Steric effects and mechanism in the formation of hemi-acetals from aliphatic aldehydes

Journal of Physical Organic Chemistry

Volumn 26, Issue 12, 2013, Pages 1048-1057

  Daw, Graham ^a   Regan, Andrew C ^a   Watt, C Ian F ^a   Wood, Evan ^a  

^a UNIVERSITY OF MANCHESTER   (United Kingdom)

Author keywords

aliphatic aldehydes; mechanism; methyl hemi acetals; rates and equilibria; steric effects

Indexed keywords

ALIPHATIC ALDEHYDES; GROUND-STATE CONFORMATIONS; METHANOL SOLUTION; METHYL HEMI-ACETALS; STERIC EFFECT; STERIC INTERACTIONS; STERIC PARAMETERS; TRANSITION STRUCTURES;

CHLORINE COMPOUNDS; COPYRIGHTS; ENTROPY; EQUILIBRIUM CONSTANTS; ESTERIFICATION; ESTERS; HYDROLYSIS; ISOMERS; MECHANISMS; METHANOL; RATE CONSTANTS;

ALDEHYDES;

EID: 84888440840     PISSN: 08943230     EISSN: 10991395     Source Type: Journal    
DOI: 10.1002/poc.3138     Document Type: Article

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