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Allyl trichlorosilane is conveniently prepared from allyl chloride, Cl3SiH, CuCl, and (i-Pr)2EtN (or Et3N) in ether at 20 °C:
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For an alternative route, utilizing trans-crotyl chloride, SiCl4, and Cp2Ni in HMPA at 90 °C, see:
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