Heterogeneous oxidation of folpet and dimethomorph by OH radicals: A kinetic and mechanistic study

Atmospheric Environment

Volumn 82, Issue , 2014, Pages 164-171

  Al Rashidi, M ^a   Chakir, A ^a   Roth, E ^a  

^a UNIVERSITÉ DE REIMS CHAMPAGNE ARDENNE   (France)

Author keywords

Atmospheric life times; Dimethomorph; Folpet; Heterogeneous kinetics; Mechanism; Ozone; Pesticides

Indexed keywords

CHEMICAL ANALYSIS; DEGRADATION; FREE RADICALS; FUNGICIDES; KINETICS; MECHANISMS; OZONE; PESTICIDES; RATE CONSTANTS;

DEGRADATION MECHANISM; DEGRADATION PRODUCTS; DIMETHOMORPH; EXPERIMENTAL METHODS; FOLPET; HETEROGENEOUS KINETICS; HETEROGENEOUS OXIDATION; LIFE-TIMES;

OXIDATION;

DIMETHOMORPH; FOLPET; FUNGICIDE; HYDROXYL RADICAL; TERBUTYLAZINE; UNCLASSIFIED DRUG;

ANALYTICAL METHOD; EXPERIMENTAL STUDY; FUNGICIDE; HETEROGENEITY; OXIDATION; REACTION RATE; REMOVAL EXPERIMENT; SIMULATION;

AIR POLLUTION; ARTICLE; ATOMIC FORCE MICROSCOPY; CHEMICAL STRUCTURE; CONTROLLED STUDY; DEGRADATION; DEGRADATION KINETICS; HUMIDITY; ION MONITORING; KINETICS; MASS FRAGMENTOGRAPHY; MATHEMATICAL ANALYSIS; MECHANICS; OXIDATION; OXIDATION KINETICS; PHOTOLYSIS; PRIORITY JOURNAL; SIMULATION; TROPOSPHERE;

CHAMPAGNE-ARDENNE; FRANCE;

EID: 84887007844     PISSN: 13522310     EISSN: 18732844     Source Type: Journal    
DOI: 10.1016/j.atmosenv.2013.10.031     Document Type: Article

References (36)

1. Al Rashidi M., Chakir A., Roth E. Heterogeneous ozonolysis of folpet and dimethomorph: a kinetic and mechanistic study. J.Phys. Chem. A 2013, 117:2908-2915.
2. Al Rashidi M., El Mouden O., Chakir A., Roth E., Salghi R. The heterogeneous photo-oxidation of difénoconazole in the atmosphere. Atmos. Environ. 2011, 45:5997-6003.
3. ATMO Champagne-Ardenne Evaluation des teneurs en pesticides sur un transect de 10Km dans la Marne 2010, (Reims).
4. Atkinson R. Gas-phase tropospheric chemistry of volatile organic compounds: 1. alkanes and alkenes. J.Phys. Chem. Ref.Data 1997, 26:215-290.
5. Bailey R., Belzer W. Large volume cold on-column injection for gas chromatography-negative chemical ionization-mass spectrometry analysis of selected pesticides in air samples. J.Agric. Food Chem. 2007, 55:11150-11155.
6. Bethel H.L., Arey J., Atkinson R. Products of the OH-initiated reaction of 3-hexene-2,5-dione. Environ. Sci. Technol. 2001, 35:4477-4480.
7. Bunce N.J., Liu L., Zhu J. Reaction of naphthalene and its derivatives with hydroxyl radicals in the gas phase. Environ. Sci. Technol. 1997, 31:2252-2259.
8. Coscollà C., Colin P., Yahyaoui A., Petrique O., Yusà V., Mellouki A., Pastor A. Occurrence of currently used pesticides in ambient air of Centre Region (France). Atmos. Environ. 2010, 44:3915-3925.
9. De Brito S.A., Stoppelli I.M., Crestana S. Pesticide exposure and cancer among rural workers from Bariri, Sao Paulo State, Brazil. Environ. Int. 2005, 31:731-738.
10. Dickhut R.M., Cincinelli A., Cochran, M., Ducklow H.W. Atmospheric concentrations and air-water flux of organochlorine pesticides along the Western Antarctic Peninsula. Environ. Sci. Technol. 2005, 39:465-470.
11. EPI.AOPWIN v.1.92a Atmospheric Oxidation Program for Microsoft Windows 2000, U.S. Environmental Protection Agency.
12. Feigenbrugel V., Le Person A., Le Calvé S., Mellouki A., Munoz A., Wirtz K. Atmospheric fate of dichlorvos: photolysis and OH-initiated oxidation studies. Environ. Sci. Technol. 2006, 40:850-857.
13. Finlayson-Pitts B., Pitts J. Chemistry of the Upper and Lower Atmosphere 2000, Academic Press, San Diego, California.
14. Gan J., Yang B., Zhang Y., Shu X., Liu C., Shu J. Products and kinetics of heterogeneous reaction of suspended vinclozolin particles with ozone. J.Phys. Chem. 2010, 114:12231-12236.
15. Gil Y., Sinfort C. Emission of pesticides to the air during sprayer application: a bibliographic review. Atmos. Environ. 2005, 39:5183-5193.
16. Glottfelty D.E., Taylor A.W., Turner B.C., Zoller W.H. Volatilization of surface-applied pesticides from fallow soil. J.Agric. Food Chem. 1984, 32:638-643.
17. Hart E., Coscollà C., Pastor A., Yusà V. GC-MS characterization of contemporary pesticides in PM10 of Valencia Region, Spain. Atmos. Environ. 2012, 62:118-129.
18. Lee W.J., Baccarelli A., Tretiakova M., Gorbanev S., Lompev A., Klimkina I., Tchibissov V., Averkina O., Dosemeci M. Pesticide exposure and lung cancer mortality in Leningrad province in Russia. Environ. Int. 2006, 32:412-416.
19. Liu X., Jeffries H.E., Sexton K.G. Atmospheric photochemical degradation of 1,4-unsaturated dicarbonyls. Environ. Sci. Technol. 1999, 33:4212-4220.
20. Mc Connell L.L., Lenoir J.S., Datta S., Seiber J.N. Wet deposition of current-use pesticides in the Sierra Nevada Mountain Range California, USA. Environ. Toxicol. Chem. 1998, 17:1908-1916.
21. Nishino N., Arey J., Atkinson R. Yields of glyoxal and ring cleavage co-products from the OH radical-initiated reactions of naphthalene and alkylnaphthalenes. Environ. Sci. Technol. 2009, 43:8554-8560.
22. O'Leary E.S., Vena J.E., Freudenheim J.L., Brasure J. Pesticide exposure and risk of breast cancer: a nested case-control study of residentially stable women living in Long Island. Environ. Res. 2004, 94:134-144.
23. Palm W.-U., Elend M., Krueger H.-U., Zetzsch C. OH radical reactivity of airborne terbuthylazine adsorbed on inert aerosol. Environ. Sci. Technol. 1997, 31:3389-3396.
24. Park J.S., Wade T.L., Sweet S. Atmospheric deposition of organochlorine contaminants to Galveston Bay, Texas. Atmos. Environ. 2001, 35:3315-3324.
25. Perraudin E., Budzinski H., Villenave E. Kinetic study of the reactions of ozone with polycyclic aromatic hydrocarbons adsorbed on atmospheric model particles. J.Atmos. Chem. 2007, 56:57-82.
26. Pflieger M., Monod A., Wortham H. Heterogeneous oxidation of terbuthylazine by "dark" OH radicals under simulated atmospheric conditions in a flow tube. Environ. Sci. Technol. 2013, 47:6239-6246.
27. Raina R., Belzer W., Jones K. Atmospheric concentrations of captan and folpet in the lower Fraser Valley agricultural region in Canada. Air Soil Water Res. 2009, 2:41-49.
28. Sander S.P., Friedl R.R., Golden D.M., Kurylo M.G., Moortgat G.K., Keller-Rudek H., Wine P.H., Ravishankara A.R., Kolb C.E., Molina M.J., Finlayson-Pitts B.J., Huie R.E., Orkin V.L. Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies 2006, Evaluation number 15.
29. 3 radical-initiated reactions of naphthalene. Environ. Sci. Technol. 1997, 31:3173-3179.
30. Schummer C., Mothiron E., Appenzeller B.M.R., Rizet A.-L., Wennig R., Millet M. Temporal variations of concentrations of currently used pesticides in the atmosphere of Strasbourg, France. Evironmantal Pollut. 2010, 158:576-584.
31. Segal-Rosenheimer M., Dubowski Y. Heterogeneous ozonolysis of cypermethrin using real-time monitoring FTIR techniques. J.Phys. Chem. 2007, 111:11682-11691.
32. Seinfeld J.H., Pandis S.N. Atmospheric Chemistry and Physics from Air Pollution to Climate Change 2006, J. Wiley, New York. second ed.
33. Van Den Berg F., Kubiak R., Benjey W.G., Majewski M.S., Yates S.R., Reeves G.L., Smelt J.H., Van Der Linden A.M.A. Emission of pesticides into the air. Water Air Soil Pollut. 1999, 115:195-218.
34. Van Maele-Fabry G., Willems J.L. Occupation related pesticide exposure and cancer of the prostate: a meta-analysis. Occup. Environ. Med. 2003, 60:634-642.
35. Wang L., Atkinson R., Arey J. Dicarbonyl products of the OH-radical initiated reactions of naphthalene and the C1 and C2-alkylnaphthalenes. Environ. Sci. Technol. 2007, 41:2803-2810.
36. Yusa V., Coscolla C., Mellouki W., Pastor A., De La Guardia M. Sampling and analysis of pesticides in ambient air. J.Chromatogr. A 2009, 1216:2972-2983.