H2 production by selective decomposition of hydrous hydrazine over Raney Ni catalyst under ambient conditions

AIChE Journal

Volumn 59, Issue 11, 2013, Pages 4297-4302

  He, Lei ^a,b   Huang, Yanqiang ^a   Wang, Aiqin ^a   Wang, Xiaodong ^a   Zhang, Tao ^a  

^a DALIAN INSTITUTE OF CHEMICAL PHYSICS   (China)

^b UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

Author keywords

Alkali promotion; Hydrogen generation; Hydrous hydrazine decomposition; Raney Ni

Indexed keywords

ALKALI PROMOTION; AMBIENT CONDITIONS; HYDROGEN GENERATIONS; HYDROGEN STORAGE MATERIALS; HYDROUS HYDRAZINES; METAL-FREE CATALYSTS; RANEY NI; SELECTIVE DECOMPOSITION;

HYDRAZINE; HYDROGEN PRODUCTION; HYDROGEN STORAGE; INDUSTRIAL APPLICATIONS; NICKEL;

CATALYST SELECTIVITY;

EID: 84885846038     PISSN: 00011541     EISSN: 15475905     Source Type: Journal    
DOI: 10.1002/aic.14151     Document Type: Article

References (31)

1. Schlapbach L, Züttel A. Hydrogen-storage materials for mobile applications. Nature. 2001;414:353-358.
2. Eberle U, Felderhoff M, Schüth F. Chemical and physical solutions for hydrogen storage. Angew. Chem Int Ed. 2009;48:6608-6630.
3. Yang J, Sudik A, Wolverton C, Siegel DJ. High capacity hydrogen storage materials: attributes for automotive applications and techniques for materials discovery. Chem Soc Rev. 2010;39:656-675.
4. Demirci UB, Miele P. Chemical hydrogen storage: 'material' gravimetric capacity versus 'system' gravimetric capacity. Energy Environ. Sci. 2011;4:3334-3341.
5. Jiang HL, Singh SK, Yan JM, Zhang XB, Xu Q. Liquid-phase chemical hydrogen storage: catalytic hydrogen generation under ambient conditions. ChemSusChem. 2010;3:541-549.
6. 2 production via catalytic decomposition of hydrazine. Int J Hydrogen Energy. 2005;30:1081-1089.
7. 3 catalysts in oxygen and steam. Influence of chloride content. Appl Catal A. 1999;182:317-325.
8. Zhang P, Wang Y, Huang Y, Zhang T, Wu G, Li J. Density functional theory investigations on the catalytic mechanisms of hydrazine decompositions on Ir(111). Catal Today. 2011;165:80-88.
9. Singh SK, Xu Q. Complete conversion of hydrous hydrazine to hydrogen at room temperature for chemical hydrogen storage. J Am Chem Soc. 2009;131:18032-18033.
10. Singh SK, Xu Q. Bimetallic nickel-iridium nanocatalysts for hydrogen generation by decomposition of hydrous hydrazine. Chem Commun. 2010;46:6545-6547.
11. Singh SK, Xu Q. Bimetallic Ni-Pt nanocatalysts for selective decomposition of hydrazine in aqueous solution to hydrogen at room temperature for chemical hydrogen storage. Inorg Chem. 2010;49:6148-6152.
12. Singh SK, Lu ZH, Xu Q. Temperature-induced enhancement of catalytic performance in selective hydrogen generation from hydrous hydrazine with Ni-based nanocatalysts for chemical hydrogen storage. Eur J Inorg Chem. 2011;14:2232-2237.
13. Wang J, Zhang X, Wang Z, Wang L, Zhang Y. Rhodium-nickel nanoparticles grown on graphene as highly efficient catalyst for complete decomposition of hydrous hydrazine at room temperature for chemical hydrogen storage. Energy Environ Sci. 2012;5:6885-6888.
14. 2 generation via selective decomposition of hydrous hydrazine. J Catal. 2013;298:1-9.
15. Singh SK, Singh AK, Aranishi K, Xu Q. Noble-metal-free bimetallic nanoparticle-catalyzed selective hydrogen generation from hydrous hydrazine for chemical hydrogen storage. J Am Chem Soc. 2011;133:19638-19641.
16. Song J, Ran R, Shao Z. Hydrazine as efficient fuel for low-temperature SOFC through ex-situ catalytic decomposition with high selectivity toward hydrogen. Int. J. Hydrogen Energy. 2010;35:7919-7924.
17. Zhao B, Song J, Ran R, Shao Z. Catalytic decomposition of hydrous hydrazine to hydrogen over oxide catalysts at ambient conditions for PEMFCs. Int J Hydrogen Energy. 2012;37:1133-1139.
18. Tong DG, Chu W, Wu P, Gu GF, Zhang L. Mesoporous multiwalled carbon nanotubes as supports for monodispersed iron-boron catalysts: improved hydrogen generation from hydrous hydrazine decomposition. J Mater Chem A. 2013;1:358.
19. 2O decomposition. Angew Chem Int Ed. 2012;51:6191-6194.
20. 2 production from biomass-derived hydrocarbons. Science. 2003;300:2075-2077.
21. Zhang C, Zhang P, Li S, Wu G, Ma X, Gong J. Superior reactivity of skeletal Ni-based catalysts for low-temperature steam reforming to produce CO-free hydrogen. Phys Chem Chem Phys. 2012;14:3295-3298.
22. Yin A-Y, Guo X-Y, Dai W-L, Fan K-N. The synthesis of propylene glycol and ethylene glycol from glycerol using Raney Ni as a versatile catalyst. Green Chem. 2009;11:1514-1516.
23. Liu B, Qiao M, Deng J, K. Fan, Zhang X, Zong B. Skeletal Ni catalyst prepared from a rapidly quenched Ni-Al alloy and its high selectivity in 2-ethylanthraquinone hydrogenation. J Catal. 2001;204:512-515.
24. Lu L, Rong Z, Du W, Ma S, Hu S. Selective hydrogenation of single benzene ring in biphenyl catalyzed by skeletal Ni. ChemCatChem 2009;1:369-371.
25. Zong B, Zhang X, Qiao M. Integration of methanation into the hydrogenation process of benzoic acid. AIChE J. 2009;55:192-197.
26. 50 alloy. J Catal. 2004;221:612-618.
27. Barnard NC, Brown SGR, Devred F, Bakker JW, Nieuwenhuys BE, Adkins NJ. A quantitative investigation of the structure of Raney-Ni catalyst material using both computer simulation and experimental measurements. J Catal. 2011;281:300-308.
28. Zhu LJ, Guo PJ, Chu XW, Yan SR, Qiao MH, Fan KN, Zhang XX, Zong BN. An environmentally benign and catalytically efficient non-pyrophoric Ni catalyst for aqueous-phase reforming of ethylene glycol. Green Chem. 2008;10:1323-1330.
29. Freel J, Robertson SD, Anderson RB, The structure of Raney nickel: III. The chemisorption of hydrogen and carbon monoxide. J Catal. 1970;18:243-248.
30. Rosca V, Duca M, Groot MT, Koper MTM. Nitrogen Cycle Electrocatalysis. Chem Rev. 2009;109:2209-2244.
31. Alberas DJ, Kiss J, Liu ZM, White JM. Surface chemistry of hydrazine on Pt(111). Surf Sci. 1992;278:51-61.