Mechanistic studies on the selective oxidative carbonylation of MeOH to dimethyl oxalate catalyzed by [Pd(COOMe)n(TsO)2-n(PPh 3)2] (n = 0, 1, 2) using p-benzoquinone as a stoichiometric oxidant

Journal of Organometallic Chemistry

Volumn 750, Issue , 2014, Pages 74-79

  Amadio, Emanuele ^a   Toniolo, Luigi ^a  

^a CA' FOSCARI UNIVERSITY OF VENICE   (Italy)

Author keywords

Benzoquinone; Methanol oxidative carbonylation; Oxalate; Palladium

Indexed keywords

BENZOQUINONES; CATALYTIC CYCLES; DIMETHYL CARBONATE; DIMETHYL OXALATE; MECHANISTIC STUDIES; OXALATE; OXIDATIVE CARBONYLATION; STOICHIOMETRIC OXIDANT;

CARBONYLATION; CATALYSIS; CHLORINE COMPOUNDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXALIC ACID; OXIDANTS; PALLADIUM;

PALLADIUM COMPOUNDS;

EID: 84888241495     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2013.11.009     Document Type: Article

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