Effect of Mn on the electrochemical properties of a layered perovskite NdBa0.5Sr0.5Co2 - XMnxO 5 + δ (x = 0, 0.25, and 0.5) for intermediate-temperature solid oxide fuel cells

Electrochimica Acta

Volumn 112, Issue , 2013, Pages 712-718

  Kim, Jiyoun ^a,b   Choi, Sihyuk ^a   Park, Seonhye ^a   Kim, Changmin ^a   Shin, Jeeyoung ^c   Kim, Guntae ^a  

^a Ulsan National Institute of Science and Technology   (South Korea)

^b BT Convergence Technology Research Department   (South Korea)

^c Dong Eui University   (South Korea)

Author keywords

Cathode; Electrochemical performance; Layered perovskite; Solid oxide fuel cell; Thermal expansion coefficient

Indexed keywords

CONDUCTING PROPERTIES; ELECTROCHEMICAL PERFORMANCE; INTERMEDIATE TEMPERATURE SOLID OXIDE FUEL CELL; LAYERED PEROVSKITE; MECHANICAL COMPATIBILITY; SPIN STATE TRANSITION; THERMAL EXPANSION COEFFICIENTS; TRADE-OFF RELATIONSHIP;

CATHODES; PEROVSKITE; SOLID OXIDE FUEL CELLS (SOFC); THERMAL EXPANSION;

MANGANESE;

EID: 84885339822     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2013.09.014     Document Type: Article

References (37)

1. Z. Shao, and S.M. Haile A high-performance cathode for the next generation of solid-oxide fuel cells Nature 431 2004 170
2. T.P. Tsai, E. Perry, and S. Barnett Low-temperature solid-oxide fuel cells utilizing thin bilayer electrolytes Journal of the Electrochemical Society 144 1997 L130
3. 5 + δ at various oxidation and reduction states Journal of Materials Chemistry 21 2011 439
4. 5 + δ Materials Research Bulletin 45 2010 1288
5. 5 + δ as materials of oxygen permeation membranes and cathodes of SOFCs Acta Materialia 56 2008 4876
6. 5 + x with perovskite-related structure and ordered A cations Journal of Material Chemistry 17 2007 2500
7. 5 + δ (x = 0, 0.5, 1) infiltrated into yttria stabilized zirconia scaffold as cathodes for solid oxide fuel cells Journal of Power Sources 201 2012 10
8. A.A. Taskin, A.N. Lavrov, and Y. Ando Achieving fast oxygen diffusion in perovskites by cation ordering Applied Physics Letters 86 2005 091910
9. 5 + δ (0 ≤ x ≤ 1.0) double perovskites as cathodes for solid oxide fuel cells Journal of the Electrochemical Society 155 2008 B1023
10. 5 + δ as a cathode material for IT-SOFCs Electrochemistry Letters 1 2012 F29 F32
11. 5 + δ (x = 0, 0.25, 0.5, 0.75, and 1.0) cathodes for intermediate-temperature solid oxide fuel cells Electrochimica Acta 100 2013 44
12. 5 + δ layered perovskite cathode for intermediate temperature solid oxide fuel cells Electrochimica Acta 55 2010 3812
13. 5 + δ perovskite cathodes for intermediate-temperature solid oxide fuel cells International Journal of Hydrogen Energy 37 2012 18381
14. 5.5 Physics of the Solid State 52 2010 1688
15. 5 + δ (0 ≤ x ≤ 1.0) perovskite cathodes for intermediate-temperature solid oxide fuel cells Journal of the Electrochemical Society 158 2011 B276
16. 5 + δ Scientific Reports 3 2013 2426
17. 5 + δ (0 ≤ x ≤ 1) at high temperature Physica B 403 2008 3406
18. 5 + δ perovskite oxides as cathodes for intermediate temperature solid oxide fuel cells Electrochimica Acta 54 2009 7551
19. 5 + δ (Ln = Nd, Eu) Journal of Material Science 46 2011 681 687
20. 3 ± δ: an EXAFS study Journal of Physics Condensed Matter 21 2009 235405
21. J.A. Dean Lange's Handbook of Chemistry 12th ed. 1979 McGraw-Hill New York, NY 9:4 9:94
22. 3 - δ (M = Ti, Cr, Mn, Fe, Co and Cu) cathodes Solid State Ionics 178 2007 995
23. 5 + δ as a potential cathode for intermediate-temperature solid oxide fuel cells Journal of Power Sources 195 2010 453
24. 4 + δ mixed conducting oxides Solid State Sciences 5 2003 973
25. 4-type oxides as cathode materials for IT-SOFCs (A = Pr, Sm; A′ = Sr; B = Fe, Co) Materials Letters 60 2006 1174
26. S. Adler, J.A. Lane, and B.C.H. Steele Electrode kinetics of porous mixed-conducting oxygen electrodes Journal of the Electrochemical Society 143 1996 3554
27. 3 (Ln = Gd, Pr) as a cathode for intermediate-temperature solid oxide fuel cells Solid State Ionics 175 2004 59
28. S.B. Adler, X.Y. Chen, and J.R. Wilson Mechanisms and rate laws for oxygen exchange on mixed-conducting oxide surfaces Journal of Catalysis 245 2006 91
29. 3 - δ electrolyte for intermediate temperature solid oxide fuel cells Journal of Power Sources 232 2013 332
30. C.J. Fu, K. Sun, N.Q. Zhang, X.B. Chen, and D.R. Zhou Electrochemical characteristics of LSCF-SDC composite cathode for intermediate temperature SOFC Electrochimica Acta 52 2007 4589
31. 2 - δ functional graded composite cathode for intermediate temperature solid oxide fuel cells International Journal of Hydrogen Energy 35 2010 1742
32. J.D. Kim, G.D. Kim, J.W. Moon, Y. Park, W.H. Lee, K. Kobayashi, M. Nagai, and C.E. Kim Characterization of LSM-YSZ composite electrode by ac impedance spectroscopy Solid State Ionics 143 2001 379
33. 1.95 for intermediate-temperature solid oxide fuel cells Electrochimica Acta 81 2012 217
34. 3 perovskite oxide Solid State Ionics 135 2000 631
35. 3 - δ (0 ≤ y ≤ 1.0) cathodes for intermediate-temperature solid oxide fuel cells Journal of Power Sources 158 2006 1202
36. 3 - δ (0 ≤ y ≤ 0.5) cathode materials for intermediate-temperature solid oxide fuel cells Solid State Ionics 176 2005 1521 1527 (Pubitemid 40833830)
37. 2 - δ based composite membranes Solid State Ionics 160 2003 247