SO2 - An indirect source of energy

Journal of the Southern African Institute of Mining and Metallurgy

Volumn 113, Issue 8, 2013, Pages 593-604

  Kriek, R J ^a   Van Ravenswaay, J P ^a   Potgieter, M ^a   Calitz, A ^a   Lates, V ^a   Bjorketun M E ^b   Siahrostami, S ^b   Rossmeisl, J ^b  

^a NORTH WEST UNIVERSITY   (South Africa)

^b TECHNICAL UNIVERSITY OF DENMARK   (Denmark)

Author keywords

Electro oxidation; Electrocatalyst; Electrolyser; Sulphur dioxide

Indexed keywords

ANODE ELECTROCATALYST; ELECTRO-CATALYTIC OXIDATION; ELECTROLYSERS; ENERGY PRODUCTIONS; GASEOUS POLLUTANTS; HYBRID SULFUR CYCLES; PRODUCTION OF HYDROGEN; RESEARCH AND DEVELOPMENT;

CATALYTIC OXIDATION; ELECTROCATALYSTS; ELECTROOXIDATION; FOG; SULFUR DETERMINATION;

SULFUR DIOXIDE;

EID: 84885401926     PISSN: 22256253     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (49)

1. APPLEBY, A.J. and PINCHON, B. 1979. The mechanism of the electrochemical oxidation of sulfur dioxide in sulfuric acid solutions. Journal of Electroanalytical Chemistry, vol. 95. pp. 59-71.
2. APPLEBY, A.J. and PINCHON, B. 1980. Electrochemical aspects of the H2SO4 SO2 thermoelectrochemical cycle for hydrogen production. International Journal of Hydrogen Energy, vol. 5. pp. 253-267. (Pubitemid 10488794)
3. AUDREY, C. and VOINOV, M. 1980. Inhibitions of the SO2 electrochemical oxidation reactions on platinum in sulfuric acid solutions. Electro chimica Acta, vol. 25. pp. 299-301. (Pubitemid 10477244)
4. BEZUIDENHOUT, G.A., DAVIS, J., VAN BEEK, B., and EKSTEEN, J.J. 2012. Operation of a concentrated mode dual-alkali scrubber plant at the Lonmin smelter. Journal of the Southern African Institute of Mining and Metallurgy, vol. 112. pp. 657-665.
5. BRECHER, L.E. and WU, C.K. 1975. Electrolytic decomposition of water, Westinghouse Electric Corporation. US Patent No. 3888750.
6. BUNCE, N. 1994. Environmental Chemistry. 2nd edn. Wuerz Publishing. p. 376.
7. CALVERT, J.G. and STOCKWELL, W.R. 1984. Mechanisms and rates of gas-phase oxidations of sulfur dioxide and nitrogen oxides in the atmosphere. SO2, NO and NOx Oxidation Mechanisms: Atmospheric Considerations. Calvert, J.G. (ed.). Butterworths. pp. 1-62.
8. COLON-MERCADO, H.R. and HOBBS, D.T. 2007. Catalyst evaluation for a sulfur dioxide-depolarized electrolyzer. Electrochemistry Communications, vol. 9. pp. 2649-2653. (Pubitemid 350001269)
9. COMTAT, M. and MAHENC, J. 1969. Electrochemical Oxidation of Sulfur Dioxide on a Platinum Electrode. Bulletin de la Société Chimique de France, vol. 11. p. 3862.
10. European Commission, Joint Research Centre (JRC)/Netherlands Environmental Assessment Agency (PBL). 2010. Emission Database for Global Atmospheric Research (EDGAR). Release version 4.1. http://edgar.jrc.ec.europa. eu.
11. FANG, Y., ZENG, Y., and LI, S. 2008. Technological influences and abatement strategies for industrial sulphur dioxide in China. International Journal of Sustainable Development & World Ecology, vol. 15, no. 2. pp. 122-131. (Pubitemid 351656059)
12. FRIEND, J.P. 1973. The global sulfur cycle. Chemistry of the Lower Troposphere. Rasool, S.I. (ed.). Plenum Press, New York, NY. pp. 177-201.
13. GORENSEK, M.B., SUMMERS, W.A., BOLTHRUNIS, C.O., LAHODA, E.J., ALLEN, D.T., and GREYVENSTEIN, R. 2009 Hybrid Sulfur Process Reference Design and Cost Analysis - Final Report, SRNL-L1200-2008-00002. Rev 1, 12 June.
14. JEONG, Y.H. and KAZIMI, M.S. 2007. Optimization of the Hybrid Sulfur Cycle for nuclear hydrogen generation. Nuclear Technololgy, vol. 159. pp. 147-157. (Pubitemid 47316431)
15. KORZENIEWSKI, C., MCKENNA, W., and PONS, S. 1987. An in situ infrared study of the oxidation of sulfur dioxide on platinum electrodes. Journal of Electroanalytical Chemistry and Interfactial Electrochemistry, vol. 235. pp. 361-368.
16. KRUGER, B. 2004. Recovery of SO2 from low strength off-gases. International Platinum Conference 'Platinum Adding Value'. Southern African Institute of Mining and Metallurgy, Johannesburg. pp. 59-62.
17. LEE, J. and LANGER, S.H. 1995. Electrochemical sulphur dioxide oxidation with platinum-aluminum electrocatalysts. Journal of Applied Electrochemistry, vol. 25. pp. 353-357.
18. LOUCKA, T. 1971. Adsorption and oxidation of sulphur and of sulphur dioxide at the platinum electrode. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, vol. 31. pp. 319-332.
19. LOUCKA, T. 1972. Adsorption and oxidation of organic compounds on a platinum electrode partly covered by adsorbed sulphur. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, vol. 36. pp. 355-367.
20. LU, P.W.T. and AMMON, R.L. 1980. An investigation of electrode materials for the anodic oxidation of sulfur dioxide in concentrated sulfuric acid. Journal of the Electrochemical Society, vol. 127. pp. 2610-2616. (Pubitemid 11477232)
21. LU, P.W.T., GARCIA, E.R., and AMMON, R.L. 1981. Recent developments in the technology of sulfur dioxide depolarised electrolysis. Journal of Applied Electrochemistry, vol. 11. pp. 347-355. (Pubitemid 11515470)
22. LU, P.W.T. and AMMON, R.L. 1982. Sulfur dioxide depolarized electrolysis for hydrogen production: development status. International Journal of Hydrogen Energy, vol. 7, no. 7. pp. 563-575. (Pubitemid 12551684)
23. MATVEEVA, E.S. and KASATKIN, E.V. 1984. Adsorption of sulfur dioxide on the platinum electrode and influence on its electrooxidation in concentrated solutions. Soviet Electrochemistry, vol. 19, pp. 801-805. (Pubitemid 14526035)
24. NOYES, A.A. and STEINOUR, H.H.1929. The potential of inert electrodes in solutions of sulfurous acid and its behavior as an oxidizing and reducing agent. Journal of the American Chemical Society, vol. 51. pp. 1409-1428.
25. O'BRIEN, J.A., HINKLEY, J.T., DONNE, S.W., and LINDQUIST, S-E. 2010. The electrochemical oxidation of aqueous sulfur dioxide: A critical review of work with respect to the hybrid sulfur cycle. Electro chimica Acta, vol. 55. pp. 573-591.
26. WORLD BANK. 1999. Pollution Prevention and Abatement Handbook. Geneva.
27. QUIJADA, C., RODES, A., VAZQUEZ, J.L., PEREZ, J.M., and ALDAZ, A. 1995. Electrochemical behaviour of aqueous SO2 at Pt electrodes in acidic medium. A voltammetric and in situ Fourier transform IR study Part I. Oxidation of SO2 at Pt electrodes with sulphur-oxygen adsorbed species. Journal of Electroanalytical Chemistry, vol. 394. pp. 217-227.
28. QUIJADA, C., MORALLON, E., VAZQUEZ, J.L., and BERLOUIS, L.E.A. 2000. Electrochemical behaviour of aqueous SO2 at polycrystalline gold electrodes in acidic media. A voltammetric and in-situ vibrational study. Part II. Oxidation of SO2 on bare and sulphur-modified electrodes. Electrochimica Acta, vol. 46. pp. 651-659.
29. QUIJADA, C. and VAZQUEZ, J.L. 2000. Recent Research Developments in Electrochemistry, Pandalai S.G., vol. 3. p. 137.
30. SAMEC, Z. and WEBER, J. 1972. Reduction of ferric ion on a rotating platinum electrode of the turbulent type in the presence and absence of adsorbed sulphur. Journal of Electroanalytical Chemistry, vol. 38. pp. 115-126.
31. SAMEC, Z. and WEBER, J. 1973. The influence of chemisorbed sulphur on the kinetic parameters of the reduction of Fe3+ ions on a platinum electrode on the basis of the marcus theory of electron transfer. Journal of Electroanalytical Chemistry, vol. 44. pp. 229-238.
32. SAMEC, Z. and WEBER, J. 1975a. Study of the oxidation of SO2 dissolved in 0.5 M H2SO4 on a gold electrode - II rotating disc electrode. Electrochimica Acta, vol. 20. pp. 413-419.
33. SAMEC, Z. and WEBER, J. 1975b. Study of the oxidation of SO2 dissolved in 0.5 M H2SO4 on a gold electrode - I stationary electrode. Electrochimica Acta, vol. 20. pp. 403-412.
34. SEO, E.T. and SAWYER, D.T. 1965. Electrochemical oxidation of dissolved sulphur dioxide at platinum and gold electrodes. Electrochimica Acta, vol. 10. pp. 239-252.
35. SIVASUBRAMANIAN, P., RAMASAMY, R.P., FREIRE, F.J., HOLLAND, C.E., and WEIDNER, J.W. 2007. Electrochemical hydrogen production from thermochemical cycles using a proton exchange membrane electrolyzer. International Journal of Hydrogen Energy, vol. 32. pp. 463-468. (Pubitemid 46330614)
36. SMITH, S.J., VAN AARDENNE, J., KLIMONT, Z., ANDRES, R.J., VOLKE, A. and DELGADO ARIAS, S. 2011. Anthropogenic sulfur doxide emissions: 1850-2005. Atmospheric Chemistry and Physics, vol. 11. pp. 1101-1116.
37. SPOTNITZ, R.M., COLUCCI, J.A., and LANGER, S.H. 1983. The activated electrooxidation of sulfur dioxide on smooth platinum. Electrochimica Acta, vol. 28, no. 8. pp. 1053-102.
38. SAVANNAH RIVER NATIONAL LABORATORY (SRNL). 2007. SRNL achieves milestone en route to hydrogen economy. Jackson, SC.
39. SRIVASTAVA, R.K., JOZEWICZ, W, and SINGER, C. 2001. SO2 Scrubbing Technologies: A Review. Environmental Progress, vol. 20, no. 4. pp. 219-228.
40. SU, S., LI, B., CUI, S., and TAO, S. 2011. Sulfur Dioxide Emissions from Combustion in China: From 1990 tp 2007. Environmental Science and Technology, vol. 45. pp. 8403-8410.
41. SUMMERS, W.A. and GORENSEK, M.B. 2006. Nuclear hydrogen production based on the Hybrid Sulfur Thermochemical Process. Proceedings of ICAPP '06, Reno, Nevada, 4-8 June. Paper 6107.
42. VALENSI, G., VAN MUYLDER, J., and POURBAIX, M. 1966. Atlas of Electrochemical Equilibria in Aqueous Solutions. Pourbai, M. (ed.). Vol II. Pergamon Press, Oxford. p. 545.
43. VALENSI, G. 1973. Technical Report RT 207 for Centre Belge d'Etude de la Corrosion. p. 121.
44. VOEGELE, A.F., LOERTING, T., TAUTERMANN, C.S., HALLBRUCKER, A., MAYER, E., and LIEDL, K.R. 2004. Sulfurous acid (H2SO3) on Io? Icarus, vol. 169. pp. 242-249.
45. WBK & ASSOCIATES INC. 2003 Sulphur Dioxide: Environmental Effects, Fate and Behaviour. Alberta Environment, Government of Alberta, Edmonton, AB.
46. WESTCOTT, G., TACKE, M., SCHOEMAN, N., and MORGAN, N. 2007. Impala Platinum Smelter, Rusternburg - An integrated smelter off-gas treatment solution. Journal of the Southern African Institute of Mining and Metallurgy, vol. 107. pp. 281-287.
47. WIESENER, K. 1973. The electrochemical oxidation of sulphur dioxide at porous catalysed carbon electrodes in sulphuric acid. Electrochimica Acta, vol. 18. pp. 185-189.
48. WILKE, T., GAO, X., TAKOUDIS, C.G., and WEAVER, M.J. 1991. Surface-enhanced Raman spectroscopy at transition metal-gas interfaces: Adsorption and reactions of sulfur dioxide on platinum-, rhodium-, and ruthenium-coated gold. Journal of Catalysis, vol. 130. pp. 62-75.
49. ZHDANOV, S.I. 1975. Encyclopedia of the Electrochemistry of the Elements. Bard, A.J. (ed.). Marcel Dekker, New York. p. 273.