Corrosion of conductive polypyrrole: Effects of possibly formed galvanic cells

Corrosion Science

Volumn 80, Issue , 2014, Pages 318-330

  Qi, Kai ^a   Qiu, Yubing ^a   Chen, Zhenyu ^a,b   Guo, Xingpeng ^a,b  

^a HUAZHONG UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

^b Hubei Key Laboratory of Materials Chemistry and Service Failure   (China)

Author keywords

A. Polymer; B. XPS; C. Oxygen reduction; C. Potential parameters

Indexed keywords

CORROSION CELLS; ELECTROCHEMICAL METHODS; ELECTROLYTE CONCENTRATION; GALVANIC CELLS; GALVANIC COUPLES; OXYGEN CONCENTRATIONS; OXYGEN REDUCTION; POTENTIAL PARAMETERS;

CELLS; CORROSION; CYTOLOGY; X RAY PHOTOELECTRON SPECTROSCOPY;

POLYPYRROLES;

EID: 84891632815     PISSN: 0010938X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.corsci.2013.11.040     Document Type: Article

References (48)

1. Valero L., Arias-Pardilla J., Cauich-Rodríguez J., Smit M.A., Otero T.F. Characterization of the movement of polypyrrole dodecylbenzenesulfonate perchlorate/tape artificial muscles. Faradaic control of reactive artificial molecular motors and muscles. Electrochim. Acta 2011, 56:3721-3726.
2. Dubal D.P., Patil S.V., Jagadale A.D., Lokhande C.D. Two step novel chemical synthesis of polypyrrole nanoplates for supercapacitor application. J. Alloys. Compd. 2011, 509:8183-8188.
3. Jeon S.S., An H.H., Yoon C.S., Im S.S. Synthesis of ultra thin polypyrrole nanosheets for chemicalsensor applications. Polymer 2011, 52:652-657.
4. Qin H.Y., Liu Z.X., Ye L.Q., Zhu J.K., Li Z.P. The use of polypyrrole modified carbon-supported cobalt hydroxide as cathode and anode catalysts for the direct borohydride fuel cell. J. Power Sources 2009, 192:385-390.
5. González M.B., Saidman S.B. Electrodeposition of polypyrrole on 316L stainless steel forcorrosion prevention. Corros. Sci. 2011, 53:276-282.
6. Ge D.T., Tian X.D., Qi R.C., Huang S.Q., Mu J., Hong S.M., Ye S.F., Zhang X.M., Li D.H., Shi W. A polypyrrole-based microchip for controlled drug release. Electrochim. Acta 2009, 55:271-275.
7. Hammache H., Makhloufi L., Saidani B. Corrosion protection of iron by polypyrrole modified by copper using the cementation process. Corros. Sci. 2003, 45:2031-2042.
8. Sharma R.K., Rastogi A.C., Desu S.B. Pulse polymerized polypyrrole electrodes for high energy density electrochemical supercapacitor. Electrochem. Commun. 2008, 10:268-272.
9. Pud A.A. Stability and degradation of conducting polymers in electrochemical systems. Synth. Met. 1994, 66:1-18.
10. Fernandez I., Trueba M., Nunez C.A., Rieumont J. Some features of the overoxidation of polypyrrole synthesized on austenitic stainless steel electrodes in aqueous nitrate solutions. Surf. Coat. Technol. 2005, 191:134-139.
11. (19.09.11). http://www.efcweb.org/Working+Parties/WP+19.html.
12. Abthagir P.S., Saraswathi R. Thermal stability of polypyrrole prepared from a ternary eutectic melt. Mater. Chem. Phys. 2005, 92:21-26.
13. Yfantis A., Appel G., Schmeiber D., Yfantis D. Polypyrrole doped with fluro-metal composites: thermal stability and structural properties. Synth. Met. 1997, 106:187-195.
14. Cataldo F., Omastova M. On the ozone degradation of polypyrrole. Polym. Degrad. Stab. 2003, 82:487-495.
15. Alumaa A., Hallik A., Sammelselg V., Tamm J. On the improvement of stability of polypyrrole films in aqueous solutions. Synth. Met. 2007, 157:485-491.
16. Tian Ying, Yang Fenglin, Yang Weishen Redox behavior and stability of polypyrrole film in sulfuric acid. Synth. Met. 2006, 156:1052-1056.
17. Chehimi Mohamed M., Abdeljalil Essadik A study of the degradation and stability of polypyrrole by inverse gas chromatography, X-ray photoelectron spectroscopy, and conductivity measurements. Synth. Met. 2004, 145:15-22.
18. Ibanez Jorge G., Alatorre-Ordaz Alejandro, Gutierrez-Granados Silvia, Batina Nikola Nanoscale degradation of polypyrrole films under oxidative stress: an atomic force microscopy study and review. Polym. Degrad. Stab. 2008, 93:827-837.
19. Ghosh Soumyadeb, Bowmaker Graham A., Cooney Ralph P., Seakins John M. Infrared and Raman spectroscopic studies of the electrochemical oxidative degradation of polypyrrole. Synth. Met. 1998, 95:63-67.
20. Liu Y.C., Hwang B.J. Mechanism of conductivity decay of polypyrrole exposed to water and enhancement of conductivity stability of copper(I)-modified polypyrrole. J. Electroanal. Chem. 2001, 501:100-106.
21. Li Y., Qian R. Electrochemical overoxidation of conducting polypyrrole nitrate film in aqueous solutions. Eletrochim. Acta 2000, 45:1727-1731.
22. Mostany J., Scharifker B.R. Direct microcalorimetric measurement of doping and overoxidation process in polypyrrole. Electrochim. Acta 1997, 42:291-301.
23. Rodriguez I., Scharifker B.R., Mostany J. In situ FTIR study of redox and overoxidation processes in polypyrrole films. J. Electroanal. Chem. 2000, 491:117-125.
24. Xie H., Yan M., Jiang Z. Transition of polypyrrole from electroactive to electroinactive state investigated by use of in situ FTIR spectroscopy. Electrochim. Acta 1997, 42:2361-2367.
25. Neoh K.G., Young T.T., Kang E.T., et al. Structural and mechanical degradation of polypyrrole films due to aqueous media and heat treatment and the subsequent redoping characteristics. J. Appl. Polym. Sci. 1997, 64:519-526.
26. Wallace G.G., Spinks G.M., Kane-Maguire L.A.P., Teasdale P.R. Conductive Electroactive Polymers: Intelligent Polymer Systems 2009, Taylor & Francis, Boca Raton.
27. Malinauskas A. Electrocatalysis at conducting polymers. Synth. Met. 1999, 107:75-83.
28. Haimeri A., Merz A. Catalysis of quinone-hydroquinone redox reactions at polypyrrole benzenesulofnate-coated platinum-electrodes. J. Electroanal. Chem. 1987, 220:55-65.
29. Schuhmann W., Lammert R., Hammerle M., Schmidt H.-L. Elecrtocatalytic properties of polypyrrole in amperometric electrodes. Biosens. Bioelecrton. 1991, 6:689-697.
30. Kwaashima M., Sato Y., Sato M., Sakaguchi M. Role of catalysts on electrode activity in oxygen diuffsion hybrid polymer electrode. Polym. J. 1991, 23:37-45.
31. Zinger B. Electrochemistry of quinoid dopants in conducting polymers. Synth. Met. 1989, 30:209-225.
32. Qi K., Qiu Y.B., Chen Z.Y., Guo X.P. Corrosion of conductive polypyrrole: effects of environmental factors, electrochemical stimulation, and doping anions. Corros. Sci. 2012, 60:50-58.
33. Qi K., Qiu Y.B., Chen Z.Y., Guo X.P. Corrosion of conductive polypyrrole: effects of continuous cathodic and anodic polarisation. Corros. Sci. 2013, 69:376-388.
34. Lin B., Hu R.G., Ye C.Q., Li Y., Lin C.J. A study on the initiation of pitting corrosion in carbon steel in chloride-containing media using scanning electrochemical probes. Eletrochim. Acta 2010, 55:6542-6545.
35. Molina J., Fernández J., del Río A.I., Lapuente R., Bonastre J., Cases F. Stability of conducting polyester/polypyrrole fabrics in different pH solutions: chemical and electrochemical characterization. Polym. Degrad. Stab. 2010, 95:2574-2583.
36. Rajagopalan Ramakrishnan, Iroh Jude O. Characterization of polyaniline-polypyrrole composite coatings on low carbon steel: a XPS and infrared spectroscopy study. Appl. Surf. Sci. 2003, 218:58-69.
37. Carquigny Stephanie, Segut Olivier, Lakard Boris, Lallemand F., Fievet Patrick Effect of electrolyte solvent on the morphology of polypyrrole films: application to the use of polypyrrole in pH sensors. Synth. Met. 2008, 158:453-461.
38. Prissanaroon-Ouajai Walaiporn, Pigram Paul J., Jones Robert, Sirivat Anuvat A novel pH sensor based on hydroquinone monosulfonate-doped conducting polypyrrole. Sens. Actuators. B 2008, 135:366-374.
39. Pei Q.B., Qian R.Y. Protonation and deprotonation of polypyrrole chain in aqueous solutions. Synth. Met. 1991, 45:35-48.
40. Doblhofer K. The non-metallic character of solvated conducting polymers. J. Electroanal. Chem. 1992, 331:1015-1027.
41. Dumanska J., Maksymiuk K. Studies on spontaneous charging/discharging processes of polypyrrole in aqueous electrolyte solutions. Electroanalysis 2001, 13:567-573.
42. Lewenstam A., Bobacka J., Ivaska A. Mechanism of ionic and redox sensitivity of p-type conducting polymers Part 1. Theory. J. Electroanal. Chem. 1994, 368:23-31.
43. Bobacka J., Gao Z.Q., Ivaska A., Lewenstam A. Mechanism of ionic and redox sensitivity of p-type conducting polymers Part 2. Experimental study of polypyrrole. J. Electroanal. Chem. 1994, 368:33-41.
44. Alumaa A., Hallik A., Sammelselg V., Tamm J. On the improvement of stability of polypyrrole films in aqueous solutions. Synth. Met. 2007, 157:485-491.
45. Vetter K.J. Electrochemical Kinetics 1967, Academic Press, New York.
46. Li Y.F., Qian R.Y. On the nature of redox processes in the cyclic voltammetry of polypyrrole nitrate in aqueous solutions. J. Electroanal. Chem. 1993, 362:267-272.
47. Qi Z., Rees N.G., Pickup P.G. Electrochemically induced substitution of polythiophenes and polypyrrole. Chem. Mater. 1996, 8:701-707.
48. Ghosh S., Bowmaker G.A., Cooney R.P., Seakins J.M. Infrared and Raman spectroscopic studies of the electrochemical oxidative degradation of polypyrrole. Synth. Met. 1998, 95:63-67.