Addition-Type Polynorbornene with Si(CH3)3 Side Groups: Detailed Study of Gas Permeation, Free Volume and Thermodynamic Properties

Membrane Gas Separation

Volumn , Issue , 2010, Pages 43-57

  Yampolskii, Yuri ^a   Starannikova, Ludmila ^a   Belov, Nikolai ^a   Gringolts, Maria ^a   Finkelshtein, Eugene ^a   Shantarovich, Victor ^b  

^a TOPCHIEV INSTITUTE OF PETROCHEMICAL SYNTHESIS   (Russian Federation)

^b SEMENOV INSTITUTE OF CHEMICAL PHYSICS   (Russian Federation)

Author keywords

Addition type polynorbornene with Si(CH3)3 side groups gas permeation, free volume and thermodynamic properties; Gas permeability PTMSN feature, relatively high gas permeability coefficient P; Monomer from dicyclopentadiene and vinyltrimethylsilane by Diels Alder reaction; PALS values, larger size of microcavities; Parameters of Arrhenius dependence of permeability in PTMSN; PTMSN investigation using positron annihilation lifetime spectroscopy (PALS) and inverse gas chromatography (IGC); PTMSN, member of a family of high permeability; Ring opening metathesis polymerization (ROMP); Sorption thermodynamics using IGC method for solutes; Temperature dependence of PALS parameters in PTMSN

Indexed keywords

EID: 84886128931     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1002/9780470665626.ch3     Document Type: Chapter

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