Methanol oxidation at diamond-supported Pt nanoparticles: Effect of the diamond surface termination

Journal of Physical Chemistry C

Volumn 117, Issue 42, 2013, Pages 21735-21742

  Celorrio, V ^a,b   Plana, D ^a   Florez Montano J ^c   Montes De Oca, M G ^a   Moore, A ^a   Lazaro M J ^b   Pastor, E ^c   Fermin D J ^a  

^a UNIVERSITY OF BRISTOL   (United Kingdom)

^b INSTITUTO DE CARBOQUÍMICA   (Spain)

^c UNIVERSIDAD DE LA LAGUNA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON DIOXIDE; CURRENT DENSITY; DIAMONDS; ELECTROCATALYSTS; FORMIC ACID; MASS SPECTROMETRY; METAL NANOPARTICLES; METHANOL; OXIDATION; PLATINUM; REACTION INTERMEDIATES; SURFACE TREATMENT;

DIFFERENTIAL ELECTROCHEMICAL MASS SPECTROMETRY; ELECTROCATALYST SUPPORT; ELECTROCATALYTIC REACTIVITY; FORMIC ACID OXIDATION; METHANOL OXIDATION; OXIDATION OF FORMIC ACIDS; SURFACE TERMINATION; VOLTAMMETRIC RESPONSE;

PLATINUM COMPOUNDS;

EID: 84886645909     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp4039804     Document Type: Article

References (62)

1. Jusys, Z.; Behm, R. J. Methanol, Formaldehyde, and Formic Acid Adsorption/Oxidation on a Carbon-Supported Pt Nanoparticle Fuel Cell Catalyst: A Comparative Quantitative DEMS Study. In Fuel Cell Catalysis; John Wiley & Sons, Inc.: New York, 2008; pp 411-464.
2. Wang, H.; Abruña, H. Electrocatalysis of Direct Alcohol Fuel Cells: Quantitative DEMS Studies Fuel Cells and Hydrogen Storage; Bocarsly, A.; Mingos, D. M. P., Eds.; Springer: Berlin, 2011; Vol. 141, pp 33-83.
3. Planes, G. A.; García, G.; Pastor, E. High Performance Mesoporous Pt Electrode for Methanol Electrooxidation. A DEMS Study Electrochem. Commun. 2007, 9, 839-844
4. Wang, H.; Löffler, T.; Baltruschat, H. Formation of Intermediates during Methanol Oxidation: A Quantitative DEMS Study J. Appl. Electrochem. 2001, 31, 759-765
5. Rabis, A.; Rodriguez, P.; Schmidt, T. J. Electrocatalysis for Polymer Electrolyte Fuel Cells: Recent Achievements and Future Challenges ACS Catal. 2012, 2, 864-890
6. Wang, H.; Baltruschat, H. DEMS Study on Methanol Oxidation at Poly- and Monocrystalline Platinum Electrodes: The Effect of Anion, Temperature, Surface Structure, Ru Adatom, and Potential J. Phys. Chem. C 2007, 111, 7038-7048
7. Jusys, Z.; Behm, R. J. Methanol Oxidation on a Carbon-Supported Pt Fuel Cell CatalystA Kinetic and Mechanistic Study by Differential Electrochemical Mass Spectrometry J. Phys. Chem. B 2001, 105, 10874-10883
8. Lázaro, M. J.; Celorrio, V.; Calvillo, L.; Pastor, E.; Moliner, R. Influence of the Synthesis Method on the Properties of Pt Catalysts Supported on Carbon Nanocoils for Ethanol Oxidation J. Power Sources 2011, 196, 4236-4241
9. Calvillo, L.; Celorrio, V.; Moliner, R.; Lázaro, M. J. Influence of the Support on the Physicochemical Properties of Pt Electrocatalysts: Comparison of Catalysts Supported on Different Carbon Materials Mater. Chem. Phys. 2011, 127, 335-341
10. Aksoylu, A. E.; Madalena, M.; Freitas, A.; Pereira, M. F. R.; Figueiredo, J. L. The Effects of Different Activated Carbon Supports and Support Modifications on the Properties of Pt/C Catalysts Carbon 2001, 39, 175-185
11. Sharma, S.; Pollet, B. G. Support Materials for PEMFC and DMFC Electrocatalysts-A Review J. Power Sources 2012, 208, 96-119
12. Kim, M.; Park, J.-N.; Kim, H.; Song, S.; Lee, W.-H. The Preparation of Pt/C Catalysts Using Various Carbon Materials for the Cathode of PEMFC J. Power Sources 2006, 163, 93-97
13. Yu, X.; Ye, S. Recent Advances in Activity and Durability Enhancement of Pt/C Catalytic Cathode in PEMFC: Part I. Physico-Chemical and Electronic Interaction Between Pt and Carbon Support, and Activity Enhancement of Pt/C Catalyst J. Power Sources 2007, 172, 133-144
14. Calvillo, L.; Lázaro, M. J.; García-Bordejé, E.; Moliner, R.; Cabot, P. L.; Esparbé, I.; Pastor, E.; Quintana, J. J. Platinum Supported on Functionalized Ordered Mesoporous Carbon as Electrocatalyst for Direct Methanol Fuel Cells J. Power Sources 2007, 169, 59-64
15. Calvillo, L.; zaro, M. J.; Suelves, I.; Echegoyen, Y.; Bordej, G. E.; Moliner, R. Study of the Surface Chemistry of Modified Carbon Nanofibers by Oxidation Treatments in Liquid Phase J. Nanosci. Nanotechnol. 2009, 9, 4164-4169
16. Moreno-Castilla, C.; Ferro-Garcia, M. A.; Joly, J. P.; Bautista-Toledo, I.; Carrasco-Marin, F.; Rivera-Utrilla, J. Activated Carbon Surface Modifications by Nitric Acid, Hydrogen Peroxide, and Ammonium Peroxydisulfate Treatments Langmuir 1995, 11, 4386-4392
17. Figueiredo, J. L.; Pereira, M. F. R. The Role of Surface Chemistry in Catalysis with Carbons Catal. Today 2010, 150, 2-7
18. 3 Treatment on the Surface Acidity of Activated Carbons Carbon 1990, 28, 675-682
19. Darmstadt, H.; Roy, C.; Kaliaguine, S.; Choi, S. J.; Ryoo, R. Surface Chemistry of Ordered Mesoporous Carbons Carbon 2002, 40, 2673-2683
20. Celorrio, V.; Montes de Oca, M. G.; Plana, D.; Moliner, R.; Fermín, D. J.; Lázaro, M. J. Electrochemical Performance of Pd and Au-Pd Core-Shell Nanoparticles on Surface Tailored Carbon Black as Catalyst Support Int. J. Hydrogen Energy 2012, 37, 7152-7160
21. Materlik, G. Diamond will Shine Brightly for Chemistry Chem. Commun. 2003, 0, 1021-1023
22. Krueger, A. Diamond Nanoparticles: Jewels for Chemistry and Physics Adv. Mater. 2008, 20, 2445-2449
23. Huang, H.; Dai, L.; Wang, D. H.; Tan, L.-S.; Osawa, E. Large-Scale Self-Assembly of Dispersed Nanodiamonds J. Mater. Chem. 2008, 18, 1347-1352
24. Chakrapani, V.; Angus, J. C.; Anderson, A. B.; Wolter, S. D.; Stoner, B. R.; Sumanasekera, G. U. Charge Transfer Equilibria Between Diamond and an Aqueous Oxygen Electrochemical Redox Couple Science 2007, 318, 1424-1430
25. Liu, Y.; Gu, Z.; Margrave, J. L.; Khabashesku, V. N. Functionalization of Nanoscale Diamond Powder: Fluoro-, Alkyl-, Amino-, and Amino Acid-Nanodiamond Derivatives Chem. Mater. 2004, 16, 3924-3930
26. Krueger, A.; Lang, D. Functionality is Key: Recent Progress in the Surface Modification of Nanodiamond Adv. Funct. Mater. 2012, 22, 890-906
27. Moore, A.; Celorrio, V.; de Oca, M. M.; Plana, D.; Hongthani, W.; Lazaro, M. J.; Fermin, D. J. Insulating diamond particles as substrate for Pd electrocatalysts Chem. Commun. 2011, 47, 7656-7658
28. Wang, J.; Swain, G. M. Fabrication and Evaluation of Platinum/Diamond Composite Electrodes for Electrocatalysis J. Electrochem. Soc. 2003, 150, E24-E32
29. SpaÌ;taru, N.; Zhang, X.; Spătaru, T. a.; Tryk, D. A.; Fujishima, A. Platinum Electrodeposition on Conductive Diamond Powder and Its Application to Methanol Oxidation in Acidic Media J. Electrochem. Soc. 2008, 155, B264
30. SpaÌtaru, T.; Anastasescu, M.; SpaÌtaru, N.; Fujishima, A. Influence of Cobalt Oxide Substrate on the Resistance to Fouling during Methanol Oxidation of Platinum Particles Electrochem. Commun. 2013, 29, 1-3
31. La-Torre-Riveros, L.; Abel-Tatis, E.; Méndez-Torres, A.; Tryk, D.; Prelas, M.; Cabrera, C. Synthesis of Platinum and Platinum-Ruthenium-Modified Diamond Nanoparticles J. Nanopart. Res. 2011, 13, 2997-3009
32. La-Torre-Riveros, L.; Guzman-Blas, R.; Méndez-Torres, A. E.; Prelas, M.; Tryk, D. A.; Cabrera, C. R. Diamond Nanoparticles as a Support for Pt and PtRu Catalysts for Direct Methanol Fuel Cells ACS Appl. Mater. Interfaces 2012, 4, 1134-1147
33. González-González, I.; Tryk, D. A.; Cabrera, C. R. Polycrystalline Boron-Doped Diamond Films as Supports for Methanol Oxidation Electrocatalysts Diamond Relat. Mater. 2006, 15, 275-278
34. Plana, D.; Humphrey, J. J. L.; Bradley, K. A.; Celorrio, V.; Fermín, D. J. Charge Transport Across High Surface Area Metal/Diamond Nanostructured Composites ACS Appl. Mater. Interfaces 2013, 5, 2985-2990
35. Maier, F.; Riedel, M.; Mantel, B.; Ristein, J.; Ley, L. Origin of Surface Conductivity in Diamond Phys. Rev. Lett. 2000, 85, 3472-3475
36. Hongthani, W.; Fox, N. A.; Fermín, D. J. Electrochemical Properties of Two Dimensional Assemblies of Insulating Diamond Particles Langmuir 2011, 27, 5112-5118
37. Holt, K. B. Undoped Diamond Nanoparticles: Origins of Surface Redox Chemistry Phys. Chem. Chem. Phys. 2010, 12, 2048-2058
38. Hongthani, W.; Fermín, D. J. Layer-by-Layer Assembly and Redox Properties of Undoped HPHT Diamond Particles Diamond Relat. Mater. 2010, 19, 680-684
39. Holt, K. B.; Ziegler, C.; Zang, J.; Hu, J.; Foord, J. S. Scanning Electrochemical Microscopy Studies of Redox Processes at Undoped Nanodiamond Surfaces J. Phys. Chem. C 2009, 113, 2761-2770
40. Pérez-Rodríguez, S.; Corengia, M.; García, G.; Zinola, C. F.; Lázaro, M. J.; Pastor, E. Gas Diffusion Electrodes for Methanol Electrooxidation Studied by a New DEMS Configuration: Influence of the Diffusion Layer Int. J. Hydrogen Energy 2012, 37, 7141-7151
41. 2 Electroreduction to High-Added Value Products: A DEMS Study: Effect of the Functionalization of the Support Int. J. Electrochem. 2011, 10.4061/2011/249804
42. Fraga, M. A.; Jordão, E.; Mendes, M. J.; Freitas, M. M. A.; Faria, J. L.; Figueiredo, J. L. Properties of Carbon-Supported Platinum Catalysts: Role of Carbon Surface Sites J. Catal. 2002, 209, 355-364
43. Guerrero-Ruiz, A.; Badenes, P.; Rodríguez-Ramos, I. Study of Some Factors Affecting the Ru and Pt Dispersions over High Surface Area Graphite-Supported Catalysts Appl. Catal., A 1998, 173, 313-321
44. Vidaković, T.; Christov, M.; Sundmacher, K. The Use of CO Stripping for in Situ Fuel Cell Catalyst Characterization Electrochim. Acta 2007, 52, 5606-5613
45. Maillard, F.; Eikerling, M.; Cherstiouk, O. V.; Schreier, S.; Savinova, E.; Stimming, U. Size Effects on Reactivity of Pt Nanoparticles in CO Monolayer Oxidation: The Role of Surface Mobility Faraday Discuss. 2004, 125, 357-377
46. Hayden, B. E.; Pletcher, D.; Suchsland, J.-P.; Williams, L. J. The Influence of Support and Particle Size on the Platinum Catalysed Oxygen Reduction Reaction Phys. Chem. Chem. Phys. 2009, 11, 9141-9148
47. Wang, S.; Jiang, S. P.; White, T. J.; Guo, J.; Wang, X. Electrocatalytic Activity and Interconnectivity of Pt Nanoparticles on Multiwalled Carbon Nanotubes for Fuel Cells J. Phys. Chem. C 2009, 113, 18935-18945
48. Cherstiouk, O. V.; Simonov, P. A.; Savinova, E. R. Model Approach to Evaluate Particle Size Effects in Electrocatalysis Preparation and Properties of Pt Nanoparticles Supported on GC and HOPG Electrochim. Acta 2003, 48, 3851-3860
49. Maillard, F.; Schreier, S.; Hanzlik, M.; Savinova, E. R.; Weinkauf, S.; Stimming, U. Influence of Particle Agglomeration on the Catalytic Activity of Carbon-Supported Pt Nanoparticles in CO Monolayer Oxidation Phys. Chem. Chem. Phys. 2005, 7, 385-393
50. Guerin, S.; Hayden, B. E.; Lee, C. E.; Mormiche, C.; Owen, J. R.; Russell, A. E.; Theobald, B.; Thompsett, D. Combinatorial Electrochemical Screening of Fuel Cell Electrocatalysts J. Comb. Chem. 2003, 6, 149-158
51. Maillard, F.; Savinova, E. R.; Simonov, P. A.; Zaikovskii, V. I.; Stimming, U. Infrared Spectroscopic Study of CO Adsorption and Electro-oxidation on Carbon-Supported Pt Nanoparticles: Interparticle versus Intraparticle Heterogeneity J. Phys. Chem. B 2004, 108, 17893-17904
52. Jusys, Z.; Kaiser, J.; Behm, R. J. Methanol Electrooxidation over Pt/C Fuel Cell Catalysts: Dependence of Product Yields on Catalyst Loading Langmuir 2003, 19, 6759-6769
53. García, G.; Florez-Montaño, J.; Hernandez-Creus, A.; Pastor, E.; Planes, G. A. Methanol Electrooxidation at Mesoporous Pt and Pt-Ru Electrodes: A Comparative Study with Carbon Supported Materials J. Power Sources 2011, 196, 2979-2986
54. Liu, Z.; Hong, L.; Tham, M. P.; Lim, T. H.; Jiang, H. Nanostructured Pt/C and Pd/C Catalysts for Direct Formic Acid Fuel Cells J. Power Sources 2006, 161, 831-835
55. Wu, Y. N.; Liao, S. J.; Su, Y. L.; Zeng, J. H.; Dang, D. Enhancement of Anodic Oxidation of Formic Acid on Palladium Decorated Pt/C Catalyst J. Power Sources 2010, 195, 6459-6462
56. Hong, P.; Luo, F.; Liao, S.; Zeng, J. Effects of Pt/C, Pd/C and PdPt/C Anode Catalysts on the Performance and Stability of Air Breathing Direct Formic Acid Fuel Cells Int. J. Hydrogen Energy 2011, 36, 8518-8524
57. Jovanović, V. M.; Tripković, D.; Tripković, A.; Kowal, A.; Stoch, J. Oxidation of Formic Acid on Platinum Electrodeposited on Polished and Oxidized Glassy Carbon Electrochem. Commun. 2005, 7, 1039-1044
58. Samjeské, G.; Miki, A.; Ye, S.; Osawa, M. Mechanistic Study of Electrocatalytic Oxidation of Formic Acid at Platinum in Acidic Solution by Time-Resolved Surface-Enhanced Infrared Absorption Spectroscopy J. Phys. Chem. B 2006, 110, 16559-16566
59. Osawa, M.; Komatsu, K.-i.; Samjeské, G.; Uchida, T.; Ikeshoji, T.; Cuesta, A.; Gutiérrez, C. The Role of Bridge-Bonded Adsorbed Formate in the Electrocatalytic Oxidation of Formic Acid on Platinum Angew. Chem., Int. Ed. 2011, 50, 1159-1163
60. Cuesta, A.; Cabello, G.; Gutierrez, C.; Osawa, M. Adsorbed Formate: the Key Intermediate in the Oxidation of Formic Acid on Platinum Electrodes Phys. Chem. Chem. Phys. 2011, 13, 20091-20095
61. Haertl, A.; Garrido, J. A.; Nowy, S.; Zimmermann, R.; Werner, C.; Horinek, D.; Netz, R.; Stutzmann, M. The Ion Sensitivity of Surface Conductive Single Crystalline Diamond J. Am. Chem. Soc. 2007, 129, 1287-1292
62. O'Donnell, K. M.; Martin, T. L.; Fox, N. A.; Cherns, D. Ab Initio Investigation of Lithium on the Diamond C(100) Surface Phys. Rev. B 2010, 82, 115303