LaFeO3 and BiFeO3 perovskites as nanocatalysts for contaminant degradation in heterogeneous Fenton-like reactions

Chemical Engineering Journal

Volumn 239, Issue , 2014, Pages 322-331

  Rusevova, Klara ^a   Köferstein, Roberto ^b   Rosell, Mònica ^a,c   Richnow, Hans H ^a   Kopinke, Frank Dieter ^a   Georgi, Anett ^a  

^a HELMHOLTZ CENTRE FOR ENVIRONMENTAL RESEARCH UFZ   (Germany)

^b MARTIN LUTHER UNIVERSITY HALLE WITTENBERG   (Germany)

^c UNIVERSITY OF BARCELONA   (Spain)

Author keywords

BiFeO3; Catalytic oxidation; Heterogeneous Fenton; LaFeO3; Perovskite

Indexed keywords

BIFEO3; COMPOUND-SPECIFIC STABLE ISOTOPE ANALYSIS; CONTAMINANT DEGRADATION; DEGRADATION EFFICIENCY; HETEROGENEOUS FENTON; LAFEO3; METHYL TERT BUTYL ETHER; PSEUDO FIRST ORDER RATE CONSTANTS;

BISMUTH COMPOUNDS; CATALYSIS; CATALYTIC OXIDATION; DEGRADATION; FREE RADICALS; IMPURITIES; ISOTOPES; OXIDATION; PHENOLS; RATE CONSTANTS; REUSABILITY; SOL-GEL PROCESS;

PEROVSKITE;

EID: 84890059686     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2013.11.025     Document Type: Article

References (44)

1. -) in aqueous solution. J. Phys. Chem. Ref. Data 1988, 17:513-886.
2. Perathoner S., Centi G. Wet hydrogen peroxide catalytic oxidation (WHPCO) of organic waste in agro-food and industrial streams. Top. Catal. 2005, 33:207-224.
3. Garrido-Ramirez E.G., Theng B.K.G., Mora M.L. Clays and oxide minerals as catalysts and nanocatalysts in Fenton-like reactions - a review. Appl. Clay Sci. 2010, 47:182-192.
4. 2. Appl. Catal. B - Environ. 2009, 89:356-364.
5. Navalon S., Alvaro M., Garcia H. Heterogeneous Fenton catalysts based on clays, silicates and zeolites. Appl. Catal. B - Environ. 2010, 99:1-26.
6. 2 at neutral pH. Catal. Commun. 2006, 7:901-906.
7. 2 Fenton-like system: kinetic, pathway and effect factors. Sep. Purif. Technol. 2008, 62:551-558.
8. Baldrian P., Merhautova V., Gabriel J., Nerud F., Stopka P., Hruby M., Benes M.J. Decolorization of synthetic dyes by hydrogen peroxide with heterogeneous catalysis by mixed iron oxides. Appl. Catal. B - Environ. 2006, 66:258-264.
9. Rusevova K., Kopinke F.D., Georgi A. Nano-sized magnetic iron oxides as catalysts for heterogeneous Fenton-like reactions-influence of Fe(II)/Fe(III) ratio on catalytic performance. J. Hazard. Mater. 2012, 241:433-440.
10. Tanaka H. An intelligent catalyst: the self-regenerative palladium-perovskite catalyst for automotive emissions control. Catal. Surv. Asia 2005, 9:63-74.
11. Pena M.A., Fierro J.L.G. Chemical structures and performance of perovskite oxides. Chem. Rev. 2001, 101:1981-2017.
12. 3 perovskites. Catal. Commun. 2003, 4:561-566.
13. 3 (0≤X≤0.6) perovskite oxides. Chem. Eng. Technol. 2011, 34:49-55.
14. 3 (Ln=La or Nd and A=K or Sr) perovskites. Appl. Catal. A - Gen. 2001, 215:245-256.
15. 2 decomposition. J. Catal. 2001, 203:264-272.
16. 3 nanoparticles. J. Am. Cer. Soc. 2011, 94:3418-3424.
17. 3 perovskite as new and performant catalyst for the wet peroxide oxidation of organic pollutants in ambient conditions. Top. Catal. 2009, 52:1211-1219.
18. 3 perovskite catalyst. Appl. Catal. B - Environ. 2004, 47:281-294.
19. 3 as a reusable heterogeneous Fenton-like catalyst. Environ. Sci. Technol. 2010, 44:1786-1791.
20. 3 (Re: La, Sm, Eu, Gd) photocatalyst. Mater. Sci. Eng. B - Adv. 2010, 171:31-34.
21. 9 suspensions. J. Phys. Chem. C 2009, 113:12826-12831.
22. 3 perovskite with improved surface area synthesized using different routes and its characterization. Mater. Chem. Phys. 2010, 119:324-329.
23. Rosell M., Gonzalez-Olmos R., Rohwerder T., Rusevova K., Georgi A., Kopinke F.D., Richnow H.H. Critical evaluation of the 2D-CSIA scheme for distinguishing fuel oxygenate degradation reaction mechanisms. Environ. Sci. Technol. 2012, 46:4757-4766.
24. Danilchenko S.N., Kukharenko O.G., Moseke C., Protsenko I.Y., Sukhodub L.F., Sulkio-Cleff B. Determination of the bone mineral crystallite size and lattice strain from diffraction line broadening. Cryst. Res. Technol. 2002, 37:1234-1240.
25. 3 X-ray and neutron diffraction study. J. Phys. Chem. Solids 1971, 32:1315.
26. 3. Mater. Res. Bull. 1971, 6:23.
27. 3 nanoparticles by SBA-16 template method as high active visible photocatalysts. J. Nanopart. Res. 2010, 12:967-974.
28. Voelker B.M., Kwan W.P. Rates of hydroxyl radical generation and organic compound oxidation in mineral-catalyzed Fenton-like systems. Environ. Sci. Technol. 2003, 37:1150-1158.
29. 2 photo-oxidation. J. Hazard. Mater. 1999, 64:91-104.
30. Kwan W.P., Voelker B.M. Influence of electrostatics on the oxidation rates of organic compounds in heterogeneous Fenton systems. Environ. Sci. Technol. 2004, 38:3425-3431.
31. Xue X.F., Hanna K., Abdelmoula M., Deng N.S. Adsorption and oxidation of PCP on the surface of magnetite: kinetic experiments and spectroscopic investigations. Appl. Catal. B - Environ. 2009, 89:432-440.
32. Gonzalez-Olmos R., Holzer F., Kopinke F.D., Georgi A. Indications of the reactive species in a heterogeneous Fenton-like reaction using Fe-containing zeolites. Appl. Catal. A - Gen. 2011, 398:44-53.
33. N.O. Mwebi, Fenton & Fenton-like Reactions: The Nature of Oxidizing Intermediates Involved. Ph.D. Thesis. Faculty of the Graduate School of the University of Maryland, Maryland, 2005.
34. Elsner M. Stable isotope fractionation to investigate natural transformation mechanisms of organic contaminants: principles, prospects and limitations. J. Environ. Monit. 2010, 12:2005-2031.
35. Elsner M., Zwank L., Hunkeler D., Schwarzenbach R.P. A new concept linking observable stable isotope fractionation to transformation pathways of organic pollutants. Environ. Sci. Technol. 2005, 39:6896-6916.
36. 2 process. Environ. Sci. Technol. 2000, 34:650-658.
37. Pignatello J.J., Liu D., Huston P. Evidence for an additional oxidant in the photoassisted Fenton reaction. Environ. Sci. Technol. 1999, 33:1832-1839.
38. OH radicals from normal and carbon-deuterated ethyl alcohol and methylamine in aqueous solutions. J. Phys. Chem. B 2003, 107:7268-7276.
39. OH. J. Phys. Chem. 1989, 93:1944-1947.
40. Tully F.P. Hydrogen-atom abstraction from alkenes by OH, ethene and 1-butene. Chem. Phys. Lett. 1988, 143:510-514.
41. Mcmillen D.F., Golden D.M. Hydrocarbon bond-dissociation energies. Ann. Rev. Phys. Chem. 1982, 33:493-532.
42. Droege A.T., Tully F.P. Hydrogen-atom abstraction from alkanes by OH. 6. Cyclopentane and cyclohexane. J. Phys. Chem. 1987, 91:1222-1225.
43. 2O systems. Int. J. Chem. Kinet. 2011, 43:557-562.
44. J.S.N. Zhang, H. Herrmann, M. Rosell, S.H. Martín, H.H. Richnow, Book of Abstracts, Joint European Stable Isotope Users Group Meeting, JESIUM, Leipzig, 2012, p. 266.