Thermodynamically stable emulsions using Janus dumbbells as colloid surfactants

Langmuir

Volumn 29, Issue 41, 2013, Pages 12679-12687

  Tu, Fuquan ^a   Park, Bum Jun ^a,b   Lee, Daeyeon ^a  

^a UNIVERSITY OF PENNSYLVANIA   (United States)

^b Kyung Hee University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

DIFFERENT MECHANISMS; EMULSION STABILIZATION; NONSPHERICAL PARTICLE; OIL WATER INTERFACES; PROPERTIES OF EMULSIONS; SURFACTANT-STABILIZED; THEORETICAL CALCULATIONS; THERMODYNAMICALLY STABLE;

COLLOIDS; DROPS; EMULSIONS; STABILIZATION; SURFACE ACTIVE AGENTS; THERMODYNAMICS; WETTING;

EMULSIFICATION;

SURFACTANT;

ARTICLE; CHEMISTRY; COLLOID; EMULSION; KINETICS; PARTICLE SIZE; SURFACE PROPERTY; THERMODYNAMICS;

COLLOIDS; EMULSIONS; KINETICS; PARTICLE SIZE; SURFACE PROPERTIES; SURFACE-ACTIVE AGENTS; THERMODYNAMICS;

EID: 84886930893     PISSN: 07437463     EISSN: 15205827     Source Type: Journal    
DOI: 10.1021/la402897d     Document Type: Article

References (56)

1. Adams, F., Walstra, P., Brooks, B., Richmond, H., and Binks, B. P. Modern Aspects of Emulsion Science; Royal Society of Chemistry: Cambridge, 1998.
2. McClements, D. J. Food Emulsions: Principles, Practices, and Techniques; CRC Press: Boca Raton, FL, 2004.
3. Aveyard, R.; Binks, B. P.; Clint, J. H. Emulsions stabilised solely by colloidal particles Adv. Colloid Interface Sci. 2003, 100, 503-546
4. Pickering, S. U. CXCVI.-Emulsions J. Chem. Soc., Trans. 1907, 91, 2001-2021
5. Binks, B. P. Particles as surfactants-similarities and differences Curr. Opin. Colloid Interface Sci. 2002, 7, 21-41
6. Aveyard, R.; Clint, J. H.; Horozov, T. S. Aspects of the stabilisation of emulsions by solid particles: Effects of line tension and monolayer curvature energy Phys. Chem. Chem. Phys. 2003, 5, 2398-2409
7. Jiang, S.; Chen, Q.; Tripathy, M.; Luijten, E.; Schweizer, K. S.; Granick, S. Janus Particle Synthesis and Assembly Adv. Mater. 2010, 22, 1060-1071
8. Juárez, J. A.; Whitby, C. P. Oil-in-water Pickering emulsion destabilisation at low particle concentrations J. Colloid Interface Sci. 2012, 368, 319-325
9. Binks, B.; Lumsdon, S. Influence of particle wettability on the type and stability of surfactant-free emulsions Langmuir 2000, 16, 8622-8631
10. de Gennes, P. G. Soft matter Rev. Mod. Phys. 1992, 64, 645-648
11. Glaser, N.; Adams, D. J.; Böker, A.; Krausch, G. Janus particles at liquid-liquid interfaces Langmuir 2006, 22, 5227-5229
12. Binks, B.; Fletcher, P. Particles adsorbed at the oil-water interface: A theoretical comparison between spheres of uniform wettability and "Janus" particles Langmuir 2001, 17, 4708-4710
13. Walther, A.; Hoffmann, M.; Müller, A. H. E. Emulsion Polymerization Using Janus Particles as Stabilizers Angew. Chem., Int. Ed. 2008, 47, 711-714
14. Mejia, A. F.; Diaz, A.; Pullela, S.; Chang, Y.-W.; Simonetty, M.; Carpenter, C.; Batteas, J. D.; Mannan, M. S.; Clearfield, A.; Cheng, Z. Pickering emulsions stabilized by amphiphilic nano-sheets Soft Matter 2012, 8, 10245-10253
15. Faria, J.; Ruiz, M. P.; Resasco, D. E. Phase-Selective Catalysis in Emulsions Stabilized by Janus Silica-Nanoparticles Adv. Synth. Catal. 2010, 352, 2359-2364
16. Fujii, S.; Yokoyama, Y.; Miyanari, Y.; Shiono, T.; Ito, M.; Yusa, S.-i.; Nakamura, Y. Micrometer-Sized Gold-Silica Janus Particles as Particulate Emulsifiers Langmuir 2013, 29, 5457-5465
17. Levine, S.; Bowen, B. D. Capillary interaction of spherical particles adsorbed on the surface of an oil/water droplet stabilized by the particles. Part I Colloids Surf. 1991, 59, 377-386
18. Aveyard, R. Can Janus particles give thermodynamically stable Pickering emulsions? Soft Matter 2012, 8, 5233-5240
19. Perro, A.; Reculusa, S.; Ravaine, S.; Bourgeat-Lami, E.; Duguet, E. Design and synthesis of Janus micro- and nanoparticles J. Mater. Chem. 2005, 15, 3745-3760
20. Wurm, F.; Kilbinger, A. F. M. Polymeric Janus Particles Angew. Chem., Int. Ed. 2009, 48, 8412-8421
21. Hu, J.; Zhou, S.; Sun, Y.; Fang, X.; Wu, L. Fabrication, properties and applications of Janus particles Chem. Soc. Rev. 2012, 41, 4356-4378
22. Walther, A.; Müller, A. H. E. Janus Particles: Synthesis, Self-Assembly, Physical Properties, and Applications Chem. Rev. 2013, 113, 5194-5261
23. Casagrande, C.; Fabre, P.; Raphael, E.; Veyssie, M. Water/Oil Interfaces Europhys. Lett. 1989, 9, 251-255
24. Takei, H.; Shimizu, N. Gradient Sensitive Microscopic Probes Prepared by Gold Evaporation and Chemisorption on Latex Spheres Langmuir 1997, 13, 1865-1868
25. Fujimoto, K.; Nakahama, K.; Shidara, M.; Kawaguchi, H. Preparation of Unsymmetrical Microspheres at the Interfaces Langmuir 1999, 15, 4630-4635
26. Paunov, V. N.; Cayre, O. J. Supraparticles and "Janus" Particles Fabricated by Replication of Particle Monolayers at Liquid Surfaces Using a Gel Trapping Technique Adv. Mater. 2004, 16, 788-791
27. Roh, K.-H.; Martin, D. C.; Lahann, J. Biphasic Janus particles with nanoscale anisotropy Nat. Mater. 2005, 4, 759-763
28. Nie, Z.; Li, W.; Seo, M.; Xu, S.; Kumacheva, E. Janus and Ternary Particles Generated by Microfluidic Synthesis: Design, Synthesis, and Self-Assembly J. Am. Chem. Soc. 2006, 128, 9408-9412
29. Nisisako, T.; Torii, T.; Takahashi, T.; Takizawa, Y. Synthesis of Monodisperse Bicolored Janus Particles with Electrical Anisotropy Using a Microfluidic Co-Flow System Adv. Mater. 2006, 18, 1152-1156
30. Shepherd, R. F.; Conrad, J. C.; Rhodes, S. K.; Link, D. R.; Marquez, M.; Weitz, D. A.; Lewis, J. A. Microfluidic Assembly of Homogeneous and Janus Colloid-Filled Hydrogel Granules Langmuir 2006, 22, 8618-8622
31. Nisisako, T.; Torii, T. Formation of Biphasic Janus Droplets in a Microfabricated Channel for the Synthesis of Shape-Controlled Polymer Microparticles Adv. Mater. 2007, 19, 1489-1493
32. Takahara, Y. K.; Ikeda, S.; Ishino, S.; Tachi, K.; Ikeue, K.; Sakata, T.; Hasegawa, T.; Mori, H.; Matsumura, M.; Ohtani, B. Asymmetrically Modified Silica Particles: A Simple Particulate Surfactant for Stabilization of Oil Droplets in Water J. Am. Chem. Soc. 2005, 127, 6271-6275
33. Hong, L.; Jiang, S.; Granick, S. Simple method to produce Janus colloidal particles in large quantity Langmuir 2006, 22, 9495-9499
34. Suzuki, D.; Tsuji, S.; Kawaguchi, H. Janus Microgels Prepared by Surfactant-Free Pickering Emulsion-Based Modification and Their Self-Assembly J. Am. Chem. Soc. 2007, 129, 8088-8089
35. Liu, B.; Wei, W.; Qu, X.; Yang, Z. Janus Colloids Formed by Biphasic Grafting at a Pickering Emulsion Interface Angew. Chem., Int. Ed. 2008, 47, 3973-3975
36. Perro, A.; Meunier, F.; Schmitt, V.; Ravaine, S. Production of large quantities of "Janus" nanoparticles using wax-in-water emulsions Colloids Surf., A 2009, 332, 57-62
37. Kim, J.-W.; Lee, D.; Shum, H. C.; Weitz, D. A. Colloid Surfactants for Emulsion Stabilization Adv. Mater. 2008, 20, 3239-3243
38. Sheu, H. R.; El-Aasser, M. S.; Vanderhoff, J. W. Phase separation in polystyrene latex interpenetrating polymer networks J. Polym. Sci., Polym. Chem. 1990, 28, 629-651
39. Mock, E. B.; De Bruyn, H.; Hawkett, B. S.; Gilbert, R. G.; Zukoski, C. F. Synthesis of Anisotropic Nanoparticles by Seeded Emulsion Polymerization Langmuir 2006, 22, 4037-4043
40. Park, J. G.; Forster, J. D.; Dufresne, E. R. High-yield synthesis of monodisperse dumbbell-shaped polymer nanoparticles J. Am. Chem. Soc. 2010, 132, 5960-5961
41. Yoon, K.; Lee, D.; Kim, J. W.; Kim, J.; Weitz, D. A. Asymmetric functionalization of colloidal dimer particles with gold nanoparticles Chem. Commun. 2012, 48, 9056-9058
42. Kuhn, H.; Försterling, H.-D.; Waldeck, D. H. Principles of Physical Chemistry; Wiley-Interscience: Hoboken, NJ, 2009.
43. Park, B. J.; Lee, D. Equilibrium Orientation of Nonspherical Janus Particles at Fluid-Fluid Interfaces ACS Nano 2011, 6, 782-790
44. Park, B. J.; Lee, D. Configuration of nonspherical amphiphilic particles at a fluid-fluid interface Soft Matter 2012, 8, 7690-7698
45. Brugarolas, T.; Park, B. J.; Lee, M. H.; Lee, D. Generation of Amphiphilic Janus Bubbles and Their Behavior at an Air-Water Interface Adv. Funct. Mater. 2011, 21, 3924-3931
46. Park, B. J.; Brugarolas, T.; Lee, D. Janus particles at an oil-water interface Soft Matter 2011, 7, 6413-6417
47. Kumar, A.; Park, B. J.; Tu, F.; Lee, D. Amphiphilic Janus particles at fluid interfaces Soft Matter 2013, 9, 6604-6617
48. Kralchevsky, P. A.; Denkov, N. D.; Danov, K. D. Particles with an Undulated Contact Line at a Fluid Interface: Interaction between Capillary Quadrupoles and Rheology of Particulate Monolayers Langmuir 2001, 17, 7694-7705
49. Stamou, D.; Duschl, C.; Johannsmann, D. Long-range attraction between colloidal spheres at the air-water interface: The consequence of an irregular meniscus Phys. Rev. E 2000, 62, 5263-5272
50. Hirose, Y.; Komura, S.; Nonomura, Y. Adsorption of Janus particles to curved interfaces J. Chem. Phys. 2007, 127, 054707
51. Hardin, R. H.; Sloane, N. J. A.; Smith, W. D. Tables of Spherical Codes with Icosahedral Symmetry; published online at http://neilsloane.com/ icosahedral.codes/index.html.
52. Arditty, S.; Whitby, C. P.; Binks, B. P.; Schmitt, V.; Leal-Calderon, F. Some general features of limited coalescence in solid-stabilized emulsions Eur. Phys. J. E 2003, 11, 273-281
53. AbismaIïl, B.; Canselier, J. P.; Wilhelm, A. M.; Delmas, H.; Gourdon, C. Emulsification by ultrasound: drop size distribution and stability Ultrason. Sonochem. 1999, 6, 75-83
54. Vladisavljević, G. T.; Schubert, H. Influence of process parameters on droplet size distribution in SPG membrane emulsification and stability of prepared emulsion droplets J. Membr. Sci. 2003, 225, 15-23
55. Thompson, K. L.; Armes, S. P.; York, D. W. Preparation of Pickering Emulsions and Colloidosomes with Relatively Narrow Size Distributions by Stirred Cell Membrane Emulsification Langmuir 2011, 27, 2357-2363
56. Sauter, J. Die Größenbestimmung der im Gemischnebel von Verbrennungskraftmaschinen vorhandenen Brennstoffteilchen; VDI-Verlag: Dusseldorf, 1926.