A multiscale physical model of a polymer electrolyte membrane water electrolyzer

Electrochimica Acta

Volumn 110, Issue , 2013, Pages 363-374

  Oliveira, Luiz Fernando L ^a   Jallut, Christian ^b,e   Franco, Alejandro A ^a,c,d  

^a CEA GRENOBLE   (France)

^b UNIVERSITÉ LYON 1   (France)

^c UNIVERSITÉ DE PICARDIE JULES VERNE   (France)

^d CNRS   (France)

^e UNIVERSITÉ PAUL SABATIER   (France)

Author keywords

Hydrogen production; Multiscale modeling; PEMWEs; Transition metal oxides; Water electrolysis

Indexed keywords

MEMBRANE ELECTRODES ASSEMBLIES; MULTI-SCALE MODELING; OPERATION CONDITIONS; PEMWES; POLYMER ELECTROLYTE MEMBRANES; SENSITIVITY STUDIES; TRANSITION-METAL OXIDES; WATER ELECTROLYSIS;

CATALYSTS; ELECTROLYTIC CELLS; HYDROGEN; HYDROGEN PRODUCTION;

POLYELECTROLYTES;

EID: 84888376003     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2013.07.214     Document Type: Article

References (49)

1. R. de Levie The electrolysis of water J. Electroanal. Chem. 476 1999 92
2. A. Marshall, B. Borresen, G. Hagen, M. Tsypkin, and R. Tunold Hydrogen production by advanced proton exchange membrane (PEM) water electrolyser - reduced energy consumption by improved electrocatalysis Energy 32 2007 431 436 (Pubitemid 44959539)
3. E. Rasten, G. Hagen, and R. Tunold Electrocatalysis in water electrolysis with solid polymer electrolyte Electrochim. Acta 48 2003 3945 3952
4. P. Millet, R. Ngameni, S.A. Grigoriev, N. Mbemba, F. Brisset, A. Ranjbari, and C. Etiévant PEM water electrolyzers: from electrocatalysis to stack development Int. J. Hydrogen Energy 35 2010 5043 5052
5. W.T. Grubb Batteries with solid ion-exchange electrolytes J. Electrochem. Soc. 106 1959 275 278
6. U.D. of Energy Solid polymer electrolyte water electrolysis technology development for large-scale hydrogen production 1981 DOE/ET/26 202-1
7. F. Barbir PEM electrolysis for production of hydrogen from renewable energy sources Solar Energy 78 2005 661 669
8. Giner, 2013. Available on http://www.ginerinc.com.
9. ProntoOnSite, 2013. Available on http://www.protonsite.com.
10. Ceth, 2013. Available online on www.ceth.fr.
11. Hydrogenics, 2013. Available on http://www.hydrogenics.com.
12. P. Millet, M. Pineri, and R. Durand New solid polymer electrolyte composite for water electrolysis J. Appl. Electrochem. 19 1989 162 166
13. A.A. Franco, Y. Suzue, R.F. de Morais, A. Kachmar, T. Mashio, A. Ohma, and K. Shinohara Multiscale modeling of electrochemical double layer formation on Pt electrodes covered by Nafion Abstract 226, 221st ECS Meeting Seattle, WA 2012
14. D.D. Borges, S. Mossa, K. Malek, G. Gebel, and A.A. Franco Effect of surface hydrophilicity on the formation of Nafion thin films inside PEMFCs catalyst layers: a computational study ECS Trans. 45 2013
15. S. Song, H. Zhang, X. Ma, Z. Shao, R.T. Baker, and B. Yi Electrochemical investigation of electrocatalysts for the oxygen evolution reaction in PEM water electrolyzers Int. J. Hydrogen Energy 33 2008 4955 4961
16. H. Ito, T. Maeda, A. Nakano, and H. Takenaka Properties of nafion membranes under PEM water electrolysis conditions Int. J. Hydrogen Energy 1 2011 1 14
17. S. Becker, and V. Karri Predictive models for PEM-electrolyzer performance using adaptive neuro-fuzzy inference systems Int. J. Hydrogen Energy 35 2010 9963 9972
18. O. Atlam, and M. Kolhe Equivalent electrical model for a proton exchange membrane (PEM) electrolyser Energy Convers. Manage. 52 2011 2952 2957
19. S. Busquet, C. Hubert, J. Labbe, D. Mayer, and R. Metkemeijer A new approach to empirical electrical modelling of a fuel cell, an electrolyser or a regenerative fuel cell J. Power Sources 134 2004 41 48 (Pubitemid 41331334)
20. P. Choi, D.G. Bessarabov, and R. Datta A simple model for solid polymer electrolyte (SPE) water electrolysis Solid State Ionics 175 2004 535 539
21. K. Onda, T. Murakami, T. Hikosaka, M. Kobayashi, R. Notu, and K. Ito Performance analysis of polymer-electrolyte water electrolysis cell at a small-unit test cell and performance prediction of large stacked cell J. Electrochem. Soc. 149 2002 A1069 A1078
22. K.S. Agbli, M.C. Péra, D. Hissel, O. Rallières, C. Turpin, and I. Doumbia Multiphysics simulation of a PEM electrolyser: energetic macroscopic representation approach Int. J. Hydrogen Energy 36 2011 1382 1398
23. F. Marangio, M. Santarelli, and M. Calì Theoretical model and experimental analysis of a high pressure PEM water electrolyser for hydrogen production Int. J. Hydrogen Energy 34 2009 1143 1158
24. S.A. Grigoriev, A.A. Kalinnikov, P. Millet, V.I. Porembsky, and V.N. Fateev Mathematical modeling of high-pressure PEM water electrolysis J. Appl. Electrochem. 40 2010 921 932
25. L.F.L. Oliveira, S. Laref, E. Mayousse, C. Jallut, and A.A. Franco A multiscale physical model for the transient analysis of PEM water electrolyzer anodes Phys. Chem. Chem. Phys. 14 2012 10215 10224
26. A.A. Franco, P. Schott, C. Jallut, and B. Maschke A dynamic mechanistic model of an electrochemical interface J. Electrochem. Soc. 153 2006 A1053 A1061
27. A.A. Franco, P. Schott, C. Jallut, and B. Maschke A multi-scale dynamic mechanistic model for the transient analysis of PEFCs Fuel Cells 07 2007 99 117 (Pubitemid 47166931)
28. A.A. Franco Un modèle physique multiéchelle de la dynamique électrochimique dans une pile à combustible à électrolyte polymère 2005 Université Claude Bernard Lyon 1 (Ph.D. Thesis)
29. A.A. Franco A multiscale modeling framework for the transient analysis of PEM fuel cells - from the fundamentals to the engineering practice 2010 Université Claude Bernard Lyon 1 Habilitation (H.D.R.) manuscript
30. A.A. Franco PEMFCs degradation modeling and analysis C. Harting, C. Roth, Polymer Electrolyte Membrane and Direct Methanol Fuel Cell Technology (PEMFCs and DMFCs) - vol. 1: Fundamentals and Performance 2012 Woodhead Cambridge, UK
31. A.A. Franco A multiscale physical model of electrochemical storage systems ECS Trans. 45 2013 11 19
32. A.A. Franco Multiscale modeling and numerical simulation of rechargeable lithium ion batteries: concepts, methods and challenges RSC Adv. 3 32 2013 13027 13058
33. A.A. Franco, and M. Tembely Transient multiscale model of aging mechanisms in a PEFC cathode J. Electrochem. Soc. 154 2007 B712 B723
34. y catalysts degradation in PEFC environments: mechanistic insights J. Electrochem. Soc. 156 2009 B410 B424
35. R.F. Morais, P. Sautet, D. Loffreda, and A.A. Franco A multiscale theoretical methodology for the calculation of electrochemical observables from ab initio data Electrochim. Acta 2011 10842 10856
36. L.F.L. Oliveira, A.A. Franco, C. Jallut, D. Loffreda, Paper in preparation, 2013.
37. J. Rossmeisl, Z.-W. Qu, H. Zhu, G.J. Kroes, and J.K. Norskov Electrolysis of water on oxide surfaces J. Electroanal. Chem. 607 2007 83 89 (Pubitemid 47175942)
38. 2 density-functional calculations Phys. Rev. B 70 2004 235402
39. R.B. Bird, W.E. Stewart, and E.N. Lightfoot Transport Phenomena 2002 John Wiley and Sons New Yark
40. A.A. Franco, and K. Malek Microstrucure-based modeling of aging mechanisms in catalyst layers of polymer electrolyte fuel cells J. Phys. Chem. B 115 2011 8088 8101
41. F. Meier, and G. Eigenberger Transport parameters for the modelling of water transport in ionomer membranes for PEM-fuel cells Electrochim. Acta 49 2004 1731 1742
42. J.O. Bockris, and S. Khan Surface Electrochemistry: A Molecular Level Approach 1993 Plenum Press New Yark; London
43. H. Ito, T. Maeda, A. Nakano, Y. Hasegawa, N. Yokoi, C.M. Hwang, M. Ishida, A. Kato, and T. Yoshida Effect of flow regime of circulating water on a proton exchange membrane electrolyzer Int. J. Hydrogen Energy 35 2010 9550 9560
44. E. Mayousse, F. Maillard, F. Fouda-Onana, O. Sicardy, and N. Guillet Synthesis and characterization of electrocatalysts for the oxygen evolution in PEM water electrolysis Int. J. Hydrogen Energy 36 2011 10474 10481
45. L. Ma, S. Sui, and Y. Zhai Investigations on high performance proton exchange membrane water electrolyzer Int. J. Hydrogen Energy 34 2009 678 684
46. 2 powders as oxygen evolution electrocatalysts Electrochimica Acta 51 2006 3161 3167
47. A.A. Franco Polymer Electrolyte Fuel Cells: Science, Applications and Challenges, 2013 Pan Stanford Publishing Singapore
48. A.A. Franco Multiscale modeling of electrochemical devices for energy conversion and storage R. Savinell, K.I. Ota, G. Kreysa, Encyclopedia of Applied Electrochemistry 2013 Springer UK
49. A.A. Franco, and M. Gerard Transient model of carbon catalyst-support corrosion in a PEFC: multi-scale coupling with electro-catalysis and impact on performance degradation J. Electrochem. Soc. 155 4 2008 B367