Utilization of glycerol for the production of glycerol carbonate through greener route

Journal of Environmental Chemical Engineering

Volumn 1, Issue 4, 2013, Pages 1231-1236

  Lanjekar, Kavita ^a   Rathod, Virendra K ^a  

^a INSTITUTE OF CHEMICAL TECHNOLOGY   (India)

Author keywords

Dimethyl carbonate; Glycerol; Glycerol carbonate; Novozym 435; Synthesis; Transesterification

Indexed keywords

CO-SUBSTRATE; DIMETHYL CARBONATE; ENZYMATIC TRANSESTERIFICATION; GLYCEROL CARBONATE; INHIBITORY EFFECT; NOVOZYM435; RATE OF REACTION; TERTIARY BUTANOL;

CARBONATION; ENZYME ACTIVITY; METHANOL; MOLECULAR SIEVES; SYNTHESIS (CHEMICAL); TRANSESTERIFICATION;

GLYCEROL;

EID: 84888440339     PISSN: None     EISSN: 22133437     Source Type: Journal    
DOI: 10.1016/j.jece.2013.09.015     Document Type: Article

References (21)

1. T. Werpy, and G. Petersen Top Value Added Chemicals from Biomass vol. 1 2004 US Department of Energy (USDOE)
2. F. Strain, Carbonate-haloformate of glycerol and method of producing same. US Patent 2,446,145 (1948).
3. T. Mizuno, T. Nakai, and M. Mihara New synthesis of glycerol carbonate from glycerol using sulfur-assisted carbonylation with carbon monoxide Heteroatom Chem. 21 2 2010 99 102
4. T. Mizuno, T. Nakai, and M. Mihara Facile synthesis of glycerol carbonate from glycerol using selenium-catalyzed carbonylation with carbon monoxide Heteroatom Chem. 21 7 2010 541 545
5. 2(phen)/KI Appl. Catal. A: Gen. 386 2010 188 193
6. M. Aresta, A. Dibenedetto, F. Nocito, and C. Pastore A study on the carboxylation of glycerol to glycerol carbonate with carbon dioxide: the role of the catalyst, solvent and reaction conditions J. Mol. Catal. A: Chem. 257 2006 149 153
7. 2SnO as a catalyst J. Mol. Catal. A: Chem. 304 2009 1 7
8. 2 in the presence of zeolites and ion exchange resins Catal. Lett. 56 1998 245 247
9. C. Hammond, J.A. Lopez-Sanchez, M.H. Rahim, N. Dimitratos, R. Jenkins, A. Carley, Q. He, C. Kiely, D. Knight, and G. Hutchings Synthesis of glycerol carbonate from glycerol and urea with gold-based catalysts Dalton Trans. 40 2011 3927 3937
10. L. Wang, Y. Ma, Y. Wang, S. Liu, and Y. Deng Efficient synthesis of glycerol carbonate from glycerol and urea with lanthanum oxide as a solid base catalyst Catal. Commun. 12 2011 1458 1462
11. J.B. Bell, C.V. Arthur, 1959. Method for preparing glycerin carbonate, US patent 2915529.
12. Z. Mouloungui, J.W. Yoo, C.A. Gachen, A. Gaset, G. Vermeersch, 1996. Organisation Nationale Interprofessionnelle Des Oleagineux - Onidol. European patent EP 739888 A.
13. M.J. Climent, A. Corma, P.D. Frutos, S. Iborra, M. Noy, A. Velty, and P. Concepcion Chemicals from biomass: synthesis of glycerol carbonate by transesterification and carbonylation with urea with hydrotalcite catalysts: the role of acid-base pairs J. Catal. 269 2010 140 149
14. M. Alvarez, A. Segarra, S. Contreras, J. Sueiras, F. Medina, and F. Figueras Enhanced use of renewable resources: transesterification of glycerol catalyzed by hydrotalcite-like compounds Chem. Eng. J. 161 2010 340 345
15. J. Ochoa-Gomez, O. Gomez-Jimenez-Aberasturi, B. Maestro-Madurga, A. Pesquera-RodrIguez, C. RamIrez-Lopez, L. Lorenzo-Ibarreta, J. Torrecilla-Soria, and M.C. Villaran-Velasco Synthesis of glycerol carbonate from glycerol and dimethyl carbonate by transesterification: catalyst screening and reaction optimization Appl. Catal. A: Gen. 366 2009 315 324
16. A. Takagaki, K. Iwatani, S. Nishimura, and K. Ebitani Synthesis of glycerol carbonate from glycerol and dialkyl carbonates using hydrotalcite as a reusable heterogeneous base catalyst Green Chem. 12 2010 578 581
17. M. Malyaadri, K. Jagadeeswaraiah, P.S. Sai Prasad, and N. Lingaiah Synthesis of glycerol carbonate by transesterification of glycerol with dimethyl carbonate over Mg/Al/Zr catalysts Appl. Catal. A: Gen. 401 2011 153 157
18. F. Stefanus, H. Simanjuntaka, T. Kyung Kim, S. Deuk Lee, B. Sung Ahn, H. Sik Kim, and H. Lee CaO-catalyzed synthesis of glycerol carbonate from glycerol and dimethyl carbonate: isolation and characterization of an active Ca species Appl. Catal. A: Gen. 401 2011 220 225
19. S.C. Kim, Y.H. Kim, H. Lee, D.Y. Yoon, and B.K. Song Lipase-catalyzed synthesis of glycerol carbonate from renewable glycerol and dimethyl carbonate through transesterification J. Mol. Catal. B: Enzym. 49 2007 75 78
20. K.H. Lee, C. Park, and E.Y. Lee Biosynthesis of glycerol carbonate from glycerol by lipase in dimethyl carbonate as the solvent Bioprocess Biosyst. Eng. 33 2010 1059 1065
21. N. Sonare, and V.K. Rathod Transesterification of used sunflower oil using immobilized enzyme J. Mol. Catal. B: Enzym. 66 2010 142 147