Prediction of the removal efficiency of pharmaceuticals by a rapid spectrophotometric method using Rhodamine B in the UV/H2O2 process

Chemical Engineering Journal

Volumn 236, Issue , 2014, Pages 438-447

  Kwon, Minhwan ^a   Kim, Seonbaek ^a   Yoon, Yeojoon ^a   Jung, Youmi ^a   Hwang, Tae Mun ^b   Kang, Joon Wun ^a  

^a Yonsei University Wonju   (South Korea)

^b Korea Institute of Civil Engineering and Building Technology   (South Korea)

Author keywords

Advanced oxidation process; OH radical; Pharmaceutical; Rhodamine B; Scavenging factor

Indexed keywords

DEGRADATION; DRUG PRODUCTS; EFFICIENCY; FORECASTING; FREE RADICALS; RHODIUM COMPOUNDS; SPECTROPHOTOMETERS; SPECTROPHOTOMETRY;

ACCURATE MEASUREMENT; ADVANCED OXIDATION PROCESSES; AVERAGE DEVIATION; EFFICIENCY OF REMOVAL; OH RADICAL; REMOVAL EFFICIENCIES; SPECTRO-PHOTOMETRIC METHOD; SYNTHETIC SOLUTIONS;

RHODAMINE B;

EID: 84888006653     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2013.10.064     Document Type: Article

References (36)

1. Daughton C.G., Ternes T.A. Pharmaceuticals and personal care products in the environment: agents of subtle change?. Environ. Health Perspect. 1999, 107:907-938.
2. Halling-Sorensen B., Nielsen S.N., Lanzky P.F., Ingerslev F., Lutzhoft H.C.H., Jorgensen S.E. Occurrence, fate and effects of pharmaceutical substances in the environment - a review. Chemosphere 1998, 36:357-394.
3. Pereira V.J., Linden K.G., Weinberg H.S. Evaluation of UV irradiation for photolytic and oxidative degradation of pharmaceutical compounds in water. Water Res. 2007, 41:4413-4423.
4. Gao Y.Q., Gao N.Y., Deng Y., Yang Y.Q., Ma Y. Ultraviolet (UV) light-activated persulfate oxidation of sulfamethazine in water. Chem. Eng. J. 2012, 195:248-253.
5. Yoon Y., Ryu J., Oh J., Choi B.G., Snyder S.A. Occurrence of endocrine disrupting compounds, pharmaceuticals, and personal care products in the Han River (Seoul, South Korea). Sci. Total Environ. 2010, 408:636-643.
6. Kim I., Tanaka H. Photodegradation characteristics of PPCPs in water with UV treatment. Environ. Int. 2009, 35:793-802.
7. Canonica S., Meunier L., Von Gunten U. Phototransformation of selected pharmaceuticals during UV treatment of drinking water. Water Res. 2008, 42:121-128.
8. Huber M.M., Canonica S., Park G.Y., Von Gunten U. Oxidation of pharmaceuticals during ozonation and advanced oxidation processes. Environ. Sci. Technol. 2003, 37:1016-1024.
9. 2 processes. Sci. Total Environ. 2012, 420:160-167.
10. 2 in synthetic and natural water samples. Water Res. 2012, 46:1501-1510.
11. Glaze W.H., Kang J.W., Chapin D.H. The chemistry of water treatment processes involving ozone, hydrogen peroxide and ultraviolet radiation. Ozone: Sci. Eng. 1987, 9:335-352.
12. Baxendale J.H., Wilson J.A. The photolysis of hydrogen peroxide at high light intensities. Trans. Faraday Soc. 1957, 53:344-356.
13. 2 process in natural waters. Environ. Sci. Technol. 2007, 41:2548-2553.
14. 2 photocatalyst. J. Hazard. Mater. 2011, 186:1560-1567.
15. 2 nanotubes catalyst for degradation of Rhodamine B in water. Chem. Eng. J. 2013, 214:129-138.
16. 2 catalyst on degradation of Rhodamine B: Fenton-photo hybrid process. Chem. Eng. J. 2013, 229:57-65.
17. E.J. Rosenfeldt, Rapid method for measuring background hydroxyl radical scavenging for impacts on design of advanced oxidation processes (AOPs). In: American Water Works Association WQTC Conference, 2010.
18. 2 treatment of Rhodamine B in aqueous solution: influence of operational parameters and kinetic modeling. Desalination 2008, 230:16-26.
19. Bolton J.R., Linden K.G. Standardization of methods for fluence (UV dose) determination in bench-scale UV experiments. J. Environ. Eng. - ASCE 2003, 129:209-215.
20. -) in aqueous solution. J. Phys. Chem. Ref. Data 1988, 17:513-886.
21. Radoicic M., Saponjic Z., Jankovic I.A., Ciric-Marjanovic G., Ahrenkiel S.P., Comora M.I. Improvements to the photocatalytic efficiency of polyaniline modified TiO2 nanoparticles. Appl. Catal. B - Environ. 2013, 136:133-139.
22. Satoh A.Y., Trosko J.E., Masten S.J. Methylene blue dye test for rapid qualitative detection of hydroxyl radicals formed in a Fenton's reaction aqueous solution. Environ. Sci. Technol. 2007, 41:2881-2887.
23. Maezono T., Tokumura M., Sekine M., Kawase Y. Hydroxyl radical concentration profile in photo-Fenton oxidation process: generation and consumption of hydroxyl radicals during the discoloration of azo-dye Orange II. Chemosphere 2011, 82:1422-1430.
24. Pereira V.J., Weinberg H.S., Linden K.G., Singer P.C. UV degradation kinetics and modeling of pharmaceutical compounds in laboratory grade and surface water via direct and indirect photolysis at 254 nm. Environ. Sci. Technol. 2007, 41:1682-1688.
25. Neta L.M.D.P. Pulse radiolysis studies. XIII: rate constants for the reaction of hydroxyl radicals with aromatic compounds in aqueous solutions. Adv. Chem. Ser. 1968, 81:222-230.
26. Zele M.G., Cooper W.J., Kurucz C.N., Waite T.D. Waite, modeling kinetics of benzene, phenol, and toluene removal in aqueous solution using the high-energy electron beam process. Environmental Applications of Ionizing Radiation 1998, 395-415. John Wiley & Sons, Inc., New York. W.J. Cooper, R. Curry, K.E. O'Shea (Eds.).
27. 2 assisted UV photodegradation of N-nitrosodimethylamine in simulated drinking water. Environ. Sci. Technol. 2003, 37:1933-1940.
28. Wols B.A., Hofman-Caris C.H.M. Review of photochemical reaction constants of organic micropollutants required for UV advanced oxidation processes in water. Water Res. 2012, 46:2815-2827.
29. Kang J.W., Lee K.H. A kinetic model of the hydrogen peroxide UV process for the treatment of hazardous waste chemicals. Environ. Eng. Sci. 1997, 14:183-192.
30. Rosenfeldt E.J., Linden K.G. Degradation of endocrine disrupting chemicals bisphenol A, ethinyl estradiol, and estradiol during UV photolysis and advanced oxidation processes. Environ. Sci. Technol. 2004, 38:5476-5483.
31. Larson R.A., Zepp R.G. Reactivity of the carbonate radical with aniline derivatives. Environ. Toxicol. Chem. 1988, 7:265-274.
32. von Gunten U. Ozonation of drinking water: Part I. Oxidation kinetics and product formation. Water Res. 2003, 37:1443-1467.
33. Coddington J.W., Hurst J.K., Lymar S.V. Hydroxyl radical formation during peroxynitrous acid decomposition. J. Am. Chem. Soc. 1999, 121:2438-2443.
34. Zehavi D., Rabani J. The oxidation of aqueous bromide ions by hydroxyl radicals. A pulse radiolytic investigation. J. Phys. Chem. A 1972, 76:312-319.
35. Maruthamuthu P., Neta P. Phosphate radicals. Spectra, acid-base equilibria, and reactions with inorganic compounds. J. Phys. Chem. A 1978, 82:710e713.
36. 2 advanced oxidation processes. Water Res. 2011, 45:4531-4543.