Long-range segregation phenomena in shape-selected bimetallic nanoparticles: Chemical state effects

ACS Nano

Volumn 7, Issue 10, 2013, Pages 9195-9204

  Ahmadi, Mahdi ^a   Behafarid, Farzad ^a   Cui, Chunhua ^b   Strasser, Peter ^b   Cuenya, Beatriz Roldan ^a,c  

^a UNIVERSITY OF CENTRAL FLORIDA   (United States)

^b TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

^c RUHR UNIVERSITY BOCHUM   (Germany)

Author keywords

AFM; diffusion; nanoparticle; octahedral; PtNi; PtNi alloy; segregation; XPS

Indexed keywords

AFM; BIMETALLIC NANOPARTICLES; EX-SITU ATOMIC FORCE MICROSCOPY; HIGHLY ORIENTED PYROLYTIC GRAPHITE; OCTAHEDRAL; PT-NI ALLOYS; PTNI; SITU X-RAY PHOTOELECTRON SPECTROSCOPY;

ATOMIC FORCE MICROSCOPY; DIFFUSION; NANOPARTICLES; NICKEL; PHOTOELECTRONS; PLATINUM; PLATINUM ALLOYS; SEGREGATION (METALLOGRAPHY); VACUUM; X RAY PHOTOELECTRON SPECTROSCOPY;

SURFACE SEGREGATION;

EID: 84887000521     PISSN: 19360851     EISSN: 1936086X     Source Type: Journal    
DOI: 10.1021/nn403793a     Document Type: Article

References (78)

1. Sinflet, J. H. Bimetallic Catalysts-Discoveries. Concepts and Applications; John Wiley & Sons: New York, 1983.
2. Croy, J. R.; Mostafa, S.; Hickman, L.; Heinrich, H.; Roldan Cuenya, B. Bimetallic Pt-Metal Catalysts for the Decomposition of Methanol: Effect of Secondary Metal on the Oxidation State, Activity, and Selectivity of Pt Appl. Catal., A 2008, 350, 207-216
3. 3 Catal. Lett. 2008, 120, 198-203
4. Stottlemyer, A. L.; Ren, H.; Chen, J. G. Reactions of Methanol and Ethylene Glycol on Ni/Pt: Bridging the Materials Gap between Single Crystal and Polycrystalline Bimetallic Surfaces Surf. Sci. 2009, 603, 2630-2638
5. Tanksale, A.; Beltramini, J. N.; Dumesic, J. A.; Lu, G. Q. Effect of Pt and Pd Promoter on Ni Supported Catalysts-A TPR/TPO/TPD and Microcalorimetry Study J. Catal. 2008, 258, 366-377
6. Stamenkovic, V.; Mun, B. S.; Mayrhofer, K. J. J.; Ross, P. N.; Markovic, N. M.; Rossmeisl, J.; Greeley, J.; Norskov, J. K. Changing the Activity of Electrocatalysts for Oxygen Reduction by Tuning the Surface Electronic Structure Angew. Chem., Int. Ed. 2006, 45, 2897-2901
7. Carpenter, M. K.; Moylan, T. E.; Kukreja, R. S.; Atwan, M. H.; Tessema, M. M. Solvothermal Synthesis of Platinum Alloy Nanoparticles for Oxygen Reduction Electrocatalysis J. Am. Chem. Soc. 2012, 134, 8535-8542
8. Cui, C.; Gan, L.; Li, H.-H.; Yu, S.-H.; Heggen, M.; Strasser, P. Octahedral PtNi Nanoparticle Catalysts: Exceptional Oxygen Reduction Activity by Tuning the Alloy Particle Surface Composition Nano Lett. 2012, 12, 5885-5889
9. 3Ni Oxygen Reduction Reaction Electrocatalysts J. Am. Chem. Soc. 2010, 132, 4984-4985
10. 3CO" Nanoparticles: Direct Evidence of Percolated and Sandwich-Segregation Structures J. Am. Chem. Soc. 2008, 130, 13818-13819
11. Choi, S.-I.; Xie, S.; Shao, M.; Odell, J. H.; Lu, N.; Peng, H.-C.; Protsailo, L.; Guerrero, S.; Park, J.; Xia, X.; Wang, J.; Kim, M. J.; Xia, Y. Synthesis and Characterization of 9 nm Pt-Ni Octahedra with a Record High Activity of 3.3 A/mgPtfor the Oxygen Reduction Reaction Nano Lett. 2013, 3420-3425
12. Khan, N. A.; Zellner, M. B.; Chen, J. G. Cyclohexene as a Chemical Probe of the Low-Temperature Hydrogenation Activity of Pt/Ni(111) Bimetallic Surfaces Surf. Sci. 2004, 556, 87-100
13. Chen, J. G.; Qi, S. T.; Humbert, M. P.; Menning, C. A.; Zhu, Y. X. Rational Design of Low-Temperature Hydrogenation Catalysts: Theoretical Predictions and Experimental Verification Acta Phys. Chim. Sin. 2010, 26, 869-876
14. Su, H. Y.; Bao, X. H.; Li, W. X. Modulating the Reactivity of Ni-Containing Pt(111)-Skin Catalysts by Density Functional Theory Calculations J. Chem. Phys. 2008, 128, 194701
15. Mu, R. T.; Fu, Q. A.; Xu, H.; Zhang, H. I.; Huang, Y. Y.; Jiang, Z.; Zhang, S. O.; Tan, D. L.; Bao, X. H. Synergetic Effect of Surface and Subsurface Ni Species at Pt-Ni Bimetallic Catalysts for CO Oxidation J. Am. Chem. Soc. 2011, 133, 1978-1986
16. 3Co and PtCu Intermetallic Compounds: Promising Catalysts for Preferential Oxidation of CO in Excess Hydrogen J. Catal. 2008, 258, 306-314
17. Li, B. T.; Kado, S.; Mukainakano, Y.; Miyazawa, T.; Miyao, T.; Naito, S.; Okumura, K.; Kunimori, K.; Tomishige, K. Surface Modification of Ni Catalysts with Trace Pt for Oxidative Steam Reforming of Methane J. Catal. 2007, 245, 144-155
18. Besenbacher, F.; Chorkendorff, I.; Clausen, B. S.; Hammer, B.; Molenbroek, A. M.; Norskov, J. K.; Stensgaard, I. Design of a Surface Alloy Catalyst for Steam Reforming Science 1998, 279, 1913-1915
19. 3 Nanoparticle Electrocatalyst for the Oxygen Reduction Reaction in PEMFC J. Electrochem. Soc. 2012, 159, B25-B34
20. Oezaslan, M.; Hasché, F.; Strasser, P. In Situ Observation of Bimetallic Alloy Nanoparticle Formation and Growth Using High-Temperature XRD Chem. Mater. 2011, 23, 2159-2165
21. 3Co Alloy Nanocatalyst via Reverse Micelle for Oxygen Reduction Reaction in PEMFCs Top. Catal. 2008, 49, 241-250
22. Ahmadi, T. S.; Wang, Z. L.; Green, T. C.; Henglein, A.; ElSayed, M. A. Shape-Controlled Synthesis of Colloidal Platinum Nanoparticles Science 1996, 272, 1924-1926
23. Scott, R. W.; Datye, A. K.; Crooks, R. M. Bimetallic Palladium-Platinum Dendrimer-Encapsulated Catalysts J. Am. Chem. Soc. 2003, 123, 3708-3709
24. Liu, C.; Wu, X.; Klemmer, T.; Shukla, N.; Yang, X.; Weller, D. Polyol Process Synthesis of Monodispersed FePt Nanoparticles J. Phys. Chem. B 2004, 108, 6121-6123
25. 1 Catalysts as Cathode in PEM Fuel Cells Electrochem. Commun. 2004, 6, 795-799
26. Wei, Z. D.; Guo, H. T.; Tang, Z. Y. Heat Treatment of Carbon-Based Powders Carrying Platinum Alloy Catalysts for Oxygen Reduction: Influence on Corrosion Resistance and Particle Size J. Power Sources 1996, 62, 233-236
27. Gasteiger, H. A.; Kocha, S. S.; Sompalli, B.; Wagner, F. T. Activity Benchmarks and Requirements for Pt, Pt-Alloy, and non-Pt Oxygen Reduction Catalysts for PEMFCs Appl. Catal., B 2005, 56, 9-35
28. Salgado, J. R. C.; Antolini, E.; Gonzalez, E. R. Structure and Activity of Carbon-Supported Pt-Co Electrocatalysts for Oxygen Reduction J. Phys. Chem. B 2004, 108, 17767-17774
29. Ferreira, P. J.; la O', G. J.; Shao-Horn, Y.; Morgan, D.; Makharia, R.; Kocha, S.; Gasteiger, H. A. Instability of Pt/C Electrocatalysts in Proton Exchange Membrane Fuel Cells-A Mechanistic Investigation J. Electrochem. Soc. 2005, 152, A2256-A2271
30. Bindra, P.; Clouser, S. J.; Yeager, E. Platinum Dissolution in Concentrated Phosphoric Acid J. Electrochem. Soc. 1979, 126, 1631-1632
31. Strasser, P. Dealloyed Core Shell Fuel Cell Electrocatalysts Rev. Chem. Eng. 2009, 25, 255-295
32. 3Pt (111) Studied by Surface X-ray Scattering J. Phys. Chem. C 2011, 115, 9074-9080
33. 1-x Nanoparticles and Their Impact on Oxygen Reduction Catalysis Nano Lett. 2012, 12, 5423-5430
34. Pourovskii, L. V.; Ruban, A. V.; Johansson, B.; Abrikosov, I. A. Antisite-Defect-Induced Surface Segregation in Ordered NiPt Alloy Phys. Rev. Lett. 2003, 90, 026105
35. Dahmani, C. E.; Cadeville, M. C.; Sanchez, J. M.; Moranlopez, J. I. Ni-Pt Phase-Diagram-Experiment and Theory Phys. Rev. Lett. 1985, 55, 1208-1211
36. Wang, G.; Van Hove, M. A.; Ross, P. N.; Baskes, M. I. Monte Carlo Simulations of Segregation in Pt-Ni Catalyst Nanoparticles J. Chem. Phys. 2005, 122, 024706
37. 3 Alloy Electrocatalyst for PEMFC Z. Anorg. Allg. Chem. 2010, 636, 2111-2111
38. Ghosh, T.; Leonard, B. M.; Zhou, Q.; DiSalvo, F. J. Pt Alloy and Intermetallic Phases with V, Cr, Mn, Ni, and Cu: Synthesis as Nanomaterials and Possible Applications As Fuel Cell Catalysts Chem. Mater. 2010, 22, 2190-2202
39. Wang, D.; Xin, H. L.; Hovden, R.; Wang, H.; Yu, Y.; Muller, D. A.; DiSalvo, F. J.; Abruña, H. D. Structurally Ordered Intermetallic Platinum-Cobalt Core-Shell Nanoparticles with Enhanced Activity and Stability as Oxygen Reduction Electrocatalysts Nat. Mater. 2013, 12, 81-87
40. Lozovoi, A. Y.; Alavi, A.; Finnis, M. W. Surface Stoichiometry and the Initial Oxidation of NiAl(110) Phys. Rev. Lett. 2000, 85, 610-613
41. Khan, N. A.; Zellner, M. B.; Murillo, L. E.; Chen, J. G. A Comparison of Similarities and Differences in the Activities of Pt/Ni(111) and Ni/Pt(111) Surfaces Catal. Lett. 2004, 95, 1-6
42. 2 Production on 3d/Pt(111) Bimetallic Surfaces Top. Catal. 2008, 51, 49-59
43. Skoplyak, O.; Menning, C. A.; Barteau, M. A.; Chen, J. G. Experimental and Theoretical Study of Reactivity Trends for Methanol on Co/Pt(111) and Ni/Pt(111) Bimetallic Surfaces J. Chem. Phys. 2007, 127, 114707
44. Gasteiger, H. A.; Markovic, N. M. Just a Dream or Future Reality? Science 2009, 324, 48-49
45. Humbert, M. P.; Chen, J. G. Correlating Hydrogenation Activity with Binding Energies of Hydrogen and Cyclohexene on M/Pt(111) (M = Fe, Co, Ni, Cu) Bimetallic Surfaces J. Catal. 2008, 257, 297-306
46. Nashner, M. S.; Frenkel, A. I.; Somerville, D.; Hills, C. W.; Shapley, J. R.; Nuzzo, R. G. Core Shell Inversion During Nucleation and Growth of Bimetallic Pt/Ru Nanoparticles J. Am. Chem. Soc. 1998, 120, 8093-8101
47. Wang, G.; Vanhove, M.; Ross, P.; Baskes, M. Quantitative Prediction of Surface Segregation in Bimetallic Pt-M Alloy Nanoparticles (M = Ni, Re, Mo) Prog. Surf. Sci. 2005, 28-45
48. Cui, C.; Ahmadi, M.; Behafarid, F.; Gan, L.; Neumann, M.; Heggen, M.; Roldan Cuenya, B.; Strasser, P. Shape-Selected Bimetallic Nanoparticle Electrocatalysts: Evolution of Their Atomic-Scale Structure, Chemical Composition, and Electrochemical Reactivity under Various Chemical Environments Faraday Discuss. 2013, 91-112
49. Cui, C.; Gan, L.; Heggen, M.; Rudi, S.; Strasser, P. Compositional Segregation in Shaped Pt Alloy Nanoparticles and Their Structural Behaviour During Electrocatalysis Nat. Mater. 2013, 765-771
50. Wu, Y.; Cai, S.; Wang, D.; He, W.; Li, Y. Syntheses of Water-Soluble Octahedral, Truncated Octahedral, and Cubic Pt-Ni Nanocrystals and Their Structure-Activity Study in Model Hydrogenation Reactions J. Am. Chem. Soc. 2012, 134, 8975-8981
51. Menning, C. A.; Chen, J. G. Thermodynamics and Kinetics of Oxygen-Induced Segregation of 3d Metals in Pt-3d-Pt(111) and Pt-3d-Pt(100) Bimetallic Structures J. Chem. Phys. 2008, 128, 164703
52. Menning, C. A.; Chen, J. G. General Trend for Adsorbate-Induced Segregation of Subsurface Metal Atoms in Bimetallic Surfaces J. Chem. Phys. 2009, 130, 174709
53. Mu, R. T.; Fu, Q.; Liu, H. Y.; Tan, D. L.; Zhai, R. S.; Bao, X. H. Reversible Surface Structural Changes in Pt-Based Bimetallic Nanoparticles During Oxidation and Reduction Cycles Appl. Surf. Sci. 2009, 255, 7296-7301
54. Yang, D. Q.; Sacher, E. Interaction of Evaporated Nickel Nanoparticles with Highly Oriented Pyrolytic Graphite: Back-Bonding to Surface Defects, as Studied by X-ray Photoelectron Spectroscopy J. Phys. Chem. B 2005, 109, 19329-19334
55. 2(110) Surf. Sci. 2012, 606, 908-918
56. 2(110) Surface Surf. Sci. 2001, 474, 28-36
57. Belton, D. N.; Sun, Y. M.; White, J. M. Metal-Support Interactions on Rhodium and Platinum/Titanium Dioxide Model Catalysts J. Phys. Chem. 1984, 88, 5172-5176
58. 2(110): Growth, Surface Composition, and Metal-Support Interactions J. Phys. Chem. C. 2008, 112, 5490-5500
59. Porsgaard, S.; Ono, L. K.; Zeuthen, H.; Knudsen, J.; Schnadt, J.; Merte, L. R.; Chevallier, J.; Helveg, S.; Salmeron, M.; Wendt, S.; Besenbacher, F. In Situ Study of CO Oxidation on HOPG-Supported Pt Nanoparticles ChemPhysChem 2013, 1553-1557
60. Croy, J. R.; Mostafa, S.; Liu, J.; Sohn, Y.-h.; Roldan Cuenya, B. Size-Dependent Study of MeOH Decomposition Over Size-Selected Pt Nanoparticles Synthesized via Micelle Encapsulation Catal. Lett. 2007, 118, 1-7
61. 2/Si(111): A High-Pressure X-ray Photoelectron Spectroscopy Study ACS Nano 2012, 10743-10749
62. Dai, W. L.; Qiao, M. H.; Deng, J. F. XPS Studies on a Novel Amorphous Ni-Co-W-B Alloy Powder Appl. Surf. Sci. 1997, 120, 119-124
63. Grunthaner, P. J.; Grunthaner, F. J.; Mayer, J. W. XPS Study of the Chemical-Structure of the Nickel-Silicon Interface J. Vac. Sci. Technol. 1980, 17, 924-929
64. Grosvenor, A. P.; Biesinger, M. C.; Smart, R. S.; McIntyre, N. S. New Interpretations of XPS Spectra of Nickel Metal and Oxides Surf. Sci. 2006, 600, 1771-1779
65. 2 Catalyst Chemosphere 2002, 48, 1103-1111
66. Rajalakshmi, N.; Ryu, H.; Shaijumon, M. M.; Ramaprabhu, S. Performance of Polymer Electrolyte Membrane Fuel Cells with Carbon Nanotubes as Oxygen Reduction Catalyst Support Material J. Power Sources 2005, 140, 250-257
67. Wen, Y. N.; Zhang, H. M. Surface Energy Calculation of the Fcc Metals by Using the MAEAM Solid State Commun. 2007, 144, 163-167
68. Deng, L.; Hu, W.; Deng, H.; Xiao, S.; Tang, J. Au-Ag Bimetallic Nanoparticles: Surface Segregation and Atomic-Scale Structure J. Phys. Chem. C 2011, 115, 11355-11363
69. Cheng, D.; Yuan, S.; Ferrando, R. Structure, Chemical Ordering, and Thermal Stability of Pt-Ni Alloy Nanoclusters J. Phys.: Condens. Matter 2013, 25, 1-9
70. 50 Phys. Rev. B 1994, 50, 2039-2042
71. Oezaslan, M.; Heggen, M.; Strasser, P. Size-Dependent Morphology of Dealloyed Bimetallic Catalysts: Linking the Nano to the Macro Scale J. Am. Chem. Soc. 2012, 134, 514-524
72. Heggen, M.; Oezaslan, M.; Houben, L.; Strasser, P. Formation and Analysis of Core-Shell Fine Structures in Pt Bimetallic Nanoparticle Fuel Cell Electrocatalysts J. Phys. Chem. C 2012, 116, 19073-19083
73. Li, W.; Österlund, L.; Vestergaard, E.; Vang, R.; Matthiesen, J.; Pedersen, T.; Lægsgaard, E.; Hammer, B.; Besenbacher, F. Oxidation of Pt(110) Phys. Rev. Lett. 2004, 93, 146104
74. Kwon, S. G.; Hyeon, T. Formation Mechanisms of Uniform Nanocrystals via Hot-Injection and Heat-Up Methods Small 2011, 7, 2685-2702
75. http://www.casaxps.com.
76. 4 Nanosheets and Their Ambient-Temperature CO Oxidation Activity ChemCatChem 2011, 3, 399-407
77. 2-Rich Gases at Low Temperatures Phys. Chem. Chem. Phys. 2001, 3, 1123-1131
78. 3Sn(hkl) Surfaces: A Selective Review Surf. Sci. 2005, 576, 145-157