533-7551.
23. Lead J.R., Wilkinson K.J. Aquatic colloids and nanoparticles: current knowledge and future trends. Environ. Chem. 2006, 3:159-171.
24. Lee Y.J., Elzinga E.J., Reeder R.J. Cu(II) adsorption at the calcite-water interface in the presence of natural organic matter: kinetic studies and molecular-scale characterization. Geochim. Cosmochim. Acta 2005, 69:49-61.
25. Longerich H.P., Jackson S.E., Gunther D. Laser ablation inductively coupled plasma mass spectrometric transient signal data acquisition and analyte concentration calculation. J. Anal. At. Spectrom. 1996, 11:899-904.
26. Milne C.J., Kinniburgh D.G., Van Riemsdijk W.H., Tipping E. Generic NICA-Donnan model parameters for metal-ion binding by humic substances. Environ. Sci. Technol. 2003, 37:958-971.
27. Murphy E. M., Zachara J. M., Smith S. C., Phillips J. L. (1990) The sorption of humic acids sorption of humic acids to mineral surfaces and their role in contaminant binding. In: 5th International Meeting of the International Humic Substances Soc: Advances in Humic Substances Research, Nagoya, Japan. pp. 413-423.
28. Sunagawa I. Crystals. Growth, Morphology and Perfection 2005, Cambridge University Press.
29. Zachara J.M., Cowan C.E., Resch C.T. Sorption of divalent metals on calcite. Geochim. Cosmochim. Acta 1991, 55:1549-1562.