Ancient projectile weapons from ice patches in northwestern Canada: Identification of resin and compound resin-ochre hafting adhesives

Journal of Archaeological Science

Volumn 41, Issue , 2014, Pages 655-665

  Helwig, Kate ^a   Monahan, Valery ^b   Poulin, Jennifer ^a   Andrews, Thomas D ^c  

^a CANADIAN CONSERVATION INSTITUTE   (Canada)

^b Government of Yukon   (Canada)

^c Prince of Wales Northern Heritage Centre   (Canada)

Author keywords

Hafting adhesive; Natural resin; Northwest Territories; Projectile weaponry; Red ochre; Spruce; Yukon

Indexed keywords

ADHESION; ARCHAEOLOGY; FTIR SPECTROSCOPY; GAS CHROMATOGRAPHY; ICE; RAMAN SPECTROSCOPY; SCANNING ELECTRON MICROSCOPY; WEAPONRY; ARCHAEOLOGICAL EVIDENCE; ARTIFACT; HOLOCENE; IDENTIFICATION METHOD; RADIOCARBON DATING; RESIN;

CANADA; SELWYN MOUNTAINS; YUKON TERRITORY; NORTHWEST TERRITORIES;

CONIFEROPHYTA; PICEA;

EID: 84886410174     PISSN: 03054403     EISSN: 10959238     Source Type: Journal    
DOI: 10.1016/j.jas.2013.09.010     Document Type: Article

References (55)

1. Alix C., Hare P.G., Andrews T.D., MacKay G. Athousand years of lost hunting arrows: wood analysis of ice patch remains in northwestern Canada. Arctic 2012, 65(5):95-117.
2. Allain J., Rigaud A. Décor et function: quelques exemples tirés du Magdalénien. L'Anthropologie 1986, 90:713-738.
3. Anderson K.B., Botto R.E. The nature and fate of natural resins in the geosphere.III. Reevaluation of the structure and composition of Highgate Copalite and Glessite. Org. Geochem. 1993, 20:1027-1038.
4. Andre A., Fehr A. Gwich'in Ethnobotany, Plants Used by the Gwich'in for Food, Medicine, Shelter and Tools 2002, 17-22. Gwich'in Social and Cultural Institute, Inuvik.
5. Andrews T.D., MacKay G. The archaeology and paleoecology of alpine ice patches: a global perspective. Arctic 2012, 65(5):iii-vi.
6. Andrews T.D., MacKay G., Andrew L. Archaeological investigations of alpine ice patches in the Selwyn Mountains, Northwest Territories, Canada. Arctic 2012, 65(5):1-21.
7. Andrews T.D., MacKay G., Andrew L., Stephenson W., Barker A., Alix C., the Shúhtagot'ine Elders of Tulita Alpine ice patches and Shúhtagot'ine land use in the Mackenzie and Selwyn Mountains, Northwest Territories, Canada. Arctic 2012, 65(5):22-42.
8. Aveling E.M., Heron C. The chemistry of birch bark tar at Mesolithic Star Car. Anc. Biomol. 1998, 2(1):69-80.
9. ® Informatics System, IR/NIR Edition).
10. Boëda E., Connan J., Dessort D., Muhesan S., Mercier N., Valladas H., Tisnerat N. Bitumen as a hafting material on Middle Palaeolithic artefacts. Nature 1996, 380:336-338.
11. Callanan M. Melting snow patches reveal Neolithic archery. Antiquity 2013, 87:728-745.
12. Charrié-Duhaut A., Porraz G., Cartwright C.R., Igreja M., Connan J., Poggenpoel C., Texier P.-J. First molecular identification of a hafting adhesive in the late Howiesons Poort at Diepkloof Rock Shelter (Western Cape, South Africa). J.Archaeol. Sci. 2013, 40:3506-3518.
13. Doménech-Carbó M.T., Kuckova S., de la Cruz-Cañizares J., Osete-Cortina L. Study of the influencing effect of pigments on the photoageing of diterpenoid resins used as pictorial media. J.Chromatogr. A 2006, 1121:248-258.
14. Dove C.J., Hare G.P., Heacker M. Identification of ancient feather fragments found in melting alpine ice patches in southern Yukon. Arctic 2005, 58(1):38-43.
15. Evershed R.P., Dudd S.N., Copley M.S., Berstan R., Stott A.W., Mottram H., Buckley S.A., Crossman Z. Chemistry of archaeological animal fats. Acc. Chem. Res. 2002, 35(8):660-668.
16. Farnell R., Hare P.G., Blake E., Bowyer V., Schweger C., Greer S., Gotthardt R. Multidisciplinary investigations of alpine ice patches in southwest Yukon, Canada: paleo-environmental and paleobiological investigations. Arctic 2004, 57(3):247-259.
17. Galloway J.M., Adamczewski J., Andrews T.D., MacKay G., Meulendyk T., Schock D.M., Bowyer V., Moorman B., Kutz S. Diet and habitat of mountain woodland caribou inferred from dung preserved in 5000 year-old alpine ice in the Selwyn Mountains, Northwest Territories, Canada. Arctic 2012, 65(5):59-79.
18. Gibson N.E., Wadley L., Williamson B.S. Microscopic residues as evidence of hafting on backed tools from the 60000 to 68000 year-old Howiesons Poort layers of Rose Cottage Cave, South Africa. South. Afr. Humanit. 2004, 16:1-11.
19. Greer S.A., Strand D. Cultural landscapes, past and present, and the south Yukon ice patches. Arctic 2012, 65(5):22-42.
20. Grimaldi D., Beck C.W., Boon J.J. Occurrence, chemical characteristics, andpalaeontology of the fossil resins from New Jersey. Am. Mus. Novit. 1989, 2948:1-27.
21. Hare P.G., Greer S., Gotthardt R., Farnell R., Bowyer V., Schweger C., Strand D. Ethnographic and archaeological investigations of alpine ice patches in southwest Yukon, Canada. Arctic 2004, 57(3):260-272.
22. Hare G.P., Thomas C.D., Topper T.N., Gotthardt R.M. The archaeology of Yukon ice patches: new artifacts, observations, and insights. Arctic 2012, 65(5):118-135.
23. Helwig K. Iron oxides: natural and synthetic. Artists' Pigments: a Handbook of Their History and Characteristics 2007, 39-109. National Gallery of Art, Washington. B.H. Berrie (Ed.).
24. Helwig K., Monahan V., Poulin J. The identification of hafting adhesive on a slotted antler point from a southwest Yukon ice patch. Am. Antiq. 2008, 73(2):279-288.
25. Holmbom T., Reunanen M., Fardim P. Composition of callus resin of Norway spruce, Scots pine, European larch and Douglas fir. Holzforschung 2008, 62:417-422.
26. Honigmann J.J. The Kaska Indians: An Ethnographic Reconstruction 1964, Yale University Publications in Anthropology, 51, Human Relations Area Files Press, Toronto.
27. Hummel D.O. Atlas of Polymer and Plastics Analysis 1988, vol. 2:415-417. Carl Hanser Verlag, Munich, part b/1. second ed.
28. Karst A. Conservation Value of the North American Boreal Forest from an Ethnobotanical Perspective 2010, Canadian Boreal Initiative, David Suzuki Foundation and Boreal Songbird Initiative, Ottawa, Vancouver, Seattle.
29. Kuhn T.S., McFarlane K.A., Groves P., Mooers A.Ø., Shapiro B. Modern and ancient DNA reveal recent partial replacement of caribou in the southwest Yukon. Mol. Ecol. 2010, 19(7):1312-1323.
30. Legros D. Oral History as History: Tutchone Athapaskan in the Period 1840-1920 2007, Occasional Papers in Yukon History No. 3, Culture and Services Branch, Tourism and Culture, Yukon Government, Whitehorse.
31. Letts B., Fulton T.L., Stiller M., Andrews T.D., MacKay G., Popko R., Shapiro B. Ancient DNA reveals genetic continuity in mountain woodland caribou of the Mackenzie and Selwyn Mountains, Northwest Territories, Canada. Arctic 2012, 65(5):80-94.
32. Lombard M. The gripping nature of ochre: the association of ochre with Howiesons Poort adhesives and Later Stone Age mastics from South Africa. J.Hum. Evol. 2007, 53:406-419.
33. Mazza P.P.A., Martini F., Sala B., Magi M., Colombini M.P., Giachi G., Landucci F., Lemorini C., Mondugno F., Ribechini E. Anew palaeolithic discovery: tar-hafted stone tools in a European Mid-Pleistocene bone-bearing bed. J.Archaeol. Sci. 2006, 33(9):1310-1318.
34. McClellan C. My Old People Say: an Ethonographic Survey of Southern Yukon Territory. Parts 1 & 2 1975, Publications in Ethnology, No. 6 (1&2), National Museums of Canada, Ottawa.
35. Meagher L.P., Beecher G.R., Flanagan V.P., Li B.W. Isolation and characterization of the lignans, isolariciresinol and pinoresinol, in flaxseed meal. J.Agric. Food Chem. 1999, 47:3173-3180.
36. Meulendyk T., Moorman B.J., Andrews T.D., MacKay G. Morphology and development of ice patches in Northwest Territories, Canada. Arctic 2012, 65(5):43-58.
37. Mills J.S. Diterpenes of Larix oleoresins. Phytochemistry 1973, 12:2407-2412.
38. Mills J.S., White R. The Organic Chemistry of Museum Objects 1994, 87. Butterworth-Heinemann, Oxford. second ed.
39. Mottram H.R., Dudd S.N., Lawrence G.J., Stojanova A., Evershed R.P. New chromatographic, mass spectrometric and stable isotope approaches to the classification of degraded animal fats preserved in archeological pottery. J.Chromatogr. A 1999, 833:209-221.
40. Okunishi T., Takaku N., Wattanawikkit P., Sakakibara N., Suzuki S., Sakai F., Umezawa T., Shimada M. Lignan production in Daphne odora cell cultures. J.Wood Sci. 2002, 48:237-241.
41. Osgood C. The Ethnography of the Great Bear Lake Indians 1933, 31-97. National Museum of Canada, National Museums of Canada, Ottawa, Annual Report, 1931.
42. Pollard A.M., Heron C. Archaeological Chemistry 1996, 248. The Royal Society of Chemistry, Cambridge, England.
43. Rainville R., Gajewski K. Holocene environmental history of the Aishihik Region, Yukon, Canada. Can. J. Earth. Sci. 2013, 50:397-405.
44. Regert M. Investigating the history of prehistoric glues by gas chromatography-mass spectrometry. J.Sep. Sci. 2004, 27(3):244-254.
45. Regert M. Analytical strategies for discriminating archaeological fatty substances from animal origin. Mass Spectrom. Rev. 2011, 30(2):177-220.
46. Reimer P.J., Baillie M.G.L., Bard E., Bayliss A., Beck J.W., Blackwell P.G., Bronk Ramsey C. IntCal09 and Marine09 radiocarbon age calibration curves, 0-50,000 years cal. BP. Radiocarbon 2009, 51:1111-1150.
47. Shao L.P., Gäfvert E., Nilsson U., Karlberg A.T., Nilsson J.L. 15-hydroperoxydehydroabietic acid-a contact allergen in colophony from Pinus species. Phytochemistry 1995, 38:853-857.
48. Sheldrick C., Lowe J.J., Reynier M.J. Palaeolithic barbed point from Gransmoor, East Yorkshire, England. Proc. Prehist. Soc. 1997, 63:359-370.
49. Stacey R.J., Heron R., Sutton M.Q. The chemistry, archaeology and ethnography of a Native American insect resin. J.Calif. Gt. Basin Anthropol. 1998, 20(1):53-71.
50. Stuiver M., Reimer P.J., Reimer R. CALIB 6.0 2005, http://calib.qub.ac.uk/calib/manual.
51. Thompson J. Women's Work, Women's Art: Nineteenth-century Northern Athapaskan Clothing 2013, McGill-Queen's University Press and Canadian Museum of Civilization, Montreal and Gatineau.
52. van den Berg K.J., Boon J.J., Pastorova I., Spetter L.F.M. Mass spectrometric methodology for the analysis of highly oxidized diterpenoid acids in Old Master paintings. J.Mass Spectrom. 2000, 35:512-533.
53. Wadley L., Hodgskiss T., Grant M. Implications for complex cognition from the hafting of tools with compound adhesives in the Middle Stone Age, South Africa. Proc. Natl. Acad. Sci. 2009, 106:9590-9594.
54. Wadley L. Compound-adhesive manufacture as a behavioral proxy for complex cognition in the Middle Stone Age. Curr. Anthropol. 2010, 51:111-119.
55. Yeo H., Chin Y.-W., Park S.-Y., Kim J. Lignans of Rosa multiflora roots. Arch. Pharm. Res. 2004, 27(3):287-290.