Use of Pd-MnMoO4-graphene hybrids as efficient and CO poisoning tolerant electrocatalysts for methanol oxidation

International Journal of Hydrogen Energy

Volumn 38, Issue 35, 2013, Pages 15388-15394

  Sharma, C S ^a   Awasthi, R ^a   Singh, R N ^a  

^a BANARAS HINDU UNIVERSITY   (India)

Author keywords

Alcohol fuel cells; Electrocatalytic activity; Hybrid materials; Methanol oxidation

Indexed keywords

ANODE MATERIAL; CO POISONING; ELECTROCATALYTIC ACTIVITY; HYBRID ELECTRODES; METHANOL OXIDATION; METHANOL OXIDATION REACTIONS;

ALCOHOL FUELS; ANODES; CATALYST ACTIVITY; ELECTROCATALYSTS; GRAPHENE; HYBRID MATERIALS; METHANOL FUELS;

METHANOL;

EID: 84887045682     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2013.09.091     Document Type: Article

References (31)

1. L. Gao, W. Yue, S. Tao, and L. Fan Novel strategy for preparation of graphene-Pd, Pt composite, and its enhanced electrocatalytic activity for alcohol oxidation Langmuir 29 2013 957 964
2. E. Antoloni, and E.R. Gonzalez Alkaline direct alcohol fuel cells J Power Sources 195 2010 3431 3450
3. J. Yang, Y. Xie, R. Wang, B. Jiang, C. Tian, and G. Mu Synergistic effect of tungsten carbide and palladium on graphene for promoted ethanol electrooxidation ACSAppl Mater Interfaces 5 2013 6571 6579
4. K. Scott, and A.K. Shukla Direct methanol fuel cells: fundamentals, problems and prospects Mod Aspects Electrochem 40 2007 127 227
5. C. Bianchini, and P.K. Shen Palladium-based electrocatalysts for alcohol oxidation in half cells and in direct alcohol fuel cells Chem Rev 109 2009 4183 4206
6. C. Lamy, A. Lima, V. LeRhun, F. Delime, C. Contaceau, and J.M. Leger Recent advances in the development of direct alcohol fuel cells (DAFC) J Power Sources 105 2002 283 296
7. Y. Wang, Z.M. Sheng, H. Yang, S.P. Jiang, and C.M. Li Electrocatalysis of carbon black-or activated carbon nanotubes-supported Pd-Ag towards methanol oxidation in alkaline media Int J Hydrogen Energy 35 2010 10087 10093
8. Z. Liu, X. Zhang, and L. Hong Physical and electrochemical characterizations of nanostructured Pd/C and PdNi/C catalyst for methanol oxidation Electrochem Commun 11 2009 925 928
9. R. Awasthi, and R.N. Singh Graphene-supported Pd-Ru nanoparticles with superior methanol electrooxidation activity Carbon 51 2013 282 289
10. R. Awasthi, and R.N. Singh Optimization of the Pd-Sn-GNS nanocomposite for enhanced electrooxidation of methanol Int J Hydrogen Energy 37 2012 2103 2110
11. Y. Wang, X. Wang, and C.M. Li Electrocatalysis of Pd-Co supported on carbon black or ball-milled carbon nanotubes towards methanol oxidation in alkaline media Appl Catal B- Environ 99 2010 229 234
12. C. Xu, L. Cheng, P.K. Shen, and Y. Liu Methanol and ethanol electrooxidation on Pt and Pd supported on carbon microspheres in alkaline media Electrochem Commun 9 2007 997 1001
13. F. Cheng, H. Wang, Z. Sun, M. Ning, Z. Cai, and M. Zhang Electrodeposited fabrication of highly ordered Pd nanowire arrays for alcohol electrooxidation Electrochem Commun 10 2008 798 801
14. V. Bambagioni, C. Bianchini, A. Marchionni, J. Filippi, F. Vizza, and J. Teddy Pd and Pt-Ru anode electrocatalysts supported on multi-walled carbon nanotubes and their use in passive and active direct alcohol fuel cells with anion-exchange membrane (alcohol = methanol, ethanol, glycerol) J Power Sources 190 2009 241 245
15. R.N. Singh, A. Singh, and Anindita Electrocatalytic activity of binary and ternary composite films of Pd, MWCNT, and Ni for ethanol electro-oxidation in alkaline solutions Carbon 47 2009 271 278
16. A. Dutta, and J. Datta Outstanding catalyst performance of PdAuNi nanoparticles for the anodic reaction in an alkaline direct ethanol (with anion-exchange membrane) fuel cell J Phys Chem C 116 2012 25677 25688
17. J. Datta, A. Dutta, and S. Mukherjee The beneficial role of the cometals Pd and Au in the carbon-supported PtPdAu catalyst toward promoting ethanol oxidation kinetics in alkaline fuel cells: temperature effect and reaction mechanism J Phys Chem C 115 2011 15324 15334
18. R.N. Singh, and R. Awasthi Graphene support for enhanced electrocatalytic activity of Pd for alcohol oxidation Catal Sci Technol 1 2011 778 783
19. M. Kumar, R. Awasthi, A.K. Pramanick, and R.N. Singh New ternary mixed oxides of Fe, Ni and Mo for enhanced oxygen evolution Int J Hydrogen Energy 36 2011 12698 12705
20. 4 nanocrystals on graphene as a synergistic catalyst for oxygen reduction Nat Mater 10 2011 780 786
21. 4 films prepared on titanium by spray pyrolysis for oxygen evolution J Electrochem Soc 137 1990 1408 1413
22. 4(0 ≤ x ≤ 1) obtained by a new precipitation method for oxygen evolution J New Mater Electrochem Syst 2 1999 59 64
23. 4 composite for supercapacitors Electrochim Acta 55 2010 6973 6978
24. B.D. Adam, C.K. Ostrom, and A. Chen Hydrogen electrosorption into PdCd nanostructures Langmuir 26 2010 7632 7637
25. G.C. Allen, S.J. Harris, and J.A. Jutson A study of a number of mixed transition metal oxide spinels using X-ray photoelectron spectroscopy Appl Surf Sci 37 1989 111 134
26. P.A. Spevak, and N.S. Mclntyre A Raman and XPS investigation of supported molybdenum oxide thin films J Phys Chem 97 1993 11031 11036
27. Z. Zhang, L. Xin, K. Sun, and W. Li Pd-Ni electrocatalysts for efficient ethanol oxidation reaction in alkaline electrolyte Int J Hydrogen Energy 36 2011 12686 12697
28. H. Li, G. Chang, Y. Zhang, J. Tian, S. Liu, and Y. Luo Photocatalytic synthesis of highly dispersed Pd nanoparticles on reduced graphene oxide and their application in methanol electro-oxidation Catal Sci Technol 2 2012 1153 1156
29. Mahapatra SS, Datta J. Characterization of Pt-Pd/C electrocatalyst for methanol oxidation in alkaline medium. IntJ Electrochem. http://dx.doi.org/10. 0461/2011/563495.
30. R. Lin, C. Cao, H. Zhang, H. Huang, and J. Ma Electro-catalytic activity of enhanced CO tolerant cerium-promoted Pt/C catalyst for PEM fuel cell anode Int J Hydrogen Energy 37 2012 4648 4656
31. V.K.V.P. Srirapu, M. Kumar, R. Awasthi, R.N. Singh, and A.S.K. Sinha Manganese molybdate and its Fe-substituted products as new efficient electrocatalysts for oxygen evolution in alkaline solution Int J Hydrogen Energy 38 2013 13587 13595