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Volumn , Issue , 2007, Pages 109-146

Foldamer Hybrids: Defined Supramolecular Structures from Flexible Molecules

Author keywords

Applications of foldamer hybridization; Foldamer hybrids; Foldamers; Folding of unstructured molecules; Hybridization of oligomers; Large polymeric aggregates; Self assembly; Structure; Well defined structures

Indexed keywords


EID: 84889476896     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1002/9783527611478.ch4     Document Type: Chapter
Times cited : (4)

References (139)
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    • Even in fully flexible alkanes steric interactions such as the syn-pentane or the 1,3-allylic strain can induce specific conformations:
    • Even in fully flexible alkanes steric interactions such as the syn-pentane or the 1,3-allylic strain can induce specific conformations:R. W. Hoffmann, Angew. Chem. Int. Ed. 2000, 39, 2054-2070.
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    • In contrast to Coulomb interactions between two point charges which are of course non-directional, charge interactions with organic molecules such as guanidinium cations are directional. This can be due to the formation of H-bond enforced ion pairs and/or the anisotropic solvation of such ions:
    • In contrast to Coulomb interactions between two point charges which are of course non-directional, charge interactions with organic molecules such as guanidinium cations are directional. This can be due to the formation of H-bond enforced ion pairs and/or the anisotropic solvation of such ions: P. E. Mason, G. W. Neilson, J. E. Enderby, M.-L. Saboungi, C. E. Dempsey, A. D. MacKerell, Jr., J. W. Brady, J. Am. Chem. Soc. 2004, 126, 11462-114710;
    • (2004) J. Am. Chem. Soc. , vol.126 , pp. 11462-114710
    • Mason, P.E.1    Neilson, G.W.2    Enderby, J.E.3    Saboungi, M.-L.4    Dempsey, C.E.5    MacKerell Jr., A.D.6    Brady, J.W.7
  • 87
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    • For a general discussion of the directionality of noncovalent interactions see:
    • For a general discussion of the directionality of noncovalent interactions see: J. P. Glusker, Top. Curr. Chem. 1998, 198, 1-56.
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    • Glusker, J.P.1
  • 111
    • 0035969621 scopus 로고    scopus 로고
    • The structure of this amphiphilic 14-helix depends very much on the influence of the solvent and the used buffer. In 10 mM TRIS with a pH of 8.0 the system selfassociates most as a hexamer at a concentration of 1.7 mM. If an acetate buffer is used and the pH is adjusted to a value of 3.8 no clear classification can be done, except for the monomer at a concentration of 0.3 mM.
    • T. Raguse, J. Lai, P. LePlae, S. Gellman, Org. Lett. 2001, 3, 3963-3966.The structure of this amphiphilic 14-helix depends very much on the influence of the solvent and the used buffer. In 10 mM TRIS with a pH of 8.0 the system selfassociates most as a hexamer at a concentration of 1.7 mM. If an acetate buffer is used and the pH is adjusted to a value of 3.8 no clear classification can be done, except for the monomer at a concentration of 0.3 mM.
    • (2001) Org. Lett. , vol.3 , pp. 3963-3966
    • Raguse, T.1    Lai, J.2    LePlae, P.3    Gellman, S.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.