The impact of post gold mining on mercury pollution in the West Rand region, Gauteng, South Africa

Journal of Geochemical Exploration

Volumn 134, Issue , 2013, Pages 111-119

  Lusilao Makiese, J G ^a   Cukrowska, E M ^a   Tessier, E ^b   Amouroux, D ^b   Weiersbye, I ^a  

^a UNIVERSITY OF THE WITWATERSRAND   (South Africa)

^b UNIVERSITÉ DE PAU ET DES PAYS DE L'ADOUR   (France)

Author keywords

Gold mining; Mercury; Modeling; Speciation

Indexed keywords

EXTRACTION OF GOLDS; EXTRACTION PROCEDURE; GEOCHEMICAL MODELING; GOLD MINING; GROUNDWATER CONTAMINATION; HORIZONTAL TRANSPORT; SPECIATION; SURFACE SEDIMENTS;

ALKYLATION; EXTRACTION; GOLD; GROUNDWATER; MERCURY (METAL); METHYLATION; MODELS; REDOX REACTIONS; SURFICIAL SEDIMENTS; WATER POLLUTION; WATERSHEDS;

GOLD MINES;

ABANDONED MINE; ACID MINE DRAINAGE; ENVIRONMENTAL IMPACT; GOLD MINE; GROUNDWATER POLLUTION; MERCURY (ELEMENT); MINING; MODELING; POLLUTANT TRANSPORT; SPECIATION (CHEMISTRY);

GAUTENG; SOUTH AFRICA;

EID: 84886595547     PISSN: 03756742     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.gexplo.2013.08.010     Document Type: Article

References (44)

1. Appleton J.D., Williams T., Orbea H., Carrasco M. Fluvial contamination associated with artisanal gold mining in the Ponce Enríquez, Portovelo-Zaruma and Nambija areas, Ecuador. Water Air Soil Pollut. 2001, 131:19-39.
2. Benes P., Havlik B. Speciation of mercury in natural waters. Biogeochemistry of Mercury in the Environment 1979, 176-202. The Elsevier, North-Holland Biomedical Press, Amsterdam. J.O. Nriagu (Ed.).
3. Blester H., Muller G., Scholer H.F. Binding and mobility of mercury in soils contaminated by emissions from chlor-alkali plants. Sci. Total. Environ. 2002, 284(1-3):191-203.
4. Boszke L., Kowalski A., Głosińska G., Szarek R., Siepak J. Selected factors affecting the speciation of mercury in the bottom sediments: an overview. Pol. J. Environ. Stud. 2003, 12(1):5-13.
5. Dai Q., Feng X., Qiu G., Jiang H. Preliminary study on mercury contamination in gold mining in Tongguan County of Shanxi Province. Environ. Chem. 2004, 23:460-464.
6. Dietz C., Madrid Y., Camara C. Mercury speciation using the capillary cold trap coupled with microwave induced plasma atomic emission spectrometry. J. Anal. At. Spectrom. 2001, 16:1397-1402.
7. Dixon K.L. Background concentrations of metals in wetland soils on and near the Savannah River Site. WSRC-MS-97-00692 Rev 1997, 1:1-19.
8. Erasmus C.S., Sellschop J.P.F., Hallbauer D.K. Major amounts of mercury in native gold from upper Witwatersrand sediments. Mintek Report No M54 1982, 1-23. Council for Mineral Technology, South Africa.
9. Feuilherade P. South African Environment Pays Price for Century of Mining Available from:, (Accessed on 26/01/11). http://www.suite101.com/content/south-african-environment-pays-price-of-century-of-mining-a286577.
10. Ganguli P.M., Mason R.P., Abu-Saba K.E., Anderson R.S., Flegal A.R. Mercury speciation in drainage from the New Idria Mercury Mine, California. Environ. Sci. Technol. 2000, 34:4773-4779.
11. Garcia-Sanchez A., Contreras F., Adams M., Santos F. Atmospheric mercury emissions from polluted gold mining areas (Venezuela). Environ. Geochem. Heal. 2006, 28:529-540.
12. Huggins F.E. Overview of analytical methods for inorganic constituents in coal. Int. J. Coal Geol. 2002, 50:169-214.
13. Kannan K., Falandysz J. Speciation and concentration of mercury in certain coastal marine sediments. Water Air Soil Pollut. 1998, 103:129-136.
14. Kaplan D.L., Myers J., Knox A.C., lverson G., Serkiz S. Mercury speciation modeling using site specific chemical and redox data from the TNXOD OU. A Westinghouse Savannah River Company Report, WSRC-TR-2000-OO058 2000, 1-44.
15. Lacerda L.D., Salomons W. Mercury from gold and silver mining: a chemical time bomb?. Environmental Science Series 1998, 146. Springer, Berlin. R. Allan, U. FoÈrstner, W. Salomons (Eds.).
16. Lang S. Environment-South Africa, Radioactive Water, the Price of Gold Available from:, (Accessed on 26/01/2011). http://ipsnews.net/news.asp?idnews=40325.
17. Leermakers M., Galletti S., De Galan S., Brion N., Baeyens W. Mercury in the southern North Sea and Scheldt Estuary. Mar. Chem. 2001, 75:229-248.
18. Li J., Lu Y., Shim H., Deng X., Lian J., Jiad Z., Lid J. Use of the BCR sequential extraction procedure for the study of metal availability to plants. J. Environ. Monit. 2010, 12:466-471.
19. Lusilao-Makiese J., Tessier E., Amouroux D., Tutu H., Chimuka L., Cukrowska E.M. Speciation of mercury in South African coals. Toxicol. Environ. Chem. 2012, 94(9):1688-1706.
20. McCarthy T.S., Venter J.S. Increasing pollution levels on the Witwatersrand recorded in the peat deposits on the Klip River wetland. S. Afr. J. Sci. 2006, 102:27-34.
21. Monperrus M., Tessier E., Veschambre S., Amouroux D., Donard O. Simultaneous speciation of mercury and butyltin compounds in natural waters and snow by propylation and species-specific isotope dilution mass spectrometry analysis. Anal. Bioanal. Chem. 2005, 381:854-862.
22. Montgomery S., Mucci A., Lucotte M., Pichet P. Total dissolved Hg in the water column of several natural and artificial systems of Northern Quebec, Canada. Can. J. Fish. Aquat. Sci. 1995, 52:2483-2492.
23. Naicker K., Cukrowska E., McCarthy T.S. Acid mine drainage arising from gold mining activity in Johannesburg, South Africa and environs. Environ. Pollut. 2003, 122:29-40.
24. Navarro A., Cardellach E., Corbella M. Mercury mobility in mine waste from Hg-mining areas in Almería, Andalusia (Se Spain). J. Geochem. Explor. 2009, 101:236-246.
25. Parker J.L., Bloom N.S. Preservation and storage techniques for low level aqueous mercury speciation. Sci. Total. Environ. 2005, 337:253-263.
26. Pestana M.H.D., Lechlerb P., Formosoc M.L.L., Millerd J. Mercury in sediments from gold and copper exploitation areas in the Camaquä River Basin, Southern Brazil. J. S. Am. Earth Sci. 2000, 13:537-547.
27. Quevauviller P. Metrologie en chimie de l'environnment 2001, 257. (London). Tec & Doc Lavoisier (Ed.).
28. Rosner T., van Schalkwyk A. The environmental impact of gold mine tailings footprints in the Johannesburg region, South Africa. Bull. Eng. Geol. Environ. 2000, 59:137-148.
29. Santos-Francés F., García-Sánchez A., Alonso-Rojo P., Contreras F., Adams M. Distribution and mobility of mercury in soils of a gold mining region, Cuyuni river basin, Venezuela. J. Environ. Manage. 2011, 92:1268-1276.
30. Schroeder W.H., Lindqvist O., Munthe J., Xiao Z. Volatilization of mercury from lake surfaces. Sci. Total. Environ. 1992, 125:47-66.
31. Schuster E. The behavior of mercury in the soil with special emphasis of complexation and adsorption processes-a review of the literature. Water Air Soil Pollut. 1991, 56:667-680.
32. Skillberg U., Bloom P.R., Qian J., Lin C.M., Bleam W.F. Complexation of mercury (II) in soil organic matter: EXAFS evidence for linear two-coordination with reduced sulphur groups. Environ. Sci. Technol. 2006, 40:4174-4180.
33. Steinnes E. Mercury. Heavy Metals in Soils 1990, 222-236. Blackie and Son, Glasgow. B.J. Alloway (Ed.).
34. Stoichev T., Amouroux D., Rodriguez Martin-Doimeadios R.C., Monperrus M., Donard O.F.X., Tsalev D.L. Speciation analysis of mercury in aquatic environment. Appl. Spectrosc. Rev. 2006, 41:591-619.
35. Tseng C.M., De Diego A., Martin F.M., Donard O.F.X. Rapid and quantitative microwave-assisted recovery of methylmercury from standard reference sediments. J. Anal. At. Spectrom. 1997, 12:629-635.
36. Tutu H. Mining and Water Pollution 2012, InTech, (Available from: http://www.intechopen.com/books/water-qualitymonitoring-and-assessment/mining-and-water-pollution. Accessed on 05/03/2013). Voudouris (Ed.).
37. USEPA Water quality standards, establishment of numeric criteria for priority toxic pollutants. States' compliance, Final rule, Federal Register, 40 CFR Part 131 1992, vol. 246:847-860.
38. USEPA SW-846 Methods, Chapter 3: inorganic analytes. Rev.4, February 2007 Available from:, (Accessed on 27/06/2011). http://www.epa.gov/osw/hazard/testmethods/sw846/pdfs/chap3.pdf.
39. Varekamp J.C., Buchholtz ten Brink M.R., Mecray E.L., Kreulen B. Mercury in Long Island Sound sediments. J. Coast. Res. 2000, 16:613-626.
40. Wallschlager D., Desai M.V.M., Spenger M., Wilken R. Mercury speciation in floodplain soils and sediments along a contaminated river transect. J. Environ. Qual. 1998, 27:1034-1044.
41. Wallschlager D., Desai M.V.M., Spenger M., Windmoler C.C., Wilken R. How humic substances dominate mercury geochemistry in contaminated floodplain soils and sediments. J. Environ. Qual. 1998, 27:1044-1054.
42. Yan H., Feng X., Shang L., Qiu G., Dai Q., Wang S., Hou Y. The variations of mercury in sediment profiles from a historically mercury-contaminated reservoir, Guizhou province, China. Sci. Total. Environ. 2008, 407:497-506.
43. Yin Y., Allen H.E., Huang C.P. Kinetics of mercury (II) adsorption and desorption on soil. Environ. Sci. Technol. 1997, 37:496-503.
44. Zagury G.J., Neculita C.-M., Bastien C., Deschenes L. Mercury fractionation, bioavailability, and ecotoxicity in highly contaminated soils from chlor-alkali plants. Environ. Toxicol. Chem. 2006, 25(4):1138-1147.