Modeling the effects of the cathode composition of a lithium iron phosphate battery on the discharge behavior

Energies

Volumn 6, Issue 11, 2013, Pages 5597-5608

  Lee, Jeongbin ^a   Yi, Jaeshin ^a   Shin, Chee Burm ^a   Yu, Seung Ho ^b   Cho, Won Il ^b  

^a Ajou University   (South Korea)

^b Korea Institute of Science and Technology   (South Korea)

Author keywords

Cathode composition; Discharge; Lithium iron phosphate battery; Model

Indexed keywords

CATHODES; DISCHARGE (FLUID MECHANICS); ELECTRIC BATTERIES; ELECTRODES; ELECTROLYTES; FINITE ELEMENT METHOD; IRON; LITHIUM; MODELS;

CATHODE COMPOSITION; DISCHARGE BEHAVIORS; GALVANOSTATIC DISCHARGE; LITHIUM IRON PHOSPHATES; LITHIUM METAL ANODE; MODELING METHODOLOGY; NONLINEAR DEPENDENCIES; ONE-DIMENSIONAL MODEL;

LITHIUM-ION BATTERIES;

EID: 84887543316     PISSN: None     EISSN: 19961073     Source Type: Journal    
DOI: 10.3390/en6115597     Document Type: Article

References (31)

1. Padhi, A.K.; Nanjundaswamy, K.S.; Goodenough, J.B. Phospho-olivines as positive-electrode materials for rechargeable lithium batteries. J. Electrochem. Soc. 1997, 144, 1184-1194.
2. Yamada, A.; Chung, S.C.; Hinokuma, K. Optimized LiFePO4 for lithium battery cathodes. J. Electrochem. Soc. 2001, 148, A224-A229.
3. Laffont, L.; Delacourt, C.; Gibot, P.; Wu, M.Y.; Kooyman, P.; Masquelier, C.; Tarascon, J.M. Study of the LiFePO4/FePO4 two-phase system by high-resolution electron energy loss spectroscopy. Chem. Mater. 2006, 18, 5520-5529.
4. Lou, X.; Zhang, Y. Synthesis of LiFePO4/C cathode materials with both high-rate capability and high tap density for lithium-ion batteries. J. Mater. Chem. 2011, 21, 4156-4160.
5. Julien, C.M.; Mauger, A.; Zaghib, K. Surface effects on electrochemical properties of nano-sized LiFePO4. J. Mater. Chem. 2011, 21, 9955-9968.
6. Kim, D.-H.; Kim, J. Synthesis of LiFePO4 nanoparticles and their electrochemical properties. J. Phys. Chem. Solids 2007, 68, 734-737.
7. Kim, D.-H.; Kim, J. Synthesis of LiFePO4 nanoparticles in polyol medium and their electrochemical properties. Electrochem. Solid-State Lett. 2006, 9, A439-A442.
8. Yang, X.; Mou, F.; Zhang, L.; Peng, G.; Dai, Z.; Wen, Z. Enhanced rate performance of two-phase carbon coated LiFePO4/(C+G) using natural graphite as carbon source. J. Power Sources 2012, 204, 182-186.
9. Chen, Z.; Dahn, J.R. Reducing carbon in LiFePO4/C composite electrodes to maximize specific energy, volumetric energy, and tap density. J. Electrochem. Soc. 2002, 149, A1184-A1189.
10. Dominko, R.; Bele, M.; Gaberscek, M.; Remskar, M.; Hanzel, D.; Pejovnik, S.; Jamnik, J. Impact of the carbon coating thickness on the electrochemical performance of LiFePO4/C composites. J. Electrochem. Soc. 2005, 152, A607-A610.
11. Yang, M.-R.; Ke, W.-H. The doping effect on the electrochemical properties of LiFe0.95M0.05PO4 (M = Mg2+, Ni2+, Al3+, or V3+) as cathode materials for lithium-ion cells. J. Electrochem. Soc. 2008, 155, A729-A732.
12. Nakamura, T.; Miwa, Y.; Tabuchi, M.; Yamada, Y. Structural and surface modifications of LiFePO4 olivine particles and their electrochemical properties. J. Electrochem. Soc. 2006, 153, A1108-A1114.
13. Barker, J.; Saidi, M.Y.; Swoyer, J.L. Lithium iron(II) phospho-olivines prepared by a novel carbothermal reduction method. Electrochem. Solid-State Lett. 2003, 6, A53-A55.
14. Cedar, G.; Doyle, M.; Arora, P.; Fuentes, Y. Computational modeling and simulation for rechargeable batteries. MRS Bull. 2002, 27, 619-623.
15. Gomadam, P.M.; Weidner, J.W.; Dougal, R.A.; White, R.E. Mathematical modeling of lithium-ion and nickel battery systems. J. Power Sources 2002, 110, 267-284.
16. Newman, J.; Thomas, K.E.; Hafezi, H.; Wheeler, D.R. Modeling of lithium-ion batteries. J. Power Sources 2003, 119-121, 838-843.
17. Santhanagopalan, S.; Guo, Q.; Ramadass, P.; White, R.E. Review of models for predicting the cycling performance of lithium ion batteries. J. Power Sources 2006, 156, 620-628.
18. Doyle, M.; Fuller, T.F.; Newman, J. Modeling of galvanostatic charge and discharge of the lithium/polymer/insertion cell. J. Electrochem. Soc. 1993, 140, 1526-1533.
19. Gu, W.B.; Wang, C.Y. Thermal-electrochemical modeling of battery systems. J. Electrochem. Soc. 2000, 147, 2910-2922.
20. Doyle, M.; Fuentes, Y. Computer simulations of a lithium-ion polymer battery and implications for higher capacity next-generation battery designs. J. Electrochem. Soc. 2003, 150, A706-A713.
21. Srinivasan, V.; Wang, C.Y. Analysis of electrochemical and thermal behavior of Li-ion cells. J. Electrochem. Soc. 2003, 150, A98-A106.
22. Ramadass, P.; Haran, B.; Gomadam, P.M.; White, R.E.; Popov, B.N. Development of first principles capacity fade model for Li-ion cells. J. Electrochem. Soc. 2004, 151, A196-A203.
23. Kwon, K.H.; Shin, C.B.; Kang, T.H.; Kim, C.-S. A two-dimensional modeling of a lithium-polymer battery. J. Power Sources 2006, 163, 151-157.
24. Kim, U.S.; Shin, C.B.; Kim, C.-S. Effect of electrode configuration on the thermal behavior of a lithium-polymer battery. J. Power Sources 2008, 180, 909-916.
25. Kim, U.S.; Shin, C.B.; Kim, C.-S. Modeling for the scale-up of a lithium-ion polymer battery. J. Power Sources 2009, 189, 841-846.
26. Kim, U.S.; Yi, J.; Shin, C.B.; Han, T.; Park, S. Modeling for the thermal behavior of a lithium-ion battery during charge. J. Power Sources 2011, 196, 5115-5121.
27. Kim, U.S.; Yi, J.; Shin, C.B.; Han, T.; Park, S. Modeling the dependence of the discharge behavior of a lithium-ion battery on the environmental temperature. J. Electrochem. Soc. 2011, 158, A611-A618.
28. Tiedemann, W.; Newman, J. Current and Potential Distribution in Lead-Acid Battery Plates. In Battery Design and Optimization, Gross, S., Ed.; The Electrochemical Society: Pennington, NJ, USA, 1979; pp. 39-49.
29. Newman, J.; Tiedemann, W. Potential and current distribution in electrochemical cells-Interpretation of the half-cell voltage measurements as a function of reference-Electrode location. J. Electrochem. Soc. 1993, 140, 1961-1968.
30. Gu, H. Mathematical analysis of a Zn/NiOOH cell. J. Electrochem. Soc. 1983, 130, 1459-1464.
31. Deutsch, C.V.; Journel, A.G. GSLIB-Geostatistical Software Library and User's Guide, 2nd ed.; Oxford University Press: New York, NY, USA, 1998; pp. 63-118.