A principle for the assembly of novel mononuclear building blocks for supramolecular chemistry

Supramolecular Chemistry

Volumn 2, Issue 2-3, 1993, Pages 243-246

  Constable, E C ^a   Hannon, M J ^a   Cargill Thompson, A M W ^a   Tocher, D A ^b   Walker, J V ^a  

^a UNIVERSITY OF CAMBRIDGE   (United Kingdom)

^b UNIVERSITY COLLEGE LONDON   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84889209386     PISSN: 10610278     EISSN: 10290478     Source Type: Journal    
DOI: 10.1080/10610279308038322     Document Type: Article

References (32)

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31. Crystal data: C3 5H2 7F1 2N7 P2 Ru, triclinic, 1, a = 8.367(2), b = 11.821(4), c = 19.398(5)Å, α = 93.83(2), β = 95.25(2), γ = 89.62(2)°, V = 1906 Å3, M = 998.6, Z = 2, dc = 1.63 g cm -3, F(000) = 936, MoKa radiation, λ = 0.71073 Å, μ(MoKα) = 5.78 cm-1. The structure was solved by Patterson methods and refined by alternating cycles of least-squares refinement and difference-Fourier synthesis; Ru, C, N, P, F anisotropic; H atoms riding on appropriate carbon atom with fixed isotropic U. One of the PF6 anions is well-defined, but the second is characterized by anomalously high thermal parameters. As this anion makes no short intramolecular contacts this imperfect anisotropic model was accepted. 6886 reflections measured (5 < 2θ < 50°), corrected for absorption, 5084 unique observed reflections with I > 1.5σ(i), R = 0.0745, wR = 0.0771.
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