Production of DMC from CO2 via indirect route: Technical-economical-environmental assessment and analysis

ACS Sustainable Chemistry and Engineering

Volumn 2, Issue 1, 2014, Pages 62-69

  Souza, Lorena F S ^a   Ferreira, Priscila R R ^a   De Medeiros, José Luiz ^a   Alves, Rita M B ^b   Araújo, Ofélia Q F ^a  

^a FEDERAL UNIVERSITY OF RIO DE JANEIRO   (Brazil)

^b Braskem SA   (Brazil)

Author keywords

CO2 reutilization; CO2 to DMC; DMC; Ethylene glycol; Extractive distillation; GHG chemical sequestration; MIBK

Indexed keywords

DMC; EXTRACTIVE DISTILLATION; GHG CHEMICAL SEQUESTRATION; MIBK; RE-UTILIZATION;

DISTILLATION; ENERGY UTILIZATION; ETHYLENE; ETHYLENE GLYCOL; GREENHOUSE GASES; KETONES; POLYOLS; PROFITABILITY; SUSTAINABLE DEVELOPMENT;

CARBON DIOXIDE;

EID: 84891762665     PISSN: None     EISSN: 21680485     Source Type: Journal    
DOI: 10.1021/sc400279n     Document Type: Article

References (14)

1. Fang, Y. J.; Xiao, W. Experimental and modeling studies on a homogeneous reactive distillation system for dimethyl carbonate synthesis by transesterification Sep. Purif. Technol. 2004, 34 (1-4) 255-263
2. Nisoli, A.; Bouwens, S. M.; Doherty, M. F.; Malone, M. F. Method of Separating Dimethyl Carbonate and Methanol. U.S. Patent 6315868 B1, November 13, 2001.
3. 2 conditions Ind. Eng. Chem. Res. 2004, 43 (24) 7732-7739
4. Hsu, K.; Hsiao, Y.; Chien, I. Design and control of dimethyl carbonate-methanol separation via extractive distillation in the dimethyl carbonate reactive-distillation process Ind. Eng. Chem. Res. 2010, 49 (2) 735-749
5. Sakakura, T.; Choi, J.; Yasuda, H. Transformation of carbon dioxide Chem. Rev. 2007, 107, 2365-2387
6. IPCC Special Report on Carbon Dioxide Capture and Storage. Metz, B.; Davidson, O.; Coninck, H.; Loos, M.; Meyer, L., Eds.; Prepared by Working Group III of the Intergovernmental Panel on Climate Change, 2005. www.ipcc.ch/pdf/ special-reports/srccs/srccs-wholereport.pdf
7. 2O Green Chem. 2011, 13, 3213-3217
8. Peppel, W. J. Preparation and properties of the alkylene carbonates Ind. Eng. Chem. 1958, 50 (5) 767-770
9. Matsuda, H.; Takahara, H.; Fujino, S.; Constantinescu, D.; Kurihara, K.; Tochigi, K.; Ochi, K.; Gmehling, J. Selection of entrainers for the separation of the binary azeotropic system methanol + dimethyl carbonate by extractive distillation Fluid Phase Equilib. 2011, 310 (1-2) 166-181
10. Camy, S.; Condoret, J. S. Dynamic modeling of a fractionation process for a liquid mixture using supercritical carbon dioxide Chem. Eng. Process. 2003, 40 (6) 499-509
11. City Environmental Quality Review (CEQR) Technical Manual. New York City Mayor's Office of Environmental Coordination, 2012. http://www.nyc.gov/html/oec/ downloads/pdf/2012-ceqr-tm.
12. Cabezas, H.; Bare, J. C.; Mallick, S. K. Pollution prevention with chemical process simulators: The generalized waste reduction (WAR) algorithm-Full version Comput. Chem. Eng. 1999, 23, 623-634
13. Turton, R.; Bailie, R. C.; Whiting, W. B.; Shaeiwitz, J. A. Analysis, Synthesis, and Design of Chemical Processes, 3 rd ed.; Prentice Hall: Upper Saddle River, NJ, 2009.
14. HYSYS® 2004.2, User Guide. Aspen Technology, Inc.: Burlington, MA, 2005.