Incorporation of Al in iron oxyhydroxides: Implications for the structure of ferrihydrite

Clay Minerals

Volumn 48, Issue 3, 2013, Pages 481-489

  Manceau, A ^a   Gates, W P ^b  

^a CNRS   (France)

^b MONASH UNIVERSITY   (Australia)

Author keywords

Ferrihydrite; HEXS; Linus Pauling; PDF; Structure

Indexed keywords

ACIDIC AQUEOUS SOLUTION; ENVIRONMENTAL GEOCHEMISTRY; FERRIHYDRITES; HEXS; IRON OXYHYDROXIDES; LINUS PAULING; PDF; SATURATION LIMITS;

SOLUBILITY; STRUCTURE (COMPOSITION);

ALUMINUM;

ALUMINUM; AQUEOUS SOLUTION; FERRIHYDRITE; GEOCHEMISTRY; IRON HYDROXIDE; OBSERVATIONAL METHOD; PREDICTION;

EID: 84885151798     PISSN: 00098558     EISSN: 14718030     Source Type: Journal    
DOI: 10.1180/claymin.2013.048.3.05     Document Type: Review

References (58)

1. Baes C.F.Jr & Mesmer R.E. (1976) The Hydrolysis of Cations. Wiley, New York.
2. Berquo T.S., Banerjee S.K., Ford R.G., Penn R.L. & Pichler T. (2007) High crystallinity Si-ferrihydrite: An insight into its Néel temperature and size dependence of magnetic properties. Journal of Geophysical Research: Solid Earth, 112.B2, 02102.
3. Billinge S.J.L. & Kanatzidis M.G. (2004) Beyond crystallography: The study of disorder, nanocrystallinity and crystallographically challenged materials with pair distribution functions. Chemical Communications, 7, 749-760. (Pubitemid 38530223)
4. Billinge S.J.L., McKimmy E.J., Shatnawi M., Kim H.J., Petkov V., Wermeille D. & Pinnavaia T.J. (2005) Mercury binding sites in thiol-functionalized mesostructured silica. Journal of the American Chemical Society, 127, 8492-8498. (Pubitemid 40828166)
5. Bottero J.Y., Manceau A., Villieras F. & Tchoubar D. (1994) Structure and mechanisms of formation of FeOOH(Cl) polymers. Langmuir, 10, 316-319.
6. Bradley S.M. & Kydd R.A. (1993) Comparison of the species formed upon base hydrolyzes of gallium(III) and iron(III) aqueous solutions: The possibility of existence of an [FeO4Fe12(OH)24(H2O)12]7+ polyoxocation. Journal of the Chemical Society, Dalton Transactions, 15, 2407-2413.
7. Casey W.H., Rustad J.R. & Spiccia L. (2009) Minerals as molecules - Use of aqueous oxide and hydroxide clusters to understand geochemical reaction. Chemistry: A European Journal, 15, 4496-4515.
8. Cismasu A.C., Michel F.M., Stebbins J.F., Levard C. & Brown G.E.Jr (2012) Properties of impurity-bearing ferrihydrite I. Effects of Al content and precipitation rate on the structure of 2-line ferrihydrite. Geochimica et Cosmochimica Acta, 92, 275-291.
9. Combes J.M., Manceau A., Calas G. & Bottero J.Y. (1989) Formation of ferric oxides from aqueous solutions: A polyhedral approach by X-ray absorption spectroscopy: 1. Hydrolysis and formation of ferric gels. Geochimica et Cosmochimica Acta, 53, 583-594.
10. Drits V.A. & Tchoubar C. (1990) X-ray diffraction by disordered lamellar structures: Theory and applications to microdivided silicates and carbons. 371 pp. Springer Verlag, Berlin.
11. Drits V.A., Sakharov B.A., Salyn A.L. & Manceau A. (1993) Structural model for ferrihydrite. Clay Minerals, 28, 185-208.
12. Fernandez-Martinez A., Timon V., Roman-Ross G., Cuello G.J., Daniels J.E. & Ayora C. (2010) The structure of schwertmannite, as nanocrystalline iron oxyhydroxidesulfate. American Mineralogist, 95, 1312-1322.
13. Fischer H.E., Barnes A.C. & Salmon P.S. (2006) Neutron and x-ray diffraction studies of liquids and glasses. Reports on Progress in Physics, 69, 233-299. (Pubitemid 41742248)
14. Gates W.P., Slade P.G., Manceau A. & Lanson B. (2002) Site occupancies by iron in nontronites. Clays and Clay Minerals, 50, 223-239.
15. Gualtieri A.F. & Venturelli P. (1999) In situ study of the goethite-hematite phase transformation by real time synchrotron powder diffraction. American Mineralogist, 84, 895-904. (Pubitemid 29497013)
16. Güven N. (1988) Smectites. Pp. 497-559 in: Hydrous Phyllosilicates (Exclusive of Micas), (S.W. Bailey, editor). Reviews in Mineralogy, 19. Mineralogical Society of America.
17. Harrington R., Hasuner D.B., Xu W., Bhandari N., Michel F.M. Brown G.E.Jr, Strongin D.R. & Parise J.B. (2011) Neutron pair distribution function study of two-line ferrihydrite. Environmental Science and Technology, 45, 9883-9890.
18. Henry M., Jolivet J.P. & Livage J. (1992) Aqueous chemistry of metal-cations-hydrolysis, condensation and complexation. Structure and Bonding, 77, 153-206.
19. Hiemstra T. & Van Riemsdijk W.H. (2009) A surface structural model for ferrihydrite I: Sites related to primary charge, molar mass, and mass density. Geochimica et Cosmochimica Acta, 73, 4423-4436.
20. Hocking R.K, Gates W.P. & Cashion J.D. (2012) Comments on the 'Direct observation of tetrahedrally coordinated Fe(III) in ferrihydrite'. Environmental Science and Technology, 46, 11471-11472.
21. Janney D.E., Cowley J.M. & Buseck P.R. (2000) Structure of synthetic 2-line ferrihydrite by electron nanodiffraction. American Mineralogist, 85, 1180-1187.
22. Janney D.E., Cowley J.M. & Busech P.R. (2001) Structure of synthetic 6-line ferrihydrite by electron nanodiffraction. American Mineralogist, 86, 327-335. (Pubitemid 32296371)
23. Jolivet J.P., Henry M. & Livage J. (2000) Metal Oxide Chemistry and Synthesis: From Solution to Solid State. John Wiley & Sons Inc: New York.
24. Klein C. & Philpotts T. (2012) Earth Materials: Introduction to Mineralogy and Petrology. Cambridge University Press.
25. Lowenstein W. (1954) The distribution of aluminum in the tetrahedra of silicates and aluminates. American Mineralogist, 39, 92-96.
26. Magini M., Licheri G., Paschina G., Piccaluga G. & Pinna G. (1988) X-ray Diffraction of Ions in Aqueous Solutions: Hydration and Complex Formation. 267 pp. CRC Press Inc., Boca Raton.
27. Maillot F., Morin G., Wang Y., Bonnin D., Ildefonse P., Chaneac C. & Calas G. (2011) New insight into the structure of nanocrystalline ferrihydrite: EXAFS evidence for tetrahedrally coordinated iron(III). Geochimica et Cosmochimica Acta, 75, 2708-2720.
28. Majzlan J. & Navrotsky A. (2003) Thermodynamics of the goethite-diaspore solid solution. European Journal of Mineralogy, 15, 495-501 (Pubitemid 36785153)
29. Manceau, A. (2009) Evaluation of the structural model for ferrihydrite derived from real-space modelling of high-energy X-ray diffraction data. Clay Minerals, 44, 19-34.
30. Manceau A. (2010) PDF analysis of ferrihydrite and the violation of Pauling's Principia. Clay Minerals, 45, 225-228.
31. Manceau A. (2011) Critical evaluation of the revised akdalaite model for ferrihydrite. American Mineralogist, 96, 521-533.
32. Manceau A. (2012a) Comment on 'Direct observation of tetrahedral coordinated Fe(III) in ferrihydrite. Environmental Science and Technology, 46, 6882-6884.
33. Manceau A. (2012b) Critical evaluation of the revised akdalaite model for ferrhydrite - Reply. American Mineralogist, 97, 255-256.
34. Manceau A. & Gates W.P. (1997) Surface structural model for ferrihydrite. Clays and Clay Minerals, 45, 448-460.
35. Manceau A., Lanson B., Drits V. A., Chateigner D., Gates W. P., Wu J., Huo D. & Stucki J. W (2000) Oxidation reduction mechanism of iron in dioctahedral smectites: 1. Crystal chemistry of oxidized reference nontronites. American Mineralogist, 85, 133-152. (Pubitemid 30166494)
36. Manceau A., Marcus M.A., Grangeon S., Lanson M., Lanson B., Gaillot A.C., Skanthakumar S. & Soderholm L. (2013) Short-range and long-range order of phyllomanganate nanoparticles determined using high energy X-ray scattering. Journal of Applied Crystallography, 46, 193-209.
37. Mazzetti L. & Thistlethwaite P.J. (2002) Raman spectra and thermal transformations of ferrihydrite and schwertmannite. Journal of Raman Spectroscopy, 33, 104-111.
38. Michel F.M., Ehm L., Antao S.M., Lee P.L., Chupas P.J., Liu G., Strongin D.R., Schoonen M.A.A., Phillips B.L. & Parise J.B. (2007) The structure of ferrihydrite, a nanocrystalline material. Science, 316, 1726-1729. (Pubitemid 46988543)
39. Michel F.M., Barron V., Torrent J., Morales A.P., Serna C. J., Boily J.-F., Liu Q., Ambrosini A., Cismasu A.C. & Brown G.E. (2010) Ordered ferrimagnetic form of ferrihydrite reveals links among structure, composition, and magnetism. Proceedings of the National Academy of Sciences of the United States of America, 107, 2787-2792.
40. Navrotsky A. (2004) Energetic clues to pathways to biomineralization: Precursors, clusters, and nanoparticles. Proceedings of the National Academy of Sciences of the United States of America, 101, 12096-12101. (Pubitemid 39145403)
41. Newman A.C.D. & Brown G. (1987) The chemical constitution of clays. Pp. 1-128 in: Chemistry of Clays and Clay Minerals (A.C.D. Newman, editor). Mineralogical Society, London.
42. Paktunc D., Manceau A. & Dutrizac J. (2013) Incorporation of Ge in ferrihydrite: Implications for the structure of ferrihydrite. American Mineralogist, 98, 859-869.
43. Pauling L. (1929) The principles determining the structure of complex ionic crystals. Journal of the American Chemical Society, 51, 1010-1026.
44. Petkov V., Ren Y., Saratovsky I., Pasten P., Gurr S.J., Hayward M.A., Poeppelmeier K.R. & Gaillard J.F. (2009) Atomic-scale structure of biogenic materials by total X-ray diffraction: A study of bacterial and fungal MnOx. ACS Nano, 3, 441-445.
45. Pinney N., Kubicki J.D., Middlemiss D.S., Grey C.P. & Morgan D. (2009) Density functional theory study of ferrihydrite and related Fe-oxyhydroxides. Chemistry of Materials, 21, 5727-5742.
46. Rancourt D.G. & Meunier J.F. (2008) Constraints on structural models of ferrihydrite as a nanocrystalline material. American Mineralogist, 93, 1412-1417.
47. Schulze D.G. & Schwertmann U. (1984) The influence of aluminium on iron oxides: X. Properties of Alsubstituted goethites. Clay Minerals, 19, 521-539.
48. Schwertmann U., Fitzpatrick R.W., Taylor R.M. & Lewis D.G. (1979) The influence of aluminum on iron oxides. II. Preparation and properties of Alsubstituted hematites. Clays and Clay Minerals, 27, 105-112. (Pubitemid 9441785)
49. Shannon R.D. (1976) Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallographica, A32, 751-767.
50. Sideris P.J., Blanc F., Gan Z. & Grey C.P. (2012) Identification of cation clustering in Mg-Al layered double hydroxides using multinuclear solid state nuclear magnetic resonance spectroscopy. Chemistry of Materials, 24, 2449-2463.
51. Stanjek H. & Weidler P.G. (1992) The effect of dry heating on the chemistry, surface area, and oxalate solubility of synthetic 2-line and 6-line ferrihydrites. Clay Minerals, 27, 397-412.
52. Towe K & Bradley W.F. (1967) Mineralogical constitution of colloidal ''hydrous ferric oxides'' Journal of Colloids and Interface Science, 24, 384-392.
53. Vilge-Ritter A., Rose J., Masion A., Botteri J.Y. & Laine J.M. (1999) Chemistry and structure of aggregates formed with Fe-salts and natural organic matter. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 147, 297-308. (Pubitemid 29076665)
54. Waseda Y. (1980) The Structure of Non-crystalline Materials. 326 pp. McGraw-Hill Inc., New York.
55. Wolska E . & Schwertmann, U. (1989 ) Nonstoichiometric structures during dehydroxylation of goethite. Zeitschrift für Kristallographie, 189, 69-75.
56. Xu W., Hausner D.B., Harrington R., Lee P.L., Strongin D.R. & Parise J.B. (2011) Structural water in ferrhydrite and constraints this provides on possible structure models. American Mineralogist, 96, 513-520.
57. Yatsenko D.A., Pakharukova V.P., Tsybulya S.V., Matvienko A.A. & Sidel'nikov A.A. (2012) Phase composition and structure of nanocrystalline products of solid-phase oxidative thermolysis of iron oxalate dehydrate. Journal of Structural Chemistry, 53, 548-556.
58. Zhang F.Q., Guan W., Zhang Y.T., Xu M. T., Li J. & Su Z.M. (2010) On the origin of the inverted stability order of reverse-Keggin [(MnO4)(CH3)12Sb12O24]6- : A DFT study of a, b, g, d and e isomers. Inorganic Chemistry, 49, 5472-5481