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The use of these complexes in the asymmetric hydrogenation of prochiral olefins such as dimethyl itaconate shows a strong induction period (FigureS1). This could be because the trinuclear complex is inactive for such types of substrates and needs some time to convert into the active species.
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The use of these complexes in the asymmetric hydrogenation of prochiral olefins such as dimethyl itaconate shows a strong induction period (FigureS1). This could be because the trinuclear complex is inactive for such types of substrates and needs some time to convert into the active species.
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The analysis according to Michalis-Menten-type kinetics is exemplarity shown in FigureS3.
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