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Volumn 5, Issue 1, 2014, Pages 136-140

Homochiral supramolecular polymerization of bowl-shaped chiral macrocycles in solution

Author keywords

[No Author keywords available]

Indexed keywords

HOMOCHIRAL; HYDROGEN BONDING INTERACTIONS; MACROCYCLES; SELF-SORTING; SUPRAMOLECULAR POLYMERIZATION; VAN DER WAALS;

EID: 84888582357     PISSN: 20416520     EISSN: 20416539     Source Type: Journal    
DOI: 10.1039/c3sc52449c     Document Type: Article
Times cited : (76)

References (32)
  • 3
    • 0003461218 scopus 로고    scopus 로고
    • in, ed. D. N. Reinhoudt, Pergamon, Oxford, 113-149
    • A. Collet, in Comprehensive Supramolecular Chemistry, ed., D. N. Reinhoudt, Pergamon, Oxford, 1996, vol. 10, pp. 113-149
    • (1996) Comprehensive Supramolecular Chemistry , vol.10
    • Collet, A.1
  • 25
    • 0000314051 scopus 로고
    • P. Wipf Chem. Rev. 1995 95 2115 2134
    • (1995) Chem. Rev. , vol.95 , pp. 2115-2134
    • Wipf, P.1
  • 32
    • 84857319239 scopus 로고    scopus 로고
    • Fig. 3c shows that the elution volume of a homochiral polymer formed with (R)- 1 at [(R)- 1] = 0.50 mM is 17.7 mL. If chiral self-sorting indeed occurs ideally, the elution volume should remain unchanged even when the same amount of its enantiomer ([(S)- 1] = 0.50 mM) is added. However, the observed value (16.4 mL), read out from Fig. 6c at [(S)- 1] = [(R)- 1] = 0.50 mM for the stereochemical copolymerization, is 1.3 mL smaller than 17.7 mL
    • T. Aida E. W. Meijer S. I. Stupp Science 2012 335 813 817
    • (2012) Science , vol.335 , pp. 813-817
    • Aida, T.1    Meijer, E.W.2    Stupp, S.I.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.