Thermal treatment of natural goethite: Thermal transformation andphysical properties

Thermochimica Acta

Volumn 568, Issue , 2013, Pages 115-121

  Liu, Haibo ^a,b   Chen, Tianhu ^a   Zou, Xuehua ^a   Qing, Chengsong ^a   Frost, Ray L ^b  

^a HEFEI UNIVERSITY OF TECHNOLOGY   (China)

^b QUEENSLAND UNIVERSITY OF TECHNOLOGY   (Australia)

Author keywords

Goethite; Hematite; Specific surface area; Thermogravimetry; Topotactic relationshipa

Indexed keywords

EMISSION SPECTROSCOPY; HEMATITE; SCANNING ELECTRON MICROSCOPY; SPECIFIC SURFACE AREA; THERMOGRAVIMETRIC ANALYSIS; TRANSMISSION ELECTRON MICROSCOPY; X RAY DIFFRACTION;

FIELD EMISSION SCANNING ELECTRON MICROSCOPES; FOURIER TRANSFORM INFRA REDS; GOETHITE; HEATING TEMPERATURES; THERMAL TRANSFORMATIONS; TOPOTACTIC RELATIONSHIPA; X RAY FLUORESCENCE; XRD (X RAY DIFFRACTION);

PORE SIZE;

EID: 84884548045     PISSN: 00406031     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tca.2013.06.027     Document Type: Article

References (49)

1. R.M. Cornell, U. Schwertmann, The Iron Oxides: Structure, Properties, Reactions, Occurrences and Uses, 2nd ed., Wiley-VCH Gmb H&Co KGaA, Weinheim, 2003.
2. H. Liu, T. Chen, Q. Xie, X. Zou, C. Qing, R.L. Frost, Kinetic study of goethitedehydration and the effect of aluminium substitution on the dehydrate, Ther-mochim. Acta 545 (2012) 20.
3. U. Schwertmann, Transformation of hematite to goethite in soils, Nature 232(1971) 624.
4. H.D. Ruan, R.L. Frost, J.T. Kloprogge, The behavior of hydroxyl units of syntheticgoethite and its dehydroxylated product hematite, Spectrochim. Acta A Mol. Biomol. Spectrosc. 57 (2001) 2575.
5. P.S.R. Prasad, K. Shiva Prasad, V. Krishna Chaitanya, E.V.S.S.K. Babu, B. Sreedhar, S. Ramana Murthy, In situ FTIR study on the dehydration of natural goethite, J. Asian Earth Sci. 27 (2006) 503.
6. 3) surfaces, J. Colloid Interface Sci. 95 (1983) 385.
7. T. Ishikawa, W.Y. Cai, K. Kandori, Adsorption of molecules onto microporoushematite, Langmuir 9 (1993) 1125.
8. Y.S. Hwang, J.J. Lenhart, Adsorption of C4-dicarboxylic acids at thehematite/water interface, Langmuir 24 (2008) 13934.
9. M.M. Benjamin, R.S. Sletten, R.P. Bailey, T. Bennett, Sorption and filtration of metals using iron-oxide-coated sand, Water Res. 30 (1996) 2609.
10. S. Goldberg, H.S. Forster, C.L. Godfrey, Molybdenum adsorption on oxides, clayminerals, and soils, Soil Sci. Soc. Am. J. 60 (1996) 425.
11. I. Christl, R. Kretzschmar, Interaction of copper and fulvic acid at thehematite-water interface, Geochim. Cosmochim. Acta 65 (2001) 3435.
12. S. Pivovarov, Adsorption of cadmium onto hematite: temperature dependence, J. Colloid Interface Sci. 234 (2001) 1.
13. S. Das, M. Jim Hendry, Adsorption of molybdate by synthetic hematite underalkaline conditions: effects of aging, Appl. Geochem. 28 (2013) 194.
14. Y. Mamindy-Pajany, C. Hurel, N. Marmier, M. Roméo, Arsenic adsorption ontohematite and goethite, C.R. Chim. 12 (2009) 876.
15. P. Mäkie, G. Westin, P. Persson, L. Österlund, Adsorption of trimethyl phos-phate on maghemite, hematite, and goethite nanoparticles, J. Phys. Chem. A115 (2011) 8948.
16. J. Giménez, M. Martínez, J. de Pablo, M. Rovira, L. Duro, Arsenic sorption ontonatural hematite, magnetite, and goethite, J. Hazard. Mater. 141 (2007) 575.
17. M. Todorović, S.K. Milonjić, J.J.Čomor, I.J. Gal, Adsorption of radioactive ions 137Cs+, 85Sr2+, and 60Co2+ on natural magnetite and hematite, Sep. Sci. Tech-nol. 27 (1992) 671.
18. H. Zhang, L. Chen, L. Zhang, X. Yu, Impact of environmental conditions on theadsorption behavior of radionuclide Ni(II) onto hematite, J. Radioanal. Nucl. Chem. 287 (2011) 357.
19. X. Shuibo, Z. Chun, Z. Xinghuo, Y. Jing, Z. Xiaojian, W. Jingsong, Removal of ura-nium (VI) from aqueous solution by adsorption of hematite, J. Environ. Radioact. 100 (2009) 162.
20. T. Morimoto, M. Nagao, F. Tokuda, Relation between the amounts of chemisorbed and physisorbed water on metal oxides, J. Phys. Chem. 73 (1969)243.
21. G. Blyholder, E.A. Richardson, Infrared and volumetric data on the adsorption of ammonia, water, and other gases on activated iron(III) oxide, J. Phys. Chem. 66 (1962) 2597.
22. F. Jones, A.L. Rohl, J.B. Farrow, W. van Bronswijk, Molecular modeling of wateradsorption on hematite, Phys. Chem. Chem. Phys. 2 (2000) 3209.
23. V.A. Grover, J. Hu, K.E. Engates, H.J. Shipley, Adsorption and desorption of biva-lent metals to hematite nanoparticles, Environ. Toxicol. Chem. 31 (2012) 86.
24. S.J. Hug, In situ Fourier transform infrared measurements of sulfate adsorptionon hematite in aqueous solutions, J. Colloid Interface Sci. 188 (1997) 415.
25. X. Huang, Intersection of isotherms for phosphate adsorption on hematite, J. Colloid Interface Sci. 271 (2004) 296.
26. 3as reflected by radiotracer studies, J. Colloid Interface Sci. 247 (2002) 12.
27. W. Zhang, B. Rittmann, Y. Chen, Size effects on adsorption of hematite nanopar-ticles on E. coli cells, Environ. Sci. Technol. 45 (2011) 2172.
28. H. Zeng, A. Singh, S. Basak, K.-U. Ulrich, M. Sahu, P. Biswas, et al., Nanoscale sizeeffects on uranium(VI) adsorption to hematite, Environ. Sci. Technol. 43 (2009)1373.
29. H. Liu, T. Chen, D. Chang, D. Chen, R.L. Frost, Catalytic cracking of tars derivedfrom rice hull gasification over goethite and palygorskite, Appl. Clay Sci. 70(2012) 51.
30. J.L. Rendon, J. Cornejo, P. de Arambarri, C.J. Serna, Pore structure of thermallytreated goethite (α-FeOOH), J. Colloid Interface Sci. 92 (1983) 508.
31. C.J. Goss, The kinetics and reaction mechanism of the goethite to hematitetransformation, Mineral. Mag. 51 (1987) 437.
32. H. Liu, T. Chen, R.L. Frost, D. Chang, C. Qing, Q. Xie, Effect of aging time and Alsubstitution on the morphology of aluminous goethite, J. Colloid Interface Sci. 385 (2012) 81.
33. S.K. Ghose, G.A. Waychunas, T.P. Trainor, P.J. Eng, Hydrated goethite (α-FeOOH)(1 0 0) interface structure: ordered water and surface functional groups, Geochim. Cosmochim. Acta 74 (2010) 1943.
34. R.G. Ford, P.M. Bertsch, Distinguishing between surface and bulkdehydration-dehydroxylation reactions in synthetic goethites by highresolution thermogravimetric analysis, Clays Clay Miner. 47 (1999) 329.
35. M.L.P. Antunes, S.J. Couperthwaite, F.T. da Conceição, C.P. Costa de Jesus, P.K. Kiyohara, A.C.V. Coelho, et al., Red mud from Brazil: thermal behavior and physical properties, Ind. Eng. Chem. Res. 51 (2011) 775.
36. U. Schwertmann, The double dehydroxylation peak of goethite, Thermochim. Acta 78 (1984) 39.
37. W. Emilia, The structure of hydrohematite, Z. Kristallogr. 154 (1981) 69.
38. C.J. Serna, J.E. Iglesias, Nature of protohaematite and hydrohaematite, J. Mater. Sci. Lett. 5 (1986) 901.
39. H.D. Ruan, R.L. Frost, J.T. Kloprogge, L. Duong, Infrared spectroscopy of goethitedehydroxylation: III. FT-IR microscopy of in situ study of the thermal transfor-mation of goethite to hematite, Spectrochim. Acta A: Mol. Biomol. Spectrosc. 58 (2002) 967.
40. U. Schwertmann, P. Cambier, E. Murad, Properties of goethites of varying crys-tallinity, Clays Clay Miner. 33 (1985) 369.
41. P. Cambier, Infrared study of goethites of varying crystallinity and particle size.I. Interpretation of OH and lattice vibration frequencies, Clay Miner. 21 (1986)191.
42. G.N. Kustova, E.B. Burgina, V.A. Sadykov, S.G. Poryvaev, Vibrational spectro-scopic investigation of the goethite thermal decomposition products, Phys. Chem. Miner. 18 (1992) 379.
43. H. Naono, K. Nakai, T. Sueyoshi, H. Yagi, Porous texture in hematite derived fromgoethite: mechanism of thermal decomposition of geothite, J. Colloid Interface Sci. 120 (1987) 439.
44. H. Naono, R. Fujiwara, H. Sugioka, K. Sumiya, H. Yanazawa, Micropore formationdue to thermal decomposition of acicular microcrystals of β-FeOOH, J. Colloid Interface Sci. 87 (1982) 317.
45. H. Stanjek, U. Schwertmann, The influence of aluminum on iron oxides. Part XVI. Hydroxyl and aluminum substitution in synthetic hematites, Clays Clay Miner. 40 (1992) 347.
46. H.D. Ruan, R.J. Gilkes, Dehydroxylation of aluminous goethite; unit cell dimensions, crystal size and surface area, Clays Clay Miner. 43 (1995) 196.
47. H.D. Ruan, R.L. Frost, J.T. Kloprogge, L. Duong, Infrared spectroscopy of goethitedehydroxylation. II. Effect of aluminium substitution on the behaviour of hydroxyl units, Spectrochim. Acta A: Mol. Biomol. Spectrosc. 58 (2002) 479.
48. H.B. Liu, T.H. Chen, D.Y. Chang, D. Chen, Y. Liu, H.P. He, et al., Nitrate reductionover nanoscale zero-valent iron prepared by hydrogen reduction of goethite, Mater. Chem. Phys. 133 (2012) 205.
49. X. Gao, D.G. Schulze, Precipitation and transformation of secondary Fe oxyhy-droxides in a histosol impacted by runoff from a lead smelter, Clays Clay Miner. 58 (2010) 377.