Measuring the isoelectric point of the edges of clay mineral particles: The case of montmorillonite

Langmuir

Volumn 29, Issue 48, 2013, Pages 14926-14934

  Pecini, Eliana M ^a   Avena, Marcelo J ^a  

^a UNIVERSIDAD NACIONAL DEL SUR   (Argentina)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTIVE CONCENTRATION; CATION EXCHANGE CAPACITIES; CLAY MINERAL PARTICLES; ELECTROLYTE CONCENTRATION; INTRINSIC REACTIVITY; ISO-ELECTRIC POINTS; POINT OF ZERO CHARGE; POTENTIOMETRIC TITRATIONS;

ADSORPTION; AROMATIC COMPOUNDS; ELECTRIC FIELDS; ELECTROPHORETIC MOBILITY; IONIC STRENGTH; ORGANIC POLYMERS; POSITIVE IONS; TITRATION;

CLAY MINERALS;

EID: 84888984420     PISSN: 07437463     EISSN: 15205827     Source Type: Journal    
DOI: 10.1021/la403384g     Document Type: Article

References (44)

1. Schulze, D. G. An Introduction to Soil Mineralogy. Minerals in Soil Environment; Dixon, J. B., Weed, S. B., Eds.; Soil Science Society America Book Series, No. 1; Soil Science Society of America: Madison, WI, 1989; pp 18.
2. Bleam, W. F. The nature of cation-substitution sites in phyllosilicates Clays Clay Miner. 1990, 38, 527-536
3. Secor, R. B.; Radke, C. J. Spillover of the diffuse double layer on montmorillonite particles J. Colloid Interface Sci. 1985, 103, 237-244
4. Chang, F. C.; Sposito, G. The electrical double layer of a disk-shaped clay mineral particle: Effect of particle size J. Colloid Interface Sci. 1994, 163, 19-27
5. Avena, M. J. Acid-base behavior of clay surfaces in aqueous media. Encyclopedia of Colloid Science; Somasundaran, P., Eds.; Taylor and Francis: New York, 2006; pp 17-46.
6. Kraepiel, A. M. L.; Keller, K.; Morel, F. M. M. On the acid-base chemistry of permanently charged minerals Environ. Sci. Technol. 1998, 32, 2829-2838
7. Tombácz, E.; Szekeres, M. Colloidal behaviour of aqueous montmorillonite suspensions: the specific role of pH in the presence of indifferent electrolytes Appl. Clay Sci. 2004, 27, 75-94
8. Lagaly, G.; Ziesmer, S. Colloid chemistry of clay minerals: the coagulation of montmorillonite dispersions Adv. Colloid Interface Sci. 2003, 100-102, 1205-128
9. Duc, M.; Gaboriaud, F.; Thomas, F. Sensitivity of acid-base properties of clays to the methods of preparation and measurement. 1. Literature review J. Colloid Interface Sci. 2005, 289, 139-147
10. Bourg, I. C.; Sposito, G.; Bourg, A. C. M. Modeling the acid-base surface chemistry of montmorillonite J. Colloid Interface Sci. 2007, 312, 297-310
11. Delhorme, M.; Labbez, C.; Caillet, C.; Thomas, F. Acid-Base properties of 2:1 clays. I. Modeling the role of electrostatics Langmuir. 2010, 26, 9240-9249
12. Lützenkirchen, J.; Preocanin, T.; Bauer, A.; Matz, V.; Sjöberg, S. Net surface proton excess of smectites obtained from a combination of potentiometric acid-base, mass and electrolyte titrations Colloids Surf. A 2012, 412, 11-19
13. Avena, M. J.; Mariscal, M. M.; De Pauli, C. P. Proton binding at clay surfaces in water Appl. Clay Sci. 2003, 24, 3-9
14. Avena, M. J.; Pauli, C. Proton adsorption and electrokinetics of an Argentinean montmorillonite J. Colloid Interface Sci. 1998, 202, 195-204
15. Keren, R.; Sparks, D. L The role of edge surfaces in flocculation of 2:1 clay minerals Soil Sci. Soc. Am. J. 1995, 59, 430-435
16. Delgado, A. V; Arroyo, F. J. Electrokinetic phenomena and their experimental determination: An Overview. In Interfacial electrokinetics and electrophoresis; Delgado, A. V., Ed.; Surfactant Science Series 106; Marcel Dekker: New York, 2002; pp 1-54.
17. Durán, J. D. G.; Ramos-Tejeda, M. M.; Arroyo, F. J.; González-Caballero, F. Rheological and electrokinetic properties of sodium montmorillonite suspensions: I. Rheological properties and interparticle energy of interaction J. Colloid Interface Sci. 2000, 229, 107-117
18. Avena, M. J.; Cabrol, R.; De Pauli, C. P. Study of some physicochemical properties of pillared montmorilonites: acid-base potentiometric titrations and electrophoretic measurements Clays Clay Miner. 1990, 38 (4) 356-362
19. Zadaka, D.; Radian, A.; Mishael, Y. G. Applying zeta potential measurements to characterize the adsorption on montmorillonite of organic cations as monomers, micelles, or polymers J. Colloid Interface Sci. 2010, 352, 171-177
20. Sondi, I.; Pravdic, V. Electrokinetics of pure clay minerals revisited J. Colloid Interface Sci. 1996, 181, 514-522
21. Thomas, F.; Michot, L. J.; Vantelon, D.; Montargès, E.; Prélot, B. Layer charge and electrophoretic mobility of smectites Colloids Surfaces A. 1999, 159, 351-358
22. Xia, L.; Zhong, H.; Liu, G.; Huang, Z.; Chang, Q.; Li, X. Comparative studies on flotation of Illite, pyrophyllite and kaolinite with Gemini and conventional cationic surfactants Trans. Nonferr. Metal Soc. China 2009, 19, 446-453
23. Bergmann, K.; O'Konski, C. T. A spectroscopy study of methylene blue monomer, dimer, and complexes with montmorillonite J. Phys. Chem. 1963, 67 (10) 2169-2177
24. Kahr, G.; Madsen, F. T. Determination of the cation exchange capacity and the surface area of bentonite, Illite and kaolinite by methylene blue adsorption App. Clay Sci. 1995, 9, 327-336
25. Meier, L. P.; Kahr, G. Determination of the cation exchange capacity (CEC) of clay minerals using the complex of copper (II) ion with triethyleneamine and tetraethyleneamine Clays Clay Miner. 1999, 47, 386-388
26. Yu, C.; Newton, S. Q.; Norman, M. A.; Miller, D. M.; Schäfer, L.; Brian, J. T. Molecular dynamics simulations of the adsorption of methylene blue at clay mineral surfaces Clays Clay Miner. 2000, 48, 665-681
27. Li, Z.; Chang, P.; Jiang, W.; Jean, J.; Hong, H. Mechanism of methylene blue removal from water by swelling clays Chem. Eng. J. 2011, 168, 1193-1200
28. Lombardi, B.; Baschini, M.; Torres Sánchez, R. M. Bentonite deposits of Northern Patagonia Appl. Clay Sci. 2003, 22, 309-12
29. Carr, J. D.; Vasiliades, J. Polyamine Substitution Reactions of Tris(2-aminoethyl)aminecopper(II) Inorg. Chem. 1972, 11 (9) 2104-2107
30. Rytwo, G.; Serban, C.; Nir, S.; Margulies, L. Use of methylene blue and crystal violet for determination of exchangeable cations in montmorillonite Clays Clay Miner. 1991, 39 (5) 551-555
31. Bujdák, J. Effect of the layer charge of clay minerals on optical properties of organic dyes. A review Appl. Clay Sci. 2006, 34, 58-73
32. Czímerová, A.; Bujdák, J.; Dohrmann, R. The aggregation of thionine and methylene blue dye in smectite dispersion Colloid Surf. A 2004, 243, 89-96
33. Cenens, J.; Schoonheydt, R. A. Visible spectroscopy of methylene blue on hectorite, laponite B and barasym in aqueous suspension Clays Clay Miner. 1988, 36, 214-224
34. Guy, R. D; Narine, D. R. Interactions of some large organic cations with bentonite in dilute aqueous systems Clays Clay Miner. 1981, 3, 205-212
35. Yariv, S.; Ghosh, D. K.; Hepler, G. Methechromasy in clay-mineral systems: adsorption of cationic dyes crystal violet and ethyl violet by kaolinite from aqueous and organic solutions J. Chem. Soc., Faraday Trans. 1991, 87, 1201-1207
36. Schoonheydt, R. A.; Heughebaert, L. Clay adsorbed dyes: methylene blue on laponite Clay Miner. 1991, 27, 91-100
37. Labbez, C.; Nonat, A.; Pochard, I.; Jönsson, B. Experimental and theoretical evidence of overcharging of calcium silicate hydrate J. Colloid Interface Sci. 2007, 309, 303-307
38. Czímerová, A.; Bujdák, J.; Dohrmann, R. Traditional and novel methods for estimating the layer charge of smectites Appl. Clay Sci. 2006, 34, 2-13
39. Ammann, L.; Bergaya, F.; Lagaly, G. Determination of the cation exchange capacity of clays with copper complex revisted Clay Miner. 2005, 40, 441-453
40. Miller, S. E.; Low, P. F. Characterization of the electrical double layer of montmorillonite Langmuir 1990, 6, 572-578
41. Sondi, I.; Milat, O.; Pravdic, V. Electrokinetic potentials of clay surfaces modified by polymers J. Colloid Interface Sci. 1997, 189, 66-73
42. Kaufhold, S.; Dohrmann, R. The variable charge of dioctahedral smectites J. Colloid Interface Sci. 2013, 390, 225-233
43. Lützenkirchen, J. Comparison of 1-pK and 2-pK versions of surface complexation theory by the goodness of fit in describing surface charge data of (hydr)oxides Environ. Sci. Technol. 1998, 32 (20) 3149-3154
44. Borkovec, M. Origin of 1-p K and 2-p K models for ionizable water-solid interfaces Langmuir 1997, 13, 2608-2613