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Volumn 110, Issue , 2013, Pages 641-645

Kinetic and thermodynamic aspects of the electrocatalysis of acid reduction in organic solvent using molecular diiron-dithiolate compounds

Author keywords

Hydrogen production; Hydrogenase model; Molecular electrocatalyst; Overpotential; Turnover frequency

Indexed keywords

ELECTROCATALYTIC EFFICIENCIES; HYDROGENASES; OVERPOTENTIAL; PTOLUENESULFONIC ACID; REDUCTION POTENTIAL; REVERSIBLE POTENTIAL; THERMODYNAMIC ASPECTS; TURNOVER FREQUENCY;

EID: 84888386179     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2013.05.048     Document Type: Article
Times cited : (22)

References (51)
  • 1
    • 77952596244 scopus 로고    scopus 로고
    • Electrochemical hydrogen production: Bridging homogeneous and heterogeneous catalysis
    • M.T.M. Koper, and E. Bouwman Electrochemical hydrogen production: bridging homogeneous and heterogeneous catalysis Angewandte Chemie International Edition 49 2010 3723 3725
    • (2010) Angewandte Chemie International Edition , vol.49 , pp. 3723-3725
    • Koper, M.T.M.1    Bouwman, E.2
  • 4
    • 0012029590 scopus 로고
    • Electrochemical reduction of protonated cyclopentadienylcobalt phosphine complexes
    • U. Koelle, and S. Paul Electrochemical reduction of protonated cyclopentadienylcobalt phosphine complexes Inorganic Chemistry 25 1986 2689 2694
    • (1986) Inorganic Chemistry , vol.25 , pp. 2689-2694
    • Koelle, U.1    Paul, S.2
  • 5
    • 0029882335 scopus 로고    scopus 로고
    • Homogeneous catalysis of electrochemical hydrogen evolution by iron(0) porphyrins
    • I. Bhugun, D. Lexa, and J.-M. Savéant Homogeneous catalysis of electrochemical hydrogen evolution by iron(0) porphyrins Journal of the American Chemical Society 118 1996 3982 3983
    • (1996) Journal of the American Chemical Society , vol.118 , pp. 3982-3983
    • Bhugun, I.1    Lexa, D.2    Savéant, J.-M.3
  • 8
    • 84857603373 scopus 로고    scopus 로고
    • Catalysts made of earth-abundant elements (Co, Ni, Fe) for water splitting: Recent progress and future challenges
    • P. Du, and R. Eisenberg Catalysts made of earth-abundant elements (Co, Ni, Fe) for water splitting: recent progress and future challenges Energy & Environmental Science 5 2012 6012 6021
    • (2012) Energy & Environmental Science , vol.5 , pp. 6012-6021
    • Du, P.1    Eisenberg, R.2
  • 9
    • 84867026878 scopus 로고    scopus 로고
    • Proton reduction to hydrogen in biological and chemical systems
    • P.D. Tran, and J. Barber Proton reduction to hydrogen in biological and chemical systems Physical Chemistry Chemical Physics 14 2012 13772 13784
    • (2012) Physical Chemistry Chemical Physics , vol.14 , pp. 13772-13784
    • Tran, P.D.1    Barber, J.2
  • 10
    • 84860374319 scopus 로고    scopus 로고
    • Recent progress in electrochemical hydrogen production with earth-abundant metal complexes as catalysts
    • M. Wang, L. Chen, and L. Sun Recent progress in electrochemical hydrogen production with earth-abundant metal complexes as catalysts Energy & Environmental Science 5 2012 6763 6778
    • (2012) Energy & Environmental Science , vol.5 , pp. 6763-6778
    • Wang, M.1    Chen, L.2    Sun, L.3
  • 11
    • 84874479302 scopus 로고    scopus 로고
    • Complexes of earth-abundant metals for catalytic electrochemical hydrogen generation under aqueous conditions
    • 10.1039/C2CS35272A
    • V.S. Thoi, Y. Sun, J.R. Long, and C.J. Chang Complexes of earth-abundant metals for catalytic electrochemical hydrogen generation under aqueous conditions Chemical Society Reviews 2013 10.1039/C2CS35272A
    • (2013) Chemical Society Reviews
    • Thoi, V.S.1    Sun, Y.2    Long, J.R.3    Chang, C.J.4
  • 13
    • 0142244261 scopus 로고    scopus 로고
    • Chemistry and the hydrogenases
    • D.J. Evans, and C.J. Pickett Chemistry and the hydrogenases Chemical Society Reviews 32 2003 268 275 (Pubitemid 38337433)
    • (2003) Chemical Society Reviews , vol.32 , Issue.5 , pp. 268-275
    • Evans, D.J.1    Pickett, C.J.2
  • 14
    • 23644445642 scopus 로고    scopus 로고
    • 2 evolution by di-iron sub-site models
    • DOI 10.1016/j.ccr.2004.11.018, PII S0010854504002905
    • J.F. Capon, F. Gloaguen, P. Schollhammer, and J. Talarmin Catalysis of the electrochemical h2 evolution by di-iron sub-site models Coordination Chemistry Reviews 249 2005 1664 1676 (Pubitemid 41116339)
    • (2005) Coordination Chemistry Reviews , vol.249 , Issue.1516 SPEC. ISSUE. , pp. 1664-1676
    • Capon, J.-F.1    Gloaguen, F.2    Schollhammer, P.3    Talarmin, J.4
  • 16
    • 57649243216 scopus 로고    scopus 로고
    • Small molecule mimics of hydrogenases: Hydrides and redox
    • F. Gloaguen, and T.B. Rauchfuss Small molecule mimics of hydrogenases: hydrides and redox Chemical Society Reviews 38 2009 100 108
    • (2009) Chemical Society Reviews , vol.38 , pp. 100-108
    • Gloaguen, F.1    Rauchfuss, T.B.2
  • 17
    • 67649283572 scopus 로고    scopus 로고
    • Functional analogues of the active sites of the [Fe]-, [NiFe]-, and [FeFe]-hydrogenases
    • C. Tard, C.J. Pickett, and Structural functional analogues of the active sites of the [Fe]-, [NiFe]-, and [FeFe]-hydrogenases Chemical Reviews 109 2009 2245 2274
    • (2009) Chemical Reviews , vol.109 , pp. 2245-2274
    • Tard, C.1    Pickett, C.J.2    Structural3
  • 19
    • 0035955213 scopus 로고    scopus 로고
    • Biomimetic hydrogen evolution catalyzed by an iron carbonyl thiolate [17]
    • DOI 10.1021/ja016516f
    • F. Gloaguen, J.D. Lawrence, and T.B. Rauchfuss Biomimetic hydrogen evolution catalyzed by an iron carbonyl thiolate Journal of the American Chemical Society 123 2001 9476 9477 (Pubitemid 32900331)
    • (2001) Journal of the American Chemical Society , vol.123 , Issue.38 , pp. 9476-9477
    • Gloaguen, F.1    Lawrence, J.D.2    Rauchfuss, T.B.3
  • 22
    • 84863090274 scopus 로고    scopus 로고
    • Electrochemical hydrogen production in aqueous micellar solution by a diiron benzenedithiolate complex relevant to [FeFe] hydrogenases
    • F. Quentel, G. Passard, and F. Gloaguen Electrochemical hydrogen production in aqueous micellar solution by a diiron benzenedithiolate complex relevant to [FeFe] hydrogenases Energy & Environmental Science 5 2012 7757 7761
    • (2012) Energy & Environmental Science , vol.5 , pp. 7757-7761
    • Quentel, F.1    Passard, G.2    Gloaguen, F.3
  • 23
    • 84867210078 scopus 로고    scopus 로고
    • A binuclear iron-thiolate catalyst for electrochemical hydrogen production in aqueous micellar solution
    • F. Quentel, G. Passard, and F. Gloaguen A binuclear iron-thiolate catalyst for electrochemical hydrogen production in aqueous micellar solution Chemistry - A European Journal 18 2012 13473 13479
    • (2012) Chemistry - A European Journal , vol.18 , pp. 13473-13479
    • Quentel, F.1    Passard, G.2    Gloaguen, F.3
  • 25
    • 84863229565 scopus 로고    scopus 로고
    • Artificial photosynthetic systems based on [FeFe]-hydrogenase mimics: The road to high efficiency for light-driven hydrogen evolution
    • F. Wang, W.-G. Wang, H.-Y. Wang, G. Si, C.-H. Tung, and L.-Z. Wu Artificial photosynthetic systems based on [FeFe]-hydrogenase mimics: the road to high efficiency for light-driven hydrogen evolution ACS Catalysis 2 2012 407 416
    • (2012) ACS Catalysis , vol.2 , pp. 407-416
    • Wang, F.1    Wang, W.-G.2    Wang, H.-Y.3    Si, G.4    Tung, C.-H.5    Wu, L.-Z.6
  • 26
    • 61549134543 scopus 로고    scopus 로고
    • Electron and proton transfers at diiron dithiolate sites relevant to the catalysis of proton reduction by the [FeFe]-hydrogenases
    • J.F. Capon, F. Gloaguen, F.Y. Pétillon, P. Schollhammer, and J. Talarmin Electron and proton transfers at diiron dithiolate sites relevant to the catalysis of proton reduction by the [FeFe]-hydrogenases Coordination Chemistry Reviews 253 2009 1476 1494
    • (2009) Coordination Chemistry Reviews , vol.253 , pp. 1476-1494
    • Capon, J.F.1    Gloaguen, F.2    Pétillon, F.Y.3    Schollhammer, P.4    Talarmin, J.5
  • 28
    • 33747177614 scopus 로고    scopus 로고
    • Activation of proton by the two-electron reduction of a di-iron organometallic complex
    • DOI 10.1016/j.jelechem.2006.06.005, PII S002207280600338X
    • J.F. Capon, F. Gloaguen, P. Schollhammer, and J. Talarmin Activation of proton by the two-electron reduction of a di-iron organometallic complex Journal of Electroanalytical Chemistry 595 2006 47 52 (Pubitemid 44233610)
    • (2006) Journal of Electroanalytical Chemistry , vol.595 , Issue.1 , pp. 47-52
    • Capon, J.-F.1    Gloaguen, F.2    Schollhammer, P.3    Talarmin, J.4
  • 29
    • 33947727517 scopus 로고    scopus 로고
    • Electrochemical proton reduction at mild potentials by monosubstituted diiron organometallic complexes bearing a benzenedithiolate bridge
    • DOI 10.1016/j.jelechem.2007.02.003, PII S0022072807000654
    • F. Gloaguen, D. Morvan, J.F. Capon, P. Schollhammer, and J. Talarmin Electrochemical proton reduction at mild potentials by monosubstituted diiron organometallic complexes bearing a benzenedithiolate bridge Journal of Electroanalytical Chemistry 603 2007 15 20 (Pubitemid 46507503)
    • (2007) Journal of Electroanalytical Chemistry , vol.603 , Issue.1 , pp. 15-20
    • Gloaguen, F.1    Morvan, D.2    Capon, J.-F.3    Schollhammer, P.4    Talarmin, J.5
  • 32
    • 84867808441 scopus 로고    scopus 로고
    • Multielectron-transfer templates via consecutive two-electron transformations: Iron-sulfur complexes relevant to biological enzymes
    • L. Chen, M. Wang, F. Gloaguen, D. Zheng, P. Zhang, and L. Sun Multielectron-transfer templates via consecutive two-electron transformations: iron-sulfur complexes relevant to biological enzymes Chemistry - A European Journal 18 2012 13968 13973
    • (2012) Chemistry - A European Journal , vol.18 , pp. 13968-13973
    • Chen, L.1    Wang, M.2    Gloaguen, F.3    Zheng, D.4    Zhang, P.5    Sun, L.6
  • 35
    • 77949402382 scopus 로고    scopus 로고
    • Electronic and geometric effects of phosphatriazaadamantane ligands on the catalytic activity of an [FeFe] hydrogenase inspired complex
    • A.K. Vannucci, S. Wang, G.S. Nichol, D.L. Lichtenberger, D.H. Evans, and R.S. Glass Electronic and geometric effects of phosphatriazaadamantane ligands on the catalytic activity of an [FeFe] hydrogenase inspired complex Dalton Transactions 39 2010 3050 3056
    • (2010) Dalton Transactions , vol.39 , pp. 3050-3056
    • Vannucci, A.K.1    Wang, S.2    Nichol, G.S.3    Lichtenberger, D.L.4    Evans, D.H.5    Glass, R.S.6
  • 36
    • 84857180637 scopus 로고    scopus 로고
    • Photoelectrochemical hydrogen generation by an [FeFe] hydrogenase active site mimic at a p-type silicon/molecular electrocatalyst junction
    • B. Kumar, M. Beyler, C.P. Kubiak, and S. Ott Photoelectrochemical hydrogen generation by an [FeFe] hydrogenase active site mimic at a p-type silicon/molecular electrocatalyst junction Chemistry - A European Journal 18 2012 1295 1298
    • (2012) Chemistry - A European Journal , vol.18 , pp. 1295-1298
    • Kumar, B.1    Beyler, M.2    Kubiak, C.P.3    Ott, S.4
  • 37
    • 84861941954 scopus 로고    scopus 로고
    • Electron delocalization from the fullerene attachment to the diiron core within the active-site mimics of [FeFe]hydrogenase
    • Y.-C. Liu, T.-H. Yen, Y.-J. Tseng, C.-H. Hu, G.-H. Lee, and M.-H. Chiang Electron delocalization from the fullerene attachment to the diiron core within the active-site mimics of [FeFe]hydrogenase Inorganic Chemistry 51 2012 5997 5999
    • (2012) Inorganic Chemistry , vol.51 , pp. 5997-5999
    • Liu, Y.-C.1    Yen, T.-H.2    Tseng, Y.-J.3    Hu, C.-H.4    Lee, G.-H.5    Chiang, M.-H.6
  • 38
    • 36348951916 scopus 로고    scopus 로고
    • Electrochemical synthesis of mono- and disubstituted diiron dithiolate complexes as models for the active site of iron-only hydrogenases
    • D. Morvan, J.F. Capon, F. Gloaguen, P. Schollhammer, and J. Talarmin Electrochemical synthesis of mono- and disubstituted diiron dithiolate complexes as models for the active site of iron-only hydrogenases European Journal of Inorganic Chemistry 2007 5062 5068
    • (2007) European Journal of Inorganic Chemistry , pp. 5062-5068
    • Morvan, D.1    Capon, J.F.2    Gloaguen, F.3    Schollhammer, P.4    Talarmin, J.5
  • 39
    • 68849087997 scopus 로고    scopus 로고
    • One- to two-electron reduction of an [FeFe]-hydrogenase active site mimic: The critical role of fluxionality of the [2Fe2S] core
    • G.A.N. Felton, B.J. Petro, R.S. Glass, D.L. Lichtenberger, and D.H. Evans One- to two-electron reduction of an [FeFe]-hydrogenase active site mimic: the critical role of fluxionality of the [2Fe2S] core Journal of the American Chemical Society 131 2009 11290 11291
    • (2009) Journal of the American Chemical Society , vol.131 , pp. 11290-11291
    • Felton, G.A.N.1    Petro, B.J.2    Glass, R.S.3    Lichtenberger, D.L.4    Evans, D.H.5
  • 40
    • 78149344910 scopus 로고    scopus 로고
    • H2 evolution and molecular electrocatalysts: Determination of overpotentials and effect of homoconjugation
    • V. Fourmond, P.-A. Jacques, M. Fontecave, and V. Artero H2 evolution and molecular electrocatalysts: determination of overpotentials and effect of homoconjugation Inorganic Chemistry 49 2010 10338 10347
    • (2010) Inorganic Chemistry , vol.49 , pp. 10338-10347
    • Fourmond, V.1    Jacques, P.-A.2    Fontecave, M.3    Artero, V.4
  • 41
    • 33751297588 scopus 로고    scopus 로고
    • Iron-only hydrogenase mimics. Thermodynamic aspects of the use of electrochemistry to evaluate catalytic efficiency for hydrogen generation
    • G.A.N. Felton, R.S. Glass, D.L. Lichtenberger, and D.H. Evans Iron-only hydrogenase mimics. Thermodynamic aspects of the use of electrochemistry to evaluate catalytic efficiency for hydrogen generation Inorganic Chemistry 45 2006 9181 9184
    • (2006) Inorganic Chemistry , vol.45 , pp. 9181-9184
    • Felton, G.A.N.1    Glass, R.S.2    Lichtenberger, D.L.3    Evans, D.H.4
  • 42
    • 0013326691 scopus 로고    scopus 로고
    • A review of the problem of distinguishing true homogeneous catalysis from soluble or other metal-particle heterogeneous catalysis under reducing conditions
    • J.A. Widegren, and R.G. Finke A review of the problem of distinguishing true homogeneous catalysis from soluble or other metal-particle heterogeneous catalysis under reducing conditions Journal of Molecular Catalysis A: Chemical 198 2003 317 341
    • (2003) Journal of Molecular Catalysis A: Chemical , vol.198 , pp. 317-341
    • Widegren, J.A.1    Finke, R.G.2
  • 43
    • 84874474269 scopus 로고    scopus 로고
    • Solar fuels generation and molecular systems: Is it homogeneous or heterogeneous catalysis?
    • V. Artero, and M. Fontecave Solar fuels generation and molecular systems: is it homogeneous or heterogeneous catalysis? Chemical Society Reviews 42 2013 2338 2356
    • (2013) Chemical Society Reviews , vol.42 , pp. 2338-2356
    • Artero, V.1    Fontecave, M.2
  • 44
    • 0040401549 scopus 로고
    • Theory of stationary electrode polarography. Single scan and cyclic methods applied to reversible, irreversible, and kinetic systems
    • R.S. Nicholson, and I. Shain Theory of stationary electrode polarography. Single scan and cyclic methods applied to reversible, irreversible, and kinetic systems Analytical Chemistry 36 1964 706 723
    • (1964) Analytical Chemistry , vol.36 , pp. 706-723
    • Nicholson, R.S.1    Shain, I.2
  • 45
    • 80052859531 scopus 로고    scopus 로고
    • Kinetics and limiting current densities of homogeneous and heterogeneous electrocatalysts
    • A.J. Sathrum, and C.P. Kubiak Kinetics and limiting current densities of homogeneous and heterogeneous electrocatalysts The Journal of Physical Chemistry Letters 2 2011 2372 2379
    • (2011) The Journal of Physical Chemistry Letters , vol.2 , pp. 2372-2379
    • Sathrum, A.J.1    Kubiak, C.P.2
  • 47
    • 84861381286 scopus 로고    scopus 로고
    • Hydrogen generation catalyzed by fluorinated diglyoxim-iron complexes at low overpotentials
    • M.J. Rose, H.B. Gray, and J.R. Winkler Hydrogen generation catalyzed by fluorinated diglyoxim-iron complexes at low overpotentials Journal of the American Chemical Society 134 2012 8310 8313
    • (2012) Journal of the American Chemical Society , vol.134 , pp. 8310-8313
    • Rose, M.J.1    Gray, H.B.2    Winkler, J.R.3
  • 50
    • 84863827014 scopus 로고    scopus 로고
    • Turnover numbers, turnover frequencies, and overpotential in molecular catalysis of electrochemical reactions. Cyclic voltammetry and preparative-scale electrolysis
    • C. Costentin, S. Drouet, M. Robert, and J.-M. Savéant Turnover numbers, turnover frequencies, and overpotential in molecular catalysis of electrochemical reactions. Cyclic voltammetry and preparative-scale electrolysis Journal of the American Chemical Society 134 2012 11235 11242
    • (2012) Journal of the American Chemical Society , vol.134 , pp. 11235-11242
    • Costentin, C.1    Drouet, S.2    Robert, M.3    Savéant, J.-M.4
  • 51
    • 84870895402 scopus 로고    scopus 로고
    • "turning over" Definitions in catalytic cycles
    • S. Kozuch, and J.M.L. Martin "Turning over" Definitions in catalytic cycles ACS Catalysis 2 2012 2787 2794
    • (2012) ACS Catalysis , vol.2 , pp. 2787-2794
    • Kozuch, S.1    Martin, J.M.L.2


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