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Volumn , Issue , 2010, Pages 507-519

Rechargeable Batteries Using Robust but Redox Active Organic Radicals

Author keywords

"organic radical battery"; "rocking chair"; Electric double layer capacitor (EDLC); Electronic double layer capacitor (EDLC); Mechanism and performance of an organic radical battery; Molecular design and synthesis of redox active radical polymers; Ring opening metathesis polymerization (ROMP); Scanning electron microscopy (SEM)

Indexed keywords


EID: 84886107136     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1002/9780470666975.ch14     Document Type: Chapter
Times cited : (29)

References (71)
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    • Murata, H.1    Nishide, H.2
  • 8
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  • 24
    • 84886133693 scopus 로고    scopus 로고
    • Most nitroxides such as TEMPO show an irreversible n-type redox reaction, especially in protic media, the reduction of nitroxide radical forms the corresponding hydroxylamine (N-OH)
    • But some nitroxides with an electron withdrawing group, and nitronylnitroxide can achieve reversible n-type redox reaction as discussed in Section 14.5
    • Most nitroxides such as TEMPO show an irreversible n-type redox reaction, especially in protic media, the reduction of nitroxide radical forms the corresponding hydroxylamine (N-OH). But some nitroxides with an electron withdrawing group, and nitronylnitroxide can achieve reversible n-type redox reaction as discussed in Section 14.5.
  • 29
    • 84886150616 scopus 로고    scopus 로고
    • For instance, a two-electron redox reaction of disulfide compounds (2RS- ? RS - SR + 2e-) is coupled with bond formation or cleavage, which restricts the rapid electron transfer and stability of the redox couples
    • For instance, a two-electron redox reaction of disulfide compounds (2RS- ? RS - SR + 2e-) is coupled with bond formation or cleavage, which restricts the rapid electron transfer and stability of the redox couples.
  • 33
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    • A dissolved radical serves as a redox mediator or shuttle, which carries the charge between the two electrodes
    • leading to the self-discharge of the battery: C. Buhrmester, L. M. Moshurchak, R. L. Wang, and J. R. Dahn, J. Electrochem. Soc
    • A dissolved radical serves as a redox mediator or shuttle, which carries the charge between the two electrodes, leading to the self-discharge of the battery: C. Buhrmester, L. M. Moshurchak, R. L. Wang, and J. R. Dahn, J. Electrochem. Soc. 153, A1800 (2006).
    • (2006) , vol.153
  • 34
    • 84886182691 scopus 로고    scopus 로고
    • The small charge storage capacity and the fluctuating voltage of the p-conjugated conducting polymers originate from the low doping levels and the potential shift via doping process
    • The small charge storage capacity and the fluctuating voltage of the p-conjugated conducting polymers originate from the low doping levels and the potential shift via doping process:
  • 37
    • 84886158158 scopus 로고    scopus 로고
    • Theoretical redox capacity (Q) was calculated from the formular weight (Fw) of the monomer repeating unit, and the number of radicals in the repeating unit (a), using the following equation: Q = 96485 × a/(Fw × 3600) (mAh/g)
    • Theoretical redox capacity (Q) was calculated from the formular weight (Fw) of the monomer repeating unit, and the number of radicals in the repeating unit (a), using the following equation: Q = 96485 × a/(Fw × 3600) (mAh/g).
  • 52
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    • Previously, Tanyeli, et al. reported the polymerization of norbornene monomer bearing the reduced N -hydroxypiperidine group. C. Tanyeli, and A. Gusmus
    • Previously, Tanyeli, et al. reported the polymerization of norbornene monomer bearing the reduced N -hydroxypiperidine group. C. Tanyeli, and A. Gusmus, Tetrahedron Lett ., 44, 1639-1642 (2003).
    • (2003) Tetrahedron Lett. , vol.44 , pp. 1639-1642
  • 66
    • 84886132626 scopus 로고    scopus 로고
    • Even for n-dopable polythiophene, the small charge storage capacity and the fluctuating voltage have impeded their use in a rechargeable battery, where a constant output voltage is required
    • Even for n-dopable polythiophene, the small charge storage capacity and the fluctuating voltage have impeded their use in a rechargeable battery, where a constant output voltage is required.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.