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Volumn 5, Issue 10, 2013, Pages 2818-2821

Selective hydrogenation of alkynes catalyzed by trinuclear rhodium hydride complexes of the type [{(Rh[PP]H)3(μ2-H)3(μ3-H)}(BF4)2]

Author keywords

Alkynes; Homogeneous catalysis; Hydride complexes; Rhodium; Selective hydrogenation

Indexed keywords

ALKYNES; HOMOGENEOUS CATALYSIS; HYDRIDE COMPLEXES; HYDROGEN CONSUMPTION; HYDROGEN PRESSURES; MICHAELIS-MENTEN KINETIC; MONONUCLEAR COMPLEXES; SELECTIVE HYDROGENATION;

EID: 84884950711     PISSN: 18673880     EISSN: 18673899     Source Type: Journal    
DOI: 10.1002/cctc.201300328     Document Type: Article
Times cited : (18)

References (31)
  • 28
    • 84884928473 scopus 로고    scopus 로고
    • The use of these complexes in the asymmetric hydrogenation of prochiral olefins such as dimethyl itaconate shows a strong induction period (FigureS1). This could be because the trinuclear complex is inactive for such types of substrates and needs some time to convert into the active species.
    • The use of these complexes in the asymmetric hydrogenation of prochiral olefins such as dimethyl itaconate shows a strong induction period (FigureS1). This could be because the trinuclear complex is inactive for such types of substrates and needs some time to convert into the active species.
  • 29
    • 84884971110 scopus 로고    scopus 로고
    • The analysis according to Michalis-Menten-type kinetics is exemplarity shown in FigureS3.
    • The analysis according to Michalis-Menten-type kinetics is exemplarity shown in FigureS3.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.