Long-lived nuclear spin states in methyl groups and quantum-rotor-induced polarization

Journal of the American Chemical Society

Volumn 135, Issue 50, 2013, Pages 18746-18749

  Meier, Benno ^a   Dumez, Jean Nicolas ^a   Stevanato, Gabriele ^a   Hill Cousins, Joseph T ^a   Roy, Soumya Singha ^a   Haìškansson, Pär ^a   Mamone, Salvatore ^a   Brown, Richard C D ^a   Pileio, Giuseppe ^a   Levitt, Malcolm H ^a  

^a UNIVERSITY OF SOUTHAMPTON   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

APPROXIMATE SYMMETRY; HETERONUCLEAR DIPOLAR COUPLINGS; INTERNAL ROTATIONS; LIQUID HELIUM TEMPERATURE; LONG-LIVED STATE; NUCLEAR SPIN STATE; ROTATIONAL BARRIERS; THERMAL EQUILIBRATIONS;

FUNCTIONAL GROUPS; LIQUEFIED GASES; RELAXATION TIME; SUPERFLUID HELIUM;

SPIN DYNAMICS;

HELIUM; METHYL GROUP;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; NUCLEAR MAGNETIC RESONANCE; POLARIZATION; QUANTUM CHEMISTRY;

EID: 84890672464     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja410432f     Document Type: Article

References (30)

1. Carravetta, M.; Johannessen, O. G.; Levitt, M. H. Phys. Rev. Lett. 2004, 92, 153003
2. Carravetta, M.; Levitt, M. H. J. Chem. Phys. 2005, 122, 214505
3. Pileio, G.; Carravetta, M.; Levitt, M. H. Proc. Natl. Acad. Sci. U.S.A. 2010, 107, 17135
4. Pileio, G.; Bowen, S.; Laustsen, C.; Tayler, M. C. D.; Hill-Cousins, J. T.; Brown, L. J.; Brown, R. C. D.; Ardenkjær-Larsen, J. H.; Levitt, M. H. J. Am. Chem. Soc. 2013, 135, 5084
5. Theis, T.; Feng, Y.; Wu, T.-L.; Warren, W. S. arXiv.orge-Print Arch., Phys. 2013, arXiv:1308.5666.
6. Levitt, M. H. Annu. Rev. Phys. Chem. 2012, 63, 89
7. Grant, A. K.; Vinogradov, E. J. Magn. Reson. 2008, 193, 177
8. Hogben, H. J.; Hore, P. J.; Kuprov, I. J. Magn. Reson. 2011, 211, 217
9. Tayler, M. C. D.; Marco-Rius, I.; Kettunen, M. I.; Brindle, K. M.; Levitt, M. H.; Pileio, G. J. Am. Chem. Soc. 2012, 134, 7668
10. Feng, Y.; Theis, T.; Liang, X.; Wang, Q.; Zhou, P.; Warren, W. S. J. Am. Chem. Soc. 2013, 135, 9632
11. Ardenkjær-Larsen, J. H.; Fridlund, B.; Gram, A.; Hansson, G.; Hansson, L.; Lerche, M. H.; Servin, R.; Thaning, M.; Golman, K. Proc. Natl. Acad. Sci. U.S.A. 2003, 100, 10158
12. Barnes, A. B.; De Paëpe, G.; van der Wel, P. C. A.; Hu, K. N.; Joo, C. G.; Bajaj, V. S.; Mak-Jurkauskas, M. L.; Sirigiri, J. R.; Herzfeld, J.; Temkin, R. J.; Griffin, R. G. J. Low Temp. Phys. 2008, 34, 237
13. Jannin, S.; Bornet, A.; Melzi, R.; Bodenhausen, G. Chem. Phys. Lett. 2012, 549, 99
14. Nelson, S. J.; Kurhanewicz, J.; Vigneron, D. B.; Larson, P. E. Z.; Harzstark, A. L.; Ferrone, M.; van Criekinge, M.; Chang, J. W.; Bok, R.; Park, I.; Reed, G.; Carvajal, L.; Small, E. J.; Munster, P.; Weinberg, V. K.; Ardenkjær-Larsen, J. H.; Chen, A. P.; Hurd, R. E.; Odegardstuen, L. I.; Robb, F. J.; Tropp, J.; Murray, J. A. Sci. Transl. Med. 2013, 5, 198ra108
15. Icker, M.; Fricke, P.; Berger, S. J. Magn. Reson. 2012, 223, 148
16. Icker, M.; Berger, S. J. Magn. Reson. 2012, 219, 1
17. Haupt, J. Phys. Lett. A 1972, 38, 389
18. Horsewill, A. J. Prog. Nucl. Magn. Reson. Spectrosc. 1999, 35, 359
19. Ludwig, C.; Saunders, M.; Marin-Montesinos, I.; Günther, U. L. Proc. Natl. Acad. Sci. U.S.A. 2010, 107, 10799
20. Tomaselli, M.; Degen, C.; Meier, B. H. J. Chem. Phys. 2003, 118, 8559
21. Granwehr, J.; Leggett, J.; Köckenberger, W. J. Magn. Reson. 2007, 187, 266
22. Bunker, P. R.; Jensen, P. Molecular Symmetry and Spectroscopy, 2 nd ed.; NRC Research Press: Ottawa, 2006.
23. Prager, M.; Heidemann, A. Chem. Rev. 1997, 97, 2933
24. Abragam, A. Principles of Nuclear Magnetism; Oxford University Press, Oxford, UK, 1983.
25. Hubbard, P. S. J. Chem. Phys. 1970, 52, 563
26. Werbelow, L. G. J. Chem. Phys. 1975, 63, 544
27. Tugarinov, V.; Hwang, P. M.; Ollerenshaw, J. E.; Kay, L. E. J. Am. Chem. Soc. 2003, 125, 10420
28. Müller, N.; Bodenhausen, G. J. Chem. Phys. 1993, 98, 6062
29. Kowalewski, J.; Mäler, L. Nuclear Spin Relaxation in Liquids: Theory, Experiments, and Applications; CRC Press: Boca Raton, FL, 2006.
30. SpinDynamica, available at www.spindynamica.soton.ac.uk.